Synthese von Cobalt‐Zinn‐ und ‐Blei‐Tetrylidinen – Reaktivitätsuntersuchungen der Dreifachbindung Article Swipe

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Maximilian Auer , Kathrin Zwettler , Klaus Eichele , Hartmut Schubert , Christian P. Sindlinger , Lars Wesemann ·

YOU? · · 2023 · Open Access · · DOI: https://doi.org/10.1002/ange.202305951

Die Tetrylidine [TbbSn≡Co(PMe 3 ) 3 ] ( 1 a ) und [TbbPb≡Co(PMe 3 ) 3 ] ( 2 ) (Tbb=2,6‐[CH(SiMe 3 ) 2 ] 2 ‐4‐( t ‐Bu)C 6 H 2 ) wurden über eine Substitutionsreaktion zwischen [Na(OEt 2 )][Co(PMe 3 ) 4 ] und [Li(thf) 2 ][TbbEBr 2 ] (E=Sn, Pb) erstmals dargestellt. Alternativ wurde das Stannylidin [Ar*Sn≡Co(PMe 3 ) 3 ] ( 1 b ) durch eine Wasserstoffatom‐Abstraktion am paramagnetischen Hydridkomplex [Ar*SnH=Co(PMe 3 ) 3 ] ( 4 ) in einer Reaktion mit AIBN (AIBN=Azobis( iso ‐butyronitril)) synthetisiert. Das Stannylidin 1 a addiert zwei Äquivalente Wasser, wobei das Dihydroxid [TbbSn(OH) 2 CoH 2 (PMe 3 ) 3 ] ( 5 ) erhalten wird. Bei der Reaktion des Stannylidins 1 a mit CO 2 wurde ein Produkt einer Redoxreaktion [TbbSn(CO 3 )Co(CO)(PMe 3 ) 3 ] ( 6 ) isoliert. Die Protonierung des Tetrylidins erfolgt am Cobaltatom und ergibt das Metallastannavinyl‐Kation [TbbSn=CoH(PMe 3 ) 3 ][BAr F 4 ] ( 7 a ) [Ar F =C 6 H 3 ‐3,5‐(CF 3 ) 2 ]. Die analogen Germanium‐ und Zinnkationen [Ar*E=CoH(PMe 3 ) 3 ][BAr F 4 ] (E=Ge 9 , Sn 7 b ) (Ar*=C 6 H 3 (2,6‐Trip) 2 , Trip=2,4,6‐C 6 H 2 i Pr 3 ) wurden durch Oxidation der paramagnetischen Komplexe [Ar*EH=Co(PMe 3 ) 3 ] (E=Ge 3 , Sn 4 ) ebenfalls erhalten, welche durch Substitution eines PMe 3 ‐Liganden am [Co(PMe 3 ) 4 ]‐Komplex durch eine Hydridoylen‐Einheit (Ar*EH) synthetisiert werden können.

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Chemistry Stereochemistry Medicinal chemistry

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Language: de
Landing Page: https://doi.org/10.1002/ange.202305951
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DOI: https://doi.org/10.1002/ange.202305951

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Title: Synthese von Cobalt‐Zinn‐ und ‐Blei‐Tetrylidinen – Reaktivitätsuntersuchungen der Dreifachbindung

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Authors: Maximilian Auer, Kathrin Zwettler, Klaus Eichele, Hartmut Schubert, Christian P. Sindlinger, Lars Wesemann

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abstract_inverted_index.(E=Sn,	52
abstract_inverted_index.ergibt	151
abstract_inverted_index.welche	231
abstract_inverted_index.werden	249
abstract_inverted_index.wurden	34, 212
abstract_inverted_index.(Ar*EH)	247
abstract_inverted_index.Produkt	129
abstract_inverted_index.Wasser,	99
abstract_inverted_index.[Co(PMe	239
abstract_inverted_index.[Na(OEt	39
abstract_inverted_index.addiert	96
abstract_inverted_index.erfolgt	147
abstract_inverted_index.‐Bu)C	29
abstract_inverted_index.Abstract	0
abstract_inverted_index.Komplexe	217
abstract_inverted_index.Reaktion	85, 119
abstract_inverted_index.[Li(thf)	47
abstract_inverted_index.][TbbEBr	49
abstract_inverted_index.analogen	178
abstract_inverted_index.erhalten	115
abstract_inverted_index.erstmals	54
abstract_inverted_index.können.	250
abstract_inverted_index.zwischen	38
abstract_inverted_index.‐4‐(	27
abstract_inverted_index.)][Co(PMe	41
abstract_inverted_index.Oxidation	214
abstract_inverted_index.[TbbSn(CO	132
abstract_inverted_index.ebenfalls	229
abstract_inverted_index.erhalten,	230
abstract_inverted_index.isoliert.	142
abstract_inverted_index.Alternativ	56
abstract_inverted_index.Cobaltatom	149
abstract_inverted_index.Dihydroxid	102
abstract_inverted_index.[TbbSn(OH)	103
abstract_inverted_index.)Co(CO)(PMe	134
abstract_inverted_index.Stannylidin	59, 93
abstract_inverted_index.Tetrylidine	2
abstract_inverted_index.Tetrylidins	146
abstract_inverted_index.]‐Komplex	243
abstract_inverted_index.‐Liganden	237
abstract_inverted_index.(2,6‐Trip)	201
abstract_inverted_index.Germanium‐	179
abstract_inverted_index.Protonierung	144
abstract_inverted_index.Stannylidins	121
abstract_inverted_index.Substitution	233
abstract_inverted_index.Zinnkationen	181
abstract_inverted_index.dargestellt.	55
abstract_inverted_index.Äquivalente	98
abstract_inverted_index.‐3,5‐(CF	172
abstract_inverted_index.(AIBN=Azobis(	88
abstract_inverted_index.Hydridkomplex	74
abstract_inverted_index.Redoxreaktion	131
abstract_inverted_index.[Ar*E=CoH(PMe	182
abstract_inverted_index.[Ar*EH=Co(PMe	218
abstract_inverted_index.synthetisiert	248
abstract_inverted_index.Trip=2,4,6‐C	204
abstract_inverted_index.[Ar*SnH=Co(PMe	75
abstract_inverted_index.[TbbSn=CoH(PMe	154
abstract_inverted_index.synthetisiert.	91
abstract_inverted_index.[Ar*Sn≡Co(PMe	60
abstract_inverted_index.[TbbPb≡Co(PMe	13
abstract_inverted_index.[TbbSn≡Co(PMe	3
abstract_inverted_index.paramagnetischen	73, 216
abstract_inverted_index.‐butyronitril))	90
abstract_inverted_index.(Tbb=2,6‐[CH(SiMe	21
abstract_inverted_index.Hydridoylen‐Einheit	246
abstract_inverted_index.Substitutionsreaktion	37
abstract_inverted_index.Metallastannavinyl‐Kation	153
abstract_inverted_index.Wasserstoffatom‐Abstraktion	71
cited_by_percentile_year
corresponding_author_ids	https://openalex.org/A5075581551
countries_distinct_count	1
institutions_distinct_count	6
corresponding_institution_ids	https://openalex.org/I8087733
sustainable_development_goals[0].id	https://metadata.un.org/sdg/6
sustainable_development_goals[0].score	0.7200000286102295
sustainable_development_goals[0].display_name	Clean water and sanitation
citation_normalized_percentile.value	0.09934118
citation_normalized_percentile.is_in_top_1_percent	False
citation_normalized_percentile.is_in_top_10_percent	False