The transition from used fuel container corrosion under oxic conditions to corrosion in an anoxic environment Article Swipe
YOU?
·
· 2023
· Open Access
·
· DOI: https://doi.org/10.1002/maco.202313757
The conversion of copper oxide films on copper to copper sulfide has been investigated in sulfide‐containing chloride solutions. Single‐phase Cu 2 O films and duplex films consisting of Cu 2 O and CuO, and possibly Cu(OH) 2 , were prepared electrochemically on copper specimens at various applied potentials and characterized using Raman spectroscopy, scanning electron microscopy, and energy dispersive X‐ray analyses. The surface condition of the specimens subsequently exposed to a solution containing sulfide was monitored by measuring the corrosion potential ( E corr ) for various exposure periods, then cathodic stripping voltammetry was performed. Cuprite (Cu 2 O) was observed to be converted to Cu 2 S by chemical reaction with sulfide, while the conversion mechanism for the mixed deposit could comprise a galvanic process involving Cu II reduction coupled to the formation of Cu 2 S by the reaction of sulfide with copper within pores in the Cu 2 O/CuO surface film and a chemical conversion of Cu 2 O to Cu 2 S. Cupric hydroxide was not converted to Cu 2 S on the time scale (24 h) of these experiments.
Related Topics
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1002/maco.202313757
- https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/maco.202313757
- OA Status
- bronze
- Cited By
- 13
- References
- 32
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4387138759
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W4387138759Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1002/maco.202313757Digital Object Identifier
- Title
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The transition from used fuel container corrosion under oxic conditions to corrosion in an anoxic environmentWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2023Year of publication
- Publication date
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2023-09-27Full publication date if available
- Authors
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Elham Salehi Alaei, Mengnan Guo, Jian Chen, Mehran Behazin, Erik Bergendal, Christina Lilja, David W. Shoesmith, James J. NoëlList of authors in order
- Landing page
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https://doi.org/10.1002/maco.202313757Publisher landing page
- PDF URL
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https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/maco.202313757Direct link to full text PDF
- Open access
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YesWhether a free full text is available
- OA status
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bronzeOpen access status per OpenAlex
- OA URL
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https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/maco.202313757Direct OA link when available
- Concepts
-
Sulfide, Copper, Corrosion, Inorganic chemistry, Oxide, Covellite, Cuprite, Cyclic voltammetry, Copper sulfide, Materials science, Scanning electron microscope, Hydroxide, Electrochemistry, Chemistry, Metallurgy, Chalcopyrite, Electrode, Composite material, Physical chemistryTop concepts (fields/topics) attached by OpenAlex
- Cited by
-
13Total citation count in OpenAlex
- Citations by year (recent)
-
2025: 7, 2024: 6Per-year citation counts (last 5 years)
- References (count)
-
32Number of works referenced by this work
- Related works (count)
-
10Other works algorithmically related by OpenAlex
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