Synthetic Strategies for the Selective Functionalization of Carbon Nanodots Allow Optically Communicating Suprastructures Article Swipe
Beatrice Bartolomei
,
Maria Sbacchi
,
Cristian Rosso
,
Ayse Günay‐Gürer
,
Lukáš Zdražil
,
Alejandro Cadranel
,
Slavko Kralj
,
Dirk M. Guldi
,
Maurizio Prato
·
YOU?
·
· 2023
· Open Access
·
· DOI: https://doi.org/10.1002/anie.202316915
YOU?
·
· 2023
· Open Access
·
· DOI: https://doi.org/10.1002/anie.202316915
The surface of Carbon Nanodots (CNDs) stands as a rich chemical platform, able to regulate the interactions between particles and external species. Performing selective functionalization of these nanoscale entities is of practical importance, however, it still represents a considerable challenge. In this work, we exploited the organic chemistry toolbox to install target functionalities on the CND surface, while monitoring the chemical changes on the material's outer shell through nuclear magnetic resonance spectroscopy. Following this, we investigated the use of click chemistry to covalently connect CNDs of different nature en‐route towards covalent suprastructures with unprecedent molecular control. The different photophysical properties of the connected particles allowed their optical communication in the excited state. This work paves the way for the development of selective and addressable CND building blocks which can act as modular nanoscale synthons that mirror the long‐established reactivity of molecular organic synthesis.
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- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1002/anie.202316915
- OA Status
- green
- Cited By
- 9
- References
- 46
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4389452767
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W4389452767Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1002/anie.202316915Digital Object Identifier
- Title
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Synthetic Strategies for the Selective Functionalization of Carbon Nanodots Allow Optically Communicating SuprastructuresWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2023Year of publication
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2023-12-08Full publication date if available
- Authors
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Beatrice Bartolomei, Maria Sbacchi, Cristian Rosso, Ayse Günay‐Gürer, Lukáš Zdražil, Alejandro Cadranel, Slavko Kralj, Dirk M. Guldi, Maurizio PratoList of authors in order
- Landing page
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https://doi.org/10.1002/anie.202316915Publisher landing page
- Open access
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YesWhether a free full text is available
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greenOpen access status per OpenAlex
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https://hdl.handle.net/11577/3533121Direct OA link when available
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Surface modification, Nanodot, Covalent bond, Nanotechnology, Nanoscopic scale, Materials science, Toolbox, Chemistry, Chemical engineering, Computer science, Organic chemistry, Engineering, Programming language, Physical chemistryTop concepts (fields/topics) attached by OpenAlex
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9Total citation count in OpenAlex
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2025: 5, 2024: 4Per-year citation counts (last 5 years)
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46Number of works referenced by this work
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10Other works algorithmically related by OpenAlex
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