The Feasibility Study of In Situ Conversion of Oil Shale Based on Calcium-Oxide-Based Composite Materia Hydration Exothermic Reaction Article Swipe
Shiwei Ma
,
Shouding Li
,
Zhaobin Zhang
,
Tao Xu
,
Bo Zheng
,
Yanzhi Hu
,
Guanfang Li
,
Xiao Li
·
YOU?
·
· 2024
· Open Access
·
· DOI: https://doi.org/10.3390/en17081798
YOU?
·
· 2024
· Open Access
·
· DOI: https://doi.org/10.3390/en17081798
Oil shale, as a vast potential resource, is considered an important alternative energy source, and its effective development and economic utilization are of significant importance in alleviating the contradiction between energy supply and demand. Presently, the in situ conversion technology for oil shale has gained significant global attention, with numerous extraction methods undergoing active research and development. One of these methods is the in situ conversion of oil shale based on the hydration reaction of calcium-oxide-based composite material (CaO-CM). This approach harnesses the heat produced by the reaction between CaO-CM and water as a heat source for the pyrolysis of oil shale. This paper conducted experiments to assess the feasibility of temperature associated with this method. The feasibility study mainly includes two aspects: First, it is necessary to investigate whether the temperature generated by the hydration reaction of CaO-CM can meet the temperature requirements for the pyrolysis of oil shale. Through pyrolysis experiments of Xinjiang oil shale, the minimum temperature required for oil shale pyrolysis was determined to be 330 °C. High-temperature and high-pressure reaction vessels were employed to explore the temperature generated by the hydration reaction of CaO-CM. The results show that with the increase in environment pressure, environment temperature, and reaction mass, the maximum temperature generated by the hydration reaction of CaO-CM also increases (reach 455.5 °C), meeting the temperature requirements for the pyrolysis of oil shale. Second, the study evaluates whether the hydration reaction of CaO-CM can induce pyrolysis hydrocarbons of the oil shale. Through the pyrolysis experiments of oil shale based on the hydration reaction of CaO-CM, the changes in the content of pyrolysis hydrocarbons (S2) in oil shale before and after pyrolysis are measured. The results show that under 10 MPa pressure, the content of pyrolysis hydrocarbons in the oil shale decreased from 40.96 mg/g to 0.08 mg/g after pyrolysis. This confirms the feasibility of the temperature conditions for the in situ conversion of oil shale based on the hydration reaction of CaO-CM.
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- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.3390/en17081798
- https://www.mdpi.com/1996-1073/17/8/1798/pdf?version=1712659525
- OA Status
- gold
- Cited By
- 2
- References
- 19
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4394605221
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W4394605221Canonical identifier for this work in OpenAlex
- DOI
-
https://doi.org/10.3390/en17081798Digital Object Identifier
- Title
-
The Feasibility Study of In Situ Conversion of Oil Shale Based on Calcium-Oxide-Based Composite Materia Hydration Exothermic ReactionWork title
- Type
-
articleOpenAlex work type
- Language
-
enPrimary language
- Publication year
-
2024Year of publication
- Publication date
-
2024-04-09Full publication date if available
- Authors
-
Shiwei Ma, Shouding Li, Zhaobin Zhang, Tao Xu, Bo Zheng, Yanzhi Hu, Guanfang Li, Xiao LiList of authors in order
- Landing page
-
https://doi.org/10.3390/en17081798Publisher landing page
- PDF URL
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https://www.mdpi.com/1996-1073/17/8/1798/pdf?version=1712659525Direct link to full text PDF
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YesWhether a free full text is available
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goldOpen access status per OpenAlex
- OA URL
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https://www.mdpi.com/1996-1073/17/8/1798/pdf?version=1712659525Direct OA link when available
- Concepts
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Oil shale, Pyrolysis, Calcium oxide, Exothermic reaction, Petroleum engineering, Oxide, Shale oil, Chemical engineering, Materials science, Waste management, Environmental science, Mineralogy, Chemistry, Geology, Metallurgy, Organic chemistry, EngineeringTop concepts (fields/topics) attached by OpenAlex
- Cited by
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2Total citation count in OpenAlex
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2024: 2Per-year citation counts (last 5 years)
- References (count)
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19Number of works referenced by this work
- Related works (count)
-
10Other works algorithmically related by OpenAlex
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| abstract_inverted_index.method. | 115 |
| abstract_inverted_index.methods | 51, 60 |
| abstract_inverted_index.minimum | 158 |
| abstract_inverted_index.results | 190, 280 |
| abstract_inverted_index.source, | 13 |
| abstract_inverted_index.vessels | 175 |
| abstract_inverted_index.whether | 129, 233 |
| abstract_inverted_index.Xinjiang | 154 |
| abstract_inverted_index.approach | 80 |
| abstract_inverted_index.aspects: | 122 |
| abstract_inverted_index.confirms | 306 |
| abstract_inverted_index.economic | 19 |
| abstract_inverted_index.employed | 177 |
| abstract_inverted_index.includes | 120 |
| abstract_inverted_index.increase | 195 |
| abstract_inverted_index.material | 77 |
| abstract_inverted_index.numerous | 49 |
| abstract_inverted_index.produced | 84 |
| abstract_inverted_index.reaction | 73, 87, 136, 174, 186, 202, 211, 236, 258, 325 |
| abstract_inverted_index.required | 160 |
| abstract_inverted_index.research | 54 |
| abstract_inverted_index.(CaO-CM). | 78 |
| abstract_inverted_index.composite | 76 |
| abstract_inverted_index.conducted | 104 |
| abstract_inverted_index.decreased | 296 |
| abstract_inverted_index.effective | 16 |
| abstract_inverted_index.evaluates | 232 |
| abstract_inverted_index.generated | 132, 182, 207 |
| abstract_inverted_index.harnesses | 81 |
| abstract_inverted_index.hydration | 72, 135, 185, 210, 235, 257, 324 |
| abstract_inverted_index.important | 10 |
| abstract_inverted_index.increases | 215 |
| abstract_inverted_index.measured. | 278 |
| abstract_inverted_index.necessary | 126 |
| abstract_inverted_index.potential | 5 |
| abstract_inverted_index.pressure, | 198, 286 |
| abstract_inverted_index.pyrolysis | 98, 146, 151, 164, 225, 241, 249, 267, 276, 290 |
| abstract_inverted_index.resource, | 6 |
| abstract_inverted_index.Presently, | 34 |
| abstract_inverted_index.associated | 112 |
| abstract_inverted_index.attention, | 47 |
| abstract_inverted_index.conditions | 312 |
| abstract_inverted_index.considered | 8 |
| abstract_inverted_index.conversion | 38, 65, 317 |
| abstract_inverted_index.determined | 166 |
| abstract_inverted_index.extraction | 50 |
| abstract_inverted_index.importance | 24 |
| abstract_inverted_index.pyrolysis. | 304 |
| abstract_inverted_index.technology | 39 |
| abstract_inverted_index.undergoing | 52 |
| abstract_inverted_index.alleviating | 26 |
| abstract_inverted_index.alternative | 11 |
| abstract_inverted_index.development | 17 |
| abstract_inverted_index.environment | 197, 199 |
| abstract_inverted_index.experiments | 105, 152, 250 |
| abstract_inverted_index.feasibility | 109, 117, 308 |
| abstract_inverted_index.investigate | 128 |
| abstract_inverted_index.significant | 23, 45 |
| abstract_inverted_index.temperature | 111, 131, 142, 159, 181, 206, 221, 311 |
| abstract_inverted_index.utilization | 20 |
| abstract_inverted_index.development. | 56 |
| abstract_inverted_index.hydrocarbons | 242, 268, 291 |
| abstract_inverted_index.requirements | 143, 222 |
| abstract_inverted_index.temperature, | 200 |
| abstract_inverted_index.contradiction | 28 |
| abstract_inverted_index.high-pressure | 173 |
| abstract_inverted_index.High-temperature | 171 |
| abstract_inverted_index.calcium-oxide-based | 75 |
| cited_by_percentile_year.max | 96 |
| cited_by_percentile_year.min | 94 |
| corresponding_author_ids | https://openalex.org/A5042626421 |
| countries_distinct_count | 1 |
| institutions_distinct_count | 8 |
| corresponding_institution_ids | https://openalex.org/I19820366, https://openalex.org/I4210126061, https://openalex.org/I4210165038 |
| citation_normalized_percentile.value | 0.64331472 |
| citation_normalized_percentile.is_in_top_1_percent | False |
| citation_normalized_percentile.is_in_top_10_percent | False |