The Use of Electrochemical Methods to Determine the Effect of Nitrides of Alloying Elements on the Electrochemical Properties of Titanium β-Alloys Article Swipe
Jitřenka Jírů
,
Vojtěch Hybášek
,
Petr Vlčák
,
Jaroslav Fojt
·
YOU?
·
· 2023
· Open Access
·
· DOI: https://doi.org/10.3390/ijms24021656
YOU?
·
· 2023
· Open Access
·
· DOI: https://doi.org/10.3390/ijms24021656
Titanium beta alloys represent the new generation of materials for the manufacturing of joint implants. Their Young’s modulus is lower and thus closer to the bone tissue compared to commonly used alloys. The surface tribological properties of these materials should be improved by ion implantation. The influence of this surface treatment on corrosion behaviour is unknown. The surface of Ti-36Nb-6Ta, Ti-36Nb-4Zr, and Ti-39Nb titanium β-alloys was modified using nitrogen ion implantation. X-ray photoelectron spectroscopy was used for surface analysis, which showed the presence of titanium, niobium, and tantalum nitrides in the treated samples and the elimination of less stable oxides. Electrochemical methods, electrochemical impedance spectra, polarisation resistance, and Mott–Schottky plot were measured in a physiological saline solution. The results of the measurements showed that ion implantation does not have a significant negative effect on the corrosion behaviour of the material. The best results of the alloys investigated were achieved by the Ti-36Nb-6Ta alloy. The combination of niobium and tantalum nitrides had a positive effect on the corrosion resistance of this alloy. After surface treatment, the polarization resistance of this alloy increased, 2.3 × 106 Ω·cm2, demonstrating higher corrosion resistance of the alloy. These results were also supported by the results of electrochemical impedance spectroscopy.
Related Topics
Concepts
Materials science
Corrosion
Niobium
Dielectric spectroscopy
Titanium
Alloy
Titanium alloy
Nitride
Metallurgy
X-ray photoelectron spectroscopy
Tantalum
Electrochemistry
Polarization (electrochemistry)
Ion implantation
Surface modification
Chemical engineering
Ion
Composite material
Electrode
Chemistry
Physical chemistry
Organic chemistry
Engineering
Layer (electronics)
Metadata
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.3390/ijms24021656
- https://www.mdpi.com/1422-0067/24/2/1656/pdf?version=1674090902
- OA Status
- gold
- Cited By
- 2
- References
- 54
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4316371976
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
-
https://openalex.org/W4316371976Canonical identifier for this work in OpenAlex
- DOI
-
https://doi.org/10.3390/ijms24021656Digital Object Identifier
- Title
-
The Use of Electrochemical Methods to Determine the Effect of Nitrides of Alloying Elements on the Electrochemical Properties of Titanium β-AlloysWork title
- Type
-
articleOpenAlex work type
- Language
-
enPrimary language
- Publication year
-
2023Year of publication
- Publication date
-
2023-01-14Full publication date if available
- Authors
-
Jitřenka Jírů, Vojtěch Hybášek, Petr Vlčák, Jaroslav FojtList of authors in order
- Landing page
-
https://doi.org/10.3390/ijms24021656Publisher landing page
- PDF URL
-
https://www.mdpi.com/1422-0067/24/2/1656/pdf?version=1674090902Direct link to full text PDF
- Open access
-
YesWhether a free full text is available
- OA status
-
goldOpen access status per OpenAlex
- OA URL
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https://www.mdpi.com/1422-0067/24/2/1656/pdf?version=1674090902Direct OA link when available
- Concepts
-
Materials science, Corrosion, Niobium, Dielectric spectroscopy, Titanium, Alloy, Titanium alloy, Nitride, Metallurgy, X-ray photoelectron spectroscopy, Tantalum, Electrochemistry, Polarization (electrochemistry), Ion implantation, Surface modification, Chemical engineering, Ion, Composite material, Electrode, Chemistry, Physical chemistry, Organic chemistry, Engineering, Layer (electronics)Top concepts (fields/topics) attached by OpenAlex
- Cited by
-
2Total citation count in OpenAlex
- Citations by year (recent)
-
2025: 2Per-year citation counts (last 5 years)
- References (count)
-
54Number of works referenced by this work
- Related works (count)
-
10Other works algorithmically related by OpenAlex
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