Synthesis of bis coumarinyl methanes using of potassium 2-oxoimidazolidine-1,3-diide as a novel, efficient and reusable catalyst Article Swipe
Mohammad Nikpassand
,
Leila Zare Fekri
·
YOU?
·
· 2019
· Open Access
·
· DOI: https://doi.org/10.22034/crl.2019.85819
YOU?
·
· 2019
· Open Access
·
· DOI: https://doi.org/10.22034/crl.2019.85819
At first, potassium 2-oxoimidazolidine-1,3-diide (POImD) was prepared of stirring a mixture of imidazolidin-2-one, KOH and H2O overnight. Then, Potassium 2-oxoimidazolidine-1,3-diide was used as a green, novel, fast, efficient and mild catalyst for the synthesis of bis coumarinyl methanes via a one-pot reaction of one equivalent of various aromatic aldehydes and two equivalents of 4-hydroxycoumarin at room temperature in aqueous media. All reactions are performed in the absence of organic solvent in high to excellent yield during short reaction time. The procedure was readily conducted and affords remarkable advantages such as simple work-up, green media and eco-friendly procedure. The catalyst was recovered and reused. Apart from the mild conditions of the process and its excellent results, the simplicity of product isolation and the possibility to recycle the catalyst offer a significant advantage. To the best of our knowledge this is the first report on synthesis of POImD. All of synthesized compounds were characterized by IR, 1H and 13C NMR spectroscopy and elemental analyses.
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Metadata
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- article
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- en
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- https://doaj.org/article/142aff324f574c25953775d517065986
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- green
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- 1
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- 10
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All OpenAlex metadata
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- OpenAlex ID
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https://openalex.org/W2939936735Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.22034/crl.2019.85819Digital Object Identifier
- Title
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Synthesis of bis coumarinyl methanes using of potassium 2-oxoimidazolidine-1,3-diide as a novel, efficient and reusable catalystWork title
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articleOpenAlex work type
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enPrimary language
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2019Year of publication
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2019-02-01Full publication date if available
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Mohammad Nikpassand, Leila Zare FekriList of authors in order
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https://doaj.org/article/142aff324f574c25953775d517065986Publisher landing page
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YesWhether a free full text is available
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greenOpen access status per OpenAlex
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https://doaj.org/article/142aff324f574c25953775d517065986Direct OA link when available
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Potassium, Catalysis, Business, Chemistry, Computer science, Organic chemistryTop concepts (fields/topics) attached by OpenAlex
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1Total citation count in OpenAlex
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2025: 1Per-year citation counts (last 5 years)
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10Other works algorithmically related by OpenAlex
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