Synthesis of quenchable amorphous diamond Article Swipe
Zhidan Zeng
,
Liuxiang Yang
,
Qiaoshi Zeng
,
Hongbo Lou
,
H. W. Sheng
,
Jianguo Wen
,
Dean J. Miller
,
Yue Meng
,
Wenge Yang
,
Wendy L. Mao
,
Ho‐kwang Mao
·
YOU?
·
· 2017
· Open Access
·
· DOI: https://doi.org/10.1038/s41467-017-00395-w
YOU?
·
· 2017
· Open Access
·
· DOI: https://doi.org/10.1038/s41467-017-00395-w
Diamond owes its unique mechanical, thermal, optical, electrical, chemical, and biocompatible materials properties to its complete sp 3 -carbon network bonding. Crystallinity is another major controlling factor for materials properties. Although other Group-14 elements silicon and germanium have complementary crystalline and amorphous forms consisting of purely sp 3 bonds, purely sp 3 -bonded tetrahedral amorphous carbon has not yet been obtained. In this letter, we combine high pressure and in situ laser heating techniques to convert glassy carbon into “quenchable amorphous diamond”, and recover it to ambient conditions. Our X-ray diffraction, high-resolution transmission electron microscopy and electron energy-loss spectroscopy experiments on the recovered sample and computer simulations confirm its tetrahedral amorphous structure and complete sp 3 bonding. This transparent quenchable amorphous diamond has, to our knowledge, the highest density among amorphous carbon materials, and shows incompressibility comparable to crystalline diamond.
Related Topics
Concepts
Amorphous carbon
Materials science
Amorphous solid
Crystallinity
Diamond
Carbon fibers
Diamond-like carbon
Transmission electron microscopy
Glassy carbon
Diamond cubic
Nanotechnology
Chemical engineering
Crystallography
Composite material
Composite number
Chemistry
Thin film
Physical chemistry
Electrochemistry
Cyclic voltammetry
Engineering
Electrode
Metadata
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1038/s41467-017-00395-w
- OA Status
- gold
- Cited By
- 112
- References
- 44
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W2749642348
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W2749642348Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1038/s41467-017-00395-wDigital Object Identifier
- Title
-
Synthesis of quenchable amorphous diamondWork title
- Type
-
articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2017Year of publication
- Publication date
-
2017-08-14Full publication date if available
- Authors
-
Zhidan Zeng, Liuxiang Yang, Qiaoshi Zeng, Hongbo Lou, H. W. Sheng, Jianguo Wen, Dean J. Miller, Yue Meng, Wenge Yang, Wendy L. Mao, Ho‐kwang MaoList of authors in order
- Landing page
-
https://doi.org/10.1038/s41467-017-00395-wPublisher landing page
- Open access
-
YesWhether a free full text is available
- OA status
-
goldOpen access status per OpenAlex
- OA URL
-
https://doi.org/10.1038/s41467-017-00395-wDirect OA link when available
- Concepts
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Amorphous carbon, Materials science, Amorphous solid, Crystallinity, Diamond, Carbon fibers, Diamond-like carbon, Transmission electron microscopy, Glassy carbon, Diamond cubic, Nanotechnology, Chemical engineering, Crystallography, Composite material, Composite number, Chemistry, Thin film, Physical chemistry, Electrochemistry, Cyclic voltammetry, Engineering, ElectrodeTop concepts (fields/topics) attached by OpenAlex
- Cited by
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112Total citation count in OpenAlex
- Citations by year (recent)
-
2025: 23, 2024: 10, 2023: 8, 2022: 9, 2021: 21Per-year citation counts (last 5 years)
- References (count)
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44Number of works referenced by this work
- Related works (count)
-
10Other works algorithmically related by OpenAlex
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