Template Synthesis, Metalation, and Self‐Assembly of Protic Gold(I)/(NHC)₂ Tectons Driven by Metallophilic Interactions Article Swipe

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Javier Ruiz , Lucía Garcı́a , Daniel Sol , Marilín Vivanco ·

YOU? · · 2016 · Open Access · · DOI: https://doi.org/10.1002/anie.201603688

A new protocol for the synthesis of protic bis(N‐heterocyclic carbene) complexes of Au I by a stepwise metal‐controlled coupling of isocyanide and propargylamine is described. They are used as tectons for the construction of supramolecular architectures through metalation and self‐assembly. Notably a unique polymeric chain of Cu I with alternate Au I /bis(imidazolate) bridging scaffolds and strong unsupported Cu I –Cu I interactions has been generated, as well as a 28‐metal‐atoms cluster containing a nanopiece of Cu 2 O trapped by peripheral Au I /bis(imidazolate) moieties.

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Metalation Self-assembly Crystallography Chemistry Stereochemistry Nanotechnology Materials science

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Type: article
Language: en
Landing Page: https://doi.org/10.1002/anie.201603688
OA Status: green
Cited By: 18
References: 58
Related Works: 10
OpenAlex ID: https://openalex.org/W2465202786

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DOI: https://doi.org/10.1002/anie.201603688

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Title: Template Synthesis, Metalation, and Self‐Assembly of Protic Gold(I)/(NHC)₂ Tectons Driven by Metallophilic Interactions

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Language: en

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Publication year: 2016

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Publication date: 2016-06-06

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Authors: Javier Ruiz, Lucía Garcı́a, Daniel Sol, Marilín Vivanco

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Landing page: https://doi.org/10.1002/anie.201603688

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Concepts: Metalation, Self-assembly, Crystallography, Chemistry, Stereochemistry, Nanotechnology, Materials science

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Cited by: 18

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Template Synthesis, Metalation, and Self‐Assembly of Protic Gold(I)/(NHC)2 Tectons Driven by Metallophilic Interactions Article Swipe

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Template Synthesis, Metalation, and Self‐Assembly of Protic Gold(I)/(NHC)₂ Tectons Driven by Metallophilic Interactions Article Swipe