Synthesis and Characterization of Highly Crystalline Bi-Functional Mn-Doped Zn2SiO4 Nanostructures by Low-Cost Sol–Gel Process Article Swipe
YOU?
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· 2023
· Open Access
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· DOI: https://doi.org/10.3390/nano13030538
Herein, we demonstrate a process for the synthesis of a highly crystalline bi-functional manganese (Mn)-doped zinc silicate (Zn2SiO4) nanostructures using a low-cost sol–gel route followed by solid state reaction method. Structural and morphological characterizations of Mn-doped Zn2SiO4 with variable doping concentration of 0.03, 0.05, 0.1, 0.2, 0.5, 1.0, and 2.0 wt% were investigated by using X-ray diffraction and high-resolution transmission electron microscopy (HR-TEM) techniques. HR-TEM-assisted elemental mapping of the as-grown sample was conducted to confirm the presence of Mn in Zn2SiO4. Photoluminescence (PL) spectra indicated that the Mn-doped Zn2SiO4 nanostructures exhibited strong green emission at 521 nm under 259 nm excitation wavelengths. It was observed that PL intensity increased with the increase of Mn-doping concentration in Zn2SiO4 nanostructures, with no change in emission peak position. Furthermore, magnetism in doped Zn2SiO4 nanostructures was probed by static DC magnetization measurement. The observed photoluminescence and magnetic properties in Mn-doped Zn2SiO4 nanostructures are discussed in terms of structural defect/lattice strain caused by Mn doping and the Jahn–Teller effect. These bi-functional properties of as-synthesized Zn2SiO4 nanostructures provide a new platform for their potential applications towards magneto-optical and spintronic and devices areas.
Related Topics
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.3390/nano13030538
- https://www.mdpi.com/2079-4991/13/3/538/pdf?version=1674978501
- OA Status
- gold
- Cited By
- 9
- References
- 52
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4318483735
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W4318483735Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.3390/nano13030538Digital Object Identifier
- Title
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Synthesis and Characterization of Highly Crystalline Bi-Functional Mn-Doped Zn2SiO4 Nanostructures by Low-Cost Sol–Gel ProcessWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2023Year of publication
- Publication date
-
2023-01-29Full publication date if available
- Authors
-
Dhiraj Kumar Bharti, Rajni Verma, Sonam Rani, Daksh Agarwal, Sonali Mehra, Amit Kumar Gangwar, Bipin Kumar Gupta, Nidhi Singh, Avanish Kumar SrivastavaList of authors in order
- Landing page
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https://doi.org/10.3390/nano13030538Publisher landing page
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https://www.mdpi.com/2079-4991/13/3/538/pdf?version=1674978501Direct link to full text PDF
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YesWhether a free full text is available
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goldOpen access status per OpenAlex
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https://www.mdpi.com/2079-4991/13/3/538/pdf?version=1674978501Direct OA link when available
- Concepts
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Photoluminescence, Materials science, Doping, Nanostructure, Analytical Chemistry (journal), Luminescence, Nanotechnology, Optoelectronics, Chemistry, ChromatographyTop concepts (fields/topics) attached by OpenAlex
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9Total citation count in OpenAlex
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2025: 4, 2024: 2, 2023: 3Per-year citation counts (last 5 years)
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52Number of works referenced by this work
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10Other works algorithmically related by OpenAlex
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