β-Terrecyclene synthase constructs the quadrane backbone in terrecyclic acid biosynthesis Article Swipe
Related Concepts
Biosynthesis
ATP synthase
Chemistry
Biochemistry
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Enzyme
Yongxiang Song
,
Wengui Wang
,
Jiafan Yang
,
De‐Wei Gao
,
John M. Billingsley
,
Songtao Wang
,
Yiguang Zhu
,
Junfeng Wang
,
Jianhua Ju
,
Yan Yan
,
Yi Tang
·
YOU?
·
· 2024
· Open Access
·
· DOI: https://doi.org/10.1039/d4sc01208a
· OA: W4395478453
YOU?
·
· 2024
· Open Access
·
· DOI: https://doi.org/10.1039/d4sc01208a
· OA: W4395478453
The construction of a quadrane scaffold by β-terrecyclene synthase via Coates' route is demonstrated through mutagenesis and isotopically sensitive branching studies. Subsequent enzymatic modifications convert β-terrecyclene into terrecyclic acid.
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