Synthesis of linear amylose-based porous carbon via low-dosage KOH activation for high-performance supercapacitors Article Swipe
Xiaodong He
,
Rui Ma
,
Puya Feng
,
Hairu Wang
,
Lili Ai
,
Mengjiao Xu
,
Dianzeng Jia
,
Luxiang Wang
,
Nannan Guo
·
YOU?
·
· 2025
· Open Access
·
· DOI: https://doi.org/10.1016/j.ijbiomac.2025.147685
YOU?
·
· 2025
· Open Access
·
· DOI: https://doi.org/10.1016/j.ijbiomac.2025.147685
The pursuit of high-energy-density carbon-derived supercapacitors continues to confront substantial material challenges, particularly regarding the rational design of electrode architectures. Herein, we systematically investigate biomass-derived porous carbons synthesized through a sustainable low-dosage KOH activation strategy, employing three distinct starch precursors: native corn starch, linear amylose, and amylopectin. Comprehensive characterization reveals critical structure-property relationships, where the amylose-derived carbon exhibits a highly disordered amorphous architecture with optimized hierarchical porosity, contrasting with the relatively ordered domains observed in corn starch and amylopectin derivatives. This structural superiority translates to exceptional electrochemical performance, demonstrating a remarkable gravimetric capacitance of 328 F g-1 at 1 A g-1 with outstanding rate capability (74 % retention at 50 A g-1) in 6 M KOH electrolyte. When configured as a symmetric supercapacitor, the material achieves an energy density of 8.1 Wh kg-1 at 250 W kg-1 while maintaining 98 % capacitance retention over 20,000 cycles - metrics that surpass most reported starch-derived carbons. This work establishes fundamental guidelines for tailoring biopolymer-derived carbons through precursor selection and activation control, offering new perspectives for sustainable energy storage solutions.
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- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1016/j.ijbiomac.2025.147685
- OA Status
- hybrid
- Cited By
- 1
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- 57
- OpenAlex ID
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Raw OpenAlex JSON
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https://openalex.org/W4414190049Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1016/j.ijbiomac.2025.147685Digital Object Identifier
- Title
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Synthesis of linear amylose-based porous carbon via low-dosage KOH activation for high-performance supercapacitorsWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2025Year of publication
- Publication date
-
2025-09-15Full publication date if available
- Authors
-
Xiaodong He, Rui Ma, Puya Feng, Hairu Wang, Lili Ai, Mengjiao Xu, Dianzeng Jia, Luxiang Wang, Nannan GuoList of authors in order
- Landing page
-
https://doi.org/10.1016/j.ijbiomac.2025.147685Publisher landing page
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YesWhether a free full text is available
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-
hybridOpen access status per OpenAlex
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https://doi.org/10.1016/j.ijbiomac.2025.147685Direct OA link when available
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1Total citation count in OpenAlex
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2025: 1Per-year citation counts (last 5 years)
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57Number of works referenced by this work
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| referenced_works | https://openalex.org/W2258661450, https://openalex.org/W3014672812, https://openalex.org/W4282824710, https://openalex.org/W2102333679, https://openalex.org/W3016292053, https://openalex.org/W4321792337, https://openalex.org/W2093831851, https://openalex.org/W3126840023, https://openalex.org/W4404702738, https://openalex.org/W2150673614, https://openalex.org/W2993886155, https://openalex.org/W3045089716, https://openalex.org/W3137651322, https://openalex.org/W4387949516, https://openalex.org/W2313465927, https://openalex.org/W2405918300, https://openalex.org/W2163585067, https://openalex.org/W2081870623, https://openalex.org/W2300733217, https://openalex.org/W2806656299, https://openalex.org/W3162109060, https://openalex.org/W2792834896, https://openalex.org/W1982568846, https://openalex.org/W2953380351, https://openalex.org/W2094555803, https://openalex.org/W2084245557, https://openalex.org/W1986700947, https://openalex.org/W2476482915, https://openalex.org/W3047645284, https://openalex.org/W2997066356, https://openalex.org/W4391888037, https://openalex.org/W4392650194, https://openalex.org/W4405311437, https://openalex.org/W4394933487, https://openalex.org/W4400079291, https://openalex.org/W4409791780, https://openalex.org/W2619399074, https://openalex.org/W3004233429, https://openalex.org/W4313648661, https://openalex.org/W4313394662, https://openalex.org/W4225162241, https://openalex.org/W4385455384, https://openalex.org/W4393257525, https://openalex.org/W4404029220, https://openalex.org/W4390022062, https://openalex.org/W4407858524, https://openalex.org/W4408514796, https://openalex.org/W2089711603, https://openalex.org/W1995092595, https://openalex.org/W2077938270, https://openalex.org/W2100588380, https://openalex.org/W3135189567, https://openalex.org/W4401973819, https://openalex.org/W3216012488, https://openalex.org/W2749229660, https://openalex.org/W4385990915, https://openalex.org/W4387624620 |
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