Synergistic combination of triazine and phenanthroline moieties in a covalent triazine framework tailored for heterogeneous photocatalytic metal-free C-Br and C-Cl activation Article Swipe
Alberto López‐Magano
,
Noelia Salaverri
,
Leyre Marzo
,
Rubén Mas‐Ballesté
,
José Alemán
·
YOU?
·
· 2022
· Open Access
·
· DOI: https://doi.org/10.1016/j.apcatb.2022.121791
YOU?
·
· 2022
· Open Access
·
· DOI: https://doi.org/10.1016/j.apcatb.2022.121791
We present the design and synthesis of a new covalent triazine framework with high content of N atoms bearing \ntriazine and phenanthroline moieties. This material displays interesting luminescence phenomena and enhanced \nphotoredox activity as a consequence of synergistic combination of both N-containing aromatic fragments. As \ncatalytic application, the reduction of a variety of brominated and challenging chlorinated aromatic structures, \nincluding persistent organic pollutants such as polybrominated diphenyl ethers, has been performed under light \nirradiation and room temperature conditions. These chemical transformations follow a photoredox mechanism \ninvolving the formation of aryl radicals, that were trapped with different radical acceptors in order to afford the \nformation of new C-C, C-B and C-P bonds
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Metadata
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1016/j.apcatb.2022.121791
- OA Status
- hybrid
- Cited By
- 22
- References
- 69
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4287881318
All OpenAlex metadata
Raw OpenAlex JSON
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https://openalex.org/W4287881318Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1016/j.apcatb.2022.121791Digital Object Identifier
- Title
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Synergistic combination of triazine and phenanthroline moieties in a covalent triazine framework tailored for heterogeneous photocatalytic metal-free C-Br and C-Cl activationWork title
- Type
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articleOpenAlex work type
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enPrimary language
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2022Year of publication
- Publication date
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2022-07-26Full publication date if available
- Authors
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Alberto López‐Magano, Noelia Salaverri, Leyre Marzo, Rubén Mas‐Ballesté, José AlemánList of authors in order
- Landing page
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https://doi.org/10.1016/j.apcatb.2022.121791Publisher landing page
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YesWhether a free full text is available
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hybridOpen access status per OpenAlex
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https://doi.org/10.1016/j.apcatb.2022.121791Direct OA link when available
- Concepts
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Triazine, Covalent bond, Phenanthroline, Chemistry, Photocatalysis, Radical, Aryl, Photochemistry, Photoredox catalysis, Metal, Catalysis, Combinatorial chemistry, 1,3,5-Triazine, Polymer chemistry, Inorganic chemistry, Organic chemistry, AlkylTop concepts (fields/topics) attached by OpenAlex
- Cited by
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22Total citation count in OpenAlex
- Citations by year (recent)
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2025: 7, 2024: 9, 2023: 5, 2022: 1Per-year citation counts (last 5 years)
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69Number of works referenced by this work
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10Other works algorithmically related by OpenAlex
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