The sintering and dielectric properties modification of Li2MgSiO4 ceramic with Ni2+-ion doping based on calculation and experiment Article Swipe
YOU?
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· 2019
· Open Access
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· DOI: https://doi.org/10.1016/j.jmrt.2019.11.061
The microwave dielectric properties and sintering behavior of Li2(Mg1-xNix)SiO4 (x = 0.00–0.10) ceramics were researched with the help of first principle calculation and solid-state reaction experiment. The crystal structure, electron density, and formation energy were obtained through the density functional theory. The X-ray diffraction, scanning electron microscopy, energy-dispersive X-ray spectroscopy, and Network Analyzer were used in this study. The substitution of Ni2+-ion to Mg2+-ion could lower the densification temperature from 1250 °C to 1150 °C and improve the microwave dielectric properties of composite ceramics, demonstrated by the result of lattice parameters, bond population, electron density, and microstructure. A peak dielectric property of Li2(Mg1-xNix)SiO4 (x = 0.00-0.10) ceramics was achieved when x = 0.04 (εr = 5.69, Q×f = 28,448 GHz at 16 GHz, τf = −15.3 ppm/ °C) sintered at 1150 °C. Besides, LBBS glass was used as the sintering aid to lower the densification temperature from 1150℃ down to 900℃. The Li2(Mg0.96Ni0.04)SiO4 ceramic with 2 wt% LBBS sintered at 900 °C obtained excellent microwave dielectric properties, εr = 5.89, Q×f = 29,320 GHz (at 16 GHz), τf = −13.8 ppm/°C, and there was no chemical reaction between the composite ceramics and Ag. It’s a promising material for the applications of the millimeter-wave devices in the field of low temperature co-fired ceramics. Keywords: Low dielectric constant, LTCC, Microwave dielectric properties, DFT
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- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1016/j.jmrt.2019.11.061
- OA Status
- gold
- Cited By
- 47
- References
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- Related Works
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- OpenAlex ID
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Raw OpenAlex JSON
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https://openalex.org/W2993408044Canonical identifier for this work in OpenAlex
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https://doi.org/10.1016/j.jmrt.2019.11.061Digital Object Identifier
- Title
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The sintering and dielectric properties modification of Li2MgSiO4 ceramic with Ni2+-ion doping based on calculation and experimentWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2019Year of publication
- Publication date
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2019-12-06Full publication date if available
- Authors
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Rui Peng, Hua Su, Di An, Yongcheng Lu, Zhihua Tao, Daming Chen, Liang Shi, Yuanxun LiList of authors in order
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https://doi.org/10.1016/j.jmrt.2019.11.061Publisher landing page
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YesWhether a free full text is available
- OA status
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goldOpen access status per OpenAlex
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https://doi.org/10.1016/j.jmrt.2019.11.061Direct OA link when available
- Concepts
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Materials science, Sintering, Ceramic, Dielectric, Microstructure, Scanning electron microscope, Analytical Chemistry (journal), Ion, Doping, Mineralogy, Composite material, Optoelectronics, Physics, Chemistry, Chromatography, Quantum mechanicsTop concepts (fields/topics) attached by OpenAlex
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47Total citation count in OpenAlex
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2025: 5, 2024: 5, 2023: 5, 2022: 5, 2021: 19Per-year citation counts (last 5 years)
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31Number of works referenced by this work
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10Other works algorithmically related by OpenAlex
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