The application of alumina supported Pd catalysts for high selectivity aniline synthesis catalysis at elevated temperatures: Site-selective chemistry Article Swipe
J.W. Campbell
,
Annelouise M. McCullagh
,
Lucas K. McGrath
,
Colin How
,
Donald A. MacLaren
,
M. Loenders
,
N. Meyer
,
R. H. Carr
,
David Lennon
·
YOU?
·
· 2023
· Open Access
·
· DOI: https://doi.org/10.1016/j.apcata.2023.119541
YOU?
·
· 2023
· Open Access
·
· DOI: https://doi.org/10.1016/j.apcata.2023.119541
The industrial scale heterogeneously catalysed hydrogenation of nitrobenzene to produce aniline is ideally suited to the incorporation of heat recovery strategies. However, a range of by-products may be observed. Thus, discerning the origins of by-product formation is crucial for developing targeted prototype catalysts. This paper examines by-product formation at elevated reaction temperatures over a previously untested low loading alumina-supported Pd (0.3 wt%) industrial grade prototype aniline synthesis catalyst in the vapour and liquid phase. Infrared spectroscopy of chemisorbed CO is used to evaluate the Pd crystallite morphology. Importantly, the morphology is seen to differ from other previously analysed 0.3 wt% Pd/Al2O3 catalyst samples. Post-reaction (vapour phase) analysis of the catalyst identifies carbon laydown to preferentially neutralise Pd(100) sites. An inter-relationship is proposed via observed nitrobenzene hydrogenation chemistry and crystallite morphology, such that specific reactions are associated with specific planes of the Pd crystallites of this Pd/Al2O3 catalyst.
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- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1016/j.apcata.2023.119541
- https://ars.els-cdn.com/content/image/1-s2.0-S0926860X23005215-ga1_lrg.jpg
- OA Status
- hybrid
- Cited By
- 7
- References
- 19
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4389687908
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Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W4389687908Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1016/j.apcata.2023.119541Digital Object Identifier
- Title
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The application of alumina supported Pd catalysts for high selectivity aniline synthesis catalysis at elevated temperatures: Site-selective chemistryWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2023Year of publication
- Publication date
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2023-12-13Full publication date if available
- Authors
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J.W. Campbell, Annelouise M. McCullagh, Lucas K. McGrath, Colin How, Donald A. MacLaren, M. Loenders, N. Meyer, R. H. Carr, David LennonList of authors in order
- Landing page
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https://doi.org/10.1016/j.apcata.2023.119541Publisher landing page
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https://ars.els-cdn.com/content/image/1-s2.0-S0926860X23005215-ga1_lrg.jpgDirect link to full text PDF
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YesWhether a free full text is available
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hybridOpen access status per OpenAlex
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https://ars.els-cdn.com/content/image/1-s2.0-S0926860X23005215-ga1_lrg.jpgDirect OA link when available
- Concepts
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Nitrobenzene, Aniline, Chemistry, Catalysis, Crystallite, Selectivity, Heterogeneous catalysis, Chemical engineering, Inorganic chemistry, Organic chemistry, Crystallography, EngineeringTop concepts (fields/topics) attached by OpenAlex
- Cited by
-
7Total citation count in OpenAlex
- Citations by year (recent)
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2025: 2, 2024: 5Per-year citation counts (last 5 years)
- References (count)
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19Number of works referenced by this work
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10Other works algorithmically related by OpenAlex
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