Study on Methanation Performance of Biomass Gasification Syngas Based on a Ni/Al2O3 Monolithic Catalyst Article Swipe
YOU?
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· 2020
· Open Access
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· DOI: https://doi.org/10.1021/acsomega.0c03536
The structure of a Ni/Al2O3 monolithic catalyst after methanation reaction and its methanation performance were studied by taking analogue syngas of biomass gasification H2/CO/N2 as feed gas when the temperature ranged from 250 to 550 °C, and the weight hourly space velocity (WHSV) was between 6000 and 14,000 mL g-1 h-1. The Ni/Al2O3 catalysts using cordierite honeycomb ceramics as the substrate were prepared by dipping and sol-gel methods. The results show that the Ni/Al2O3 catalyst prepared by the dipping method (DIP-Ni/Al2O3) has better methanation performance than the Ni/Al2O3 catalyst prepared by the sol-gel method (SG-Ni/Al2O3) through many tests such as TEM, BET, XRD, H2-TPD, H2-TPR, and TG analysis. The DIP-Ni/Al2O3 catalyst exhibits the best methanation performance at 400 °C when the molar ratio of H2, CO, and N2 is 3/1/1 and the WHSV is 10,000 mL g-1 h-1. Under this condition, the CO conversion and CH4 selectivity are 98.6 and 90.9%, respectively. In addition, the methanation performance of the DIP-Ni/Al2O3 catalyst is relatively more stable, and the CO conversion and CH4 selectivity were basically maintained at around 90% within the experimental WHSV range. The influence of Ni content on the methanation performance of the DIP-Ni/Al2O3 catalyst can be seen in the order from high to low of methanation performance: 15% Ni, 20% Ni, and 10% Ni, and the maximum values of CO conversion and CH4 selectivity reach 96.8 and 96%, respectively, at 400 °C for 15% Ni/Al2O3.
Related Topics
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1021/acsomega.0c03536
- https://pubs.acs.org/doi/pdf/10.1021/acsomega.0c03536
- OA Status
- gold
- Cited By
- 22
- References
- 32
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W3097251036
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W3097251036Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1021/acsomega.0c03536Digital Object Identifier
- Title
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Study on Methanation Performance of Biomass Gasification Syngas Based on a Ni/Al2O3 Monolithic CatalystWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
-
2020Year of publication
- Publication date
-
2020-10-29Full publication date if available
- Authors
-
Wanli Xing, Yifan Liu, Wanli Zhang, Yang Sun, Xingping Kai, Tianhua YangList of authors in order
- Landing page
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https://doi.org/10.1021/acsomega.0c03536Publisher landing page
- PDF URL
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https://pubs.acs.org/doi/pdf/10.1021/acsomega.0c03536Direct link to full text PDF
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YesWhether a free full text is available
- OA status
-
goldOpen access status per OpenAlex
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https://pubs.acs.org/doi/pdf/10.1021/acsomega.0c03536Direct OA link when available
- Concepts
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Methanation, Syngas, Catalysis, Biomass gasification, Biomass (ecology), Materials science, Chemical engineering, Waste management, Chemistry, Organic chemistry, Engineering, Geology, OceanographyTop concepts (fields/topics) attached by OpenAlex
- Cited by
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22Total citation count in OpenAlex
- Citations by year (recent)
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2025: 8, 2024: 6, 2023: 5, 2022: 2, 2021: 1Per-year citation counts (last 5 years)
- References (count)
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32Number of works referenced by this work
- Related works (count)
-
10Other works algorithmically related by OpenAlex
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