Synthesis of Enantiopure [3]Cyclorubicenes Article Swipe
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Moritz P. Schuldt
,
Frank Röminger
,
Michael Mastalerz
·
YOU?
·
· 2025
· Open Access
·
· DOI: https://doi.org/10.1002/ange.202520880
· OA: W4416093236
YOU?
·
· 2025
· Open Access
·
· DOI: https://doi.org/10.1002/ange.202520880
· OA: W4416093236
The interest in chiral nanohoops and nanotubes as well as their chiroptical properties has steadily increased in recent years. The synthesis of pentagon containing enantiopure [3]cyclorubicenes, which are cutouts and potential precursors of chiral Haeckelite nanotubes is presented, based on enantiopure “corner units”. The resulting enantiopure nanohoops were studied for their electronic and chiroptical properties with one of the highest dissymmetry values reported for CPPs of up to 2.3 × 10 −2 .
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