Synthesis and Crystal Structure of Anhydrous Di-iodyl Carbonate (IO 2 ) 2 [CO 3 ], Hosting I 5+ -Cations Article Swipe
Dominik Spahr
,
Lkhamsuren Bayarjargal
,
Lukas Brüning
,
Valentin Kovalev
,
Elena Bykova
,
Maxim Bykov
,
Victor Milman
,
Mohamed Mézouar
,
B. Winkler
·
YOU?
·
· 2025
· Open Access
·
· DOI: https://doi.org/10.1021/jacsau.5c00829
YOU?
·
· 2025
· Open Access
·
· DOI: https://doi.org/10.1021/jacsau.5c00829
The anhydrous di-iodyl carbonate (IO2)2[CO3] has been synthesized in a laser-heated diamond anvil cell at 30(2) GPa and 1600(200) K by a reaction of I2O5 with CO2. Its monoclinic crystal structure (C2/c with Z = 4) was determined from synchrotron single crystal X-ray diffraction data. The experimental structural model was confirmed by density functional theory based calculations in combination with experimental Raman spectroscopy. (IO2)2[CO3]-C2/c belongs to the family of sp2-carbonates, and its crystal structure is characterized by the presence of nearly trigonal-planar [CO3]2- groups. In contrast to other iodide-containing carbonates, in this structure the iodine atoms are present as small and highly oxidized I5+-cations and not as large I--anions. The I5+-cations are coordinated by seven oxygen atoms. The successful synthesis of (IO2)2[CO3]-C2/c represents a significant enlargement of the crystal chemistry of carbonates, as this chemically simple carbonate demonstrates that anhydrous carbonates with highly charged cations can be formed and that sp2-carbonates hosting a positively charged halogen atom as the only cation can be synthesized.
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- https://doi.org/10.1021/jacsau.5c00829
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Synthesis and Crystal Structure of Anhydrous Di-iodyl Carbonate (IO 2 ) 2 [CO 3 ], Hosting I 5+ -CationsWork title
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articleOpenAlex work type
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enPrimary language
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2025Year of publication
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2025-10-14Full publication date if available
- Authors
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Dominik Spahr, Lkhamsuren Bayarjargal, Lukas Brüning, Valentin Kovalev, Elena Bykova, Maxim Bykov, Victor Milman, Mohamed Mézouar, B. WinklerList of authors in order
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https://doi.org/10.1021/jacsau.5c00829Publisher landing page
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goldOpen access status per OpenAlex
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1Total citation count in OpenAlex
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2025: 1Per-year citation counts (last 5 years)
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33Number of works referenced by this work
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| publication_date | 2025-10-14 |
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