Sub‐5 Ångstrom Porosity Tuning in Calixarene‐Derived Porous Liquids via Supramolecular Complexation Construction Article Swipe
Errui Li
,
Arvind Ganesan
,
Hongjun Liu
,
Alexander S. Ivanov
,
Lilin He
,
Phattananawee Nalaoh
,
David M. Jenkins
,
Carlos A. Steren
,
Narges Mokhtarinori
,
Jian Zhi Hu
,
Bo Li
,
De‐en Jiang
,
Shannon M. Mahurin
,
Zhenzhen Yang
,
Sheng Dai
·
YOU?
·
· 2025
· Open Access
·
· DOI: https://doi.org/10.1002/anie.202421615
YOU?
·
· 2025
· Open Access
·
· DOI: https://doi.org/10.1002/anie.202421615
Sub‐Ångstrom‐level porosity engineering, which is appealing in gas separations, has been demonstrated in solid carbon, polymer, and framework materials but rarely achieved in the liquid phase. In this work, a gas molecular sieving effect in the liquid phase at sub‐5 Ångstrom scale is created via sophisticated porosity tuning in calixarene‐derived porous liquids (PLs). Type II PLs are constructed via supramolecular complexation between the sodium salts of calixarene derivatives and crown ether solvents. The chemical structure variation and assembly behavior of the porous host upon PL construction are monitored by spectroscopy‐, X‐ray‐, and neutron‐scattering techniques. The presence of permanent porosity in calixarene‐derived PLs is verified by pressure swing gas uptake, altered CO 2 physisorption behavior, and molecular simulations. Sub‐5 Ångstrom porosity tuning within the PL phase is achieved by introducing bulky substituted groups on the benzene ring of the calixarene host, which then greatly affects the dynamic motion and transport behavior of CO 2 molecules and the Xe uptake performance. The approach being demonstrated in this work represents a promising pathway to tune and leverage the porosity effect for enhanced gas uptake capacity and selectivity in liquid sorbents.
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- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1002/anie.202421615
- OA Status
- green
- Cited By
- 9
- References
- 58
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4406099795
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W4406099795Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1002/anie.202421615Digital Object Identifier
- Title
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Sub‐5 Ångstrom Porosity Tuning in Calixarene‐Derived Porous Liquids via Supramolecular Complexation ConstructionWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2025Year of publication
- Publication date
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2025-01-06Full publication date if available
- Authors
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Errui Li, Arvind Ganesan, Hongjun Liu, Alexander S. Ivanov, Lilin He, Phattananawee Nalaoh, David M. Jenkins, Carlos A. Steren, Narges Mokhtarinori, Jian Zhi Hu, Bo Li, De‐en Jiang, Shannon M. Mahurin, Zhenzhen Yang, Sheng DaiList of authors in order
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https://doi.org/10.1002/anie.202421615Publisher landing page
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YesWhether a free full text is available
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greenOpen access status per OpenAlex
- OA URL
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https://www.osti.gov/servlets/purl/2530656Direct OA link when available
- Concepts
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Calixarene, Porosity, Supramolecular chemistry, Materials science, Chemical engineering, Chemistry, Organic chemistry, Composite material, Molecule, EngineeringTop concepts (fields/topics) attached by OpenAlex
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9Total citation count in OpenAlex
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2025: 9Per-year citation counts (last 5 years)
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10Other works algorithmically related by OpenAlex
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