TEMPERATURE-BASED REACTIVE FLOW MODEL FOR ANFO Article Swipe
Reaction rates depend on temperature as well as on the mechanical state. In shock wave initiation, experimental data almost always comprise mechanical measurements such as shock speed, material speed, compression, and pressure, and are accordingly modeled in terms of these parameters. Omission of temperature is one reason why mechanically based reaction rates do not extrapolate well out with the range of states used to normalize them. The model presented addresses chemical processes directly, enabling chemical kinetic data reported in terms of temperature (and at STP, generally) to be used in shock reaction models. We have recently extended a temperature-based model for use with ANFO-type formulations. Reactive material is treated as a heterogeneous mixture of components, each of which has its own model for response to dynamic loading (equation of state, strength model, reactions.) A finite-rate equilibration model is used to determine the overall response of the mixture to dynamic loading. In this model of ANFO, the ammonium nitrate and the fuel oil are treated as separate components in the unreacted mixture.
Related Topics
Concepts
Ammonium nitrate
Materials science
Shock (circulatory)
Thermodynamics
Chemical reaction
Mechanics
Kinetic energy
Reaction rate
Compression (physics)
Equation of state
Chemical kinetics
Composite material
Chemistry
Kinetics
Physical chemistry
Physics
Medicine
Quantum mechanics
Biochemistry
Catalysis
Internal medicine
Metadata
- Type
- paratext
- Language
- en
- Landing Page
- https://www.osti.gov/biblio/784476
- https://www.osti.gov/biblio/784476
- OA Status
- green
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W2565481154
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W2565481154Canonical identifier for this work in OpenAlex
- Title
-
TEMPERATURE-BASED REACTIVE FLOW MODEL FOR ANFOWork title
- Type
-
paratextOpenAlex work type
- Language
-
enPrimary language
- Publication year
-
2024Year of publication
- Publication date
-
2024-02-05Full publication date if available
- Authors
-
Roberta Mulford, Damian SwiftList of authors in order
- Landing page
-
https://www.osti.gov/biblio/784476Publisher landing page
- PDF URL
-
https://www.osti.gov/biblio/784476Direct link to full text PDF
- Open access
-
YesWhether a free full text is available
- OA status
-
greenOpen access status per OpenAlex
- OA URL
-
https://www.osti.gov/biblio/784476Direct OA link when available
- Concepts
-
Ammonium nitrate, Materials science, Shock (circulatory), Thermodynamics, Chemical reaction, Mechanics, Kinetic energy, Reaction rate, Compression (physics), Equation of state, Chemical kinetics, Composite material, Chemistry, Kinetics, Physical chemistry, Physics, Medicine, Quantum mechanics, Biochemistry, Catalysis, Internal medicineTop concepts (fields/topics) attached by OpenAlex
- Cited by
-
0Total citation count in OpenAlex
- Related works (count)
-
10Other works algorithmically related by OpenAlex
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| abstract_inverted_index.heterogeneous | 111 |
| abstract_inverted_index.temperature-based | 98 |
| cited_by_percentile_year | |
| countries_distinct_count | 0 |
| institutions_distinct_count | 2 |
| sustainable_development_goals[0].id | https://metadata.un.org/sdg/7 |
| sustainable_development_goals[0].score | 0.6100000143051147 |
| sustainable_development_goals[0].display_name | Affordable and clean energy |
| citation_normalized_percentile |