Theory of electron spin resonance in scanning tunneling microscopy Article Swipe
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· 2024
· Open Access
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· DOI: https://doi.org/10.1103/physrevresearch.6.023126
Electron spin resonance (ESR) spectroscopy in scanning tunneling microscopy (STM) has enabled probing the electronic structure of single magnetic atoms and molecules on surfaces with unprecedented energy resolution, as well as demonstrating coherent manipulation of single spins. Despite this remarkable success, the field could still be greatly advanced by a more quantitative understanding of the ESR-STM physical mechanisms. Here, we present a theory of ESR-STM that quantitatively models not only the ESR signal itself, but also the full background tunneling current, from which the ESR signal is derived. Our theory is based on a combination of Green's function techniques to describe the electron tunneling and a quantum master equation for the dynamics of the spin system along with microwave radiation interacting with both the tunneling current and the magnetic system. We show that this theory is able to quantitatively reproduce the experimental results for a spin-1/2 system (TiH molecules on MgO) across many orders of magnitude in tunneling current, providing access to the relaxation and decoherence rates that govern the spin dynamics due to intrinsic mechanisms and to the applied bias voltage. More importantly, our work establishes that (i) sizable ESR signals, which are a measure of microwave-induced changes in the junction magnetoresistance, require surprisingly high tip spin polarizations, and (ii) the coupling of the magnetization dynamics to the microwave field gives rise to the asymmetric ESR spectra often observed in this spectroscopy. Additionally, our theory provides very specific predictions for the dependence of the relaxation and decoherence times on the bias voltage and the tip-sample distance. Finally, with the help of electromagnetic simulations, we find that the transitions in our ESR-STM experiments, in which the tunnel junction is irradiated by a nearby microwave antenna, can be driven by the ac magnetic field at the junction. Published by the American Physical Society 2024
Related Topics
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1103/physrevresearch.6.023126
- http://link.aps.org/pdf/10.1103/PhysRevResearch.6.023126
- OA Status
- gold
- Cited By
- 10
- References
- 68
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4396673374
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W4396673374Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1103/physrevresearch.6.023126Digital Object Identifier
- Title
-
Theory of electron spin resonance in scanning tunneling microscopyWork title
- Type
-
articleOpenAlex work type
- Language
-
enPrimary language
- Publication year
-
2024Year of publication
- Publication date
-
2024-05-06Full publication date if available
- Authors
-
Christian R. Ast, Piotr Kot, Maneesha Ismail, Sebastián de-la-Peña, Antonio I. Fernández‐Domínguez, Juan Carlos CuevasList of authors in order
- Landing page
-
https://doi.org/10.1103/physrevresearch.6.023126Publisher landing page
- PDF URL
-
https://link.aps.org/pdf/10.1103/PhysRevResearch.6.023126Direct link to full text PDF
- Open access
-
YesWhether a free full text is available
- OA status
-
goldOpen access status per OpenAlex
- OA URL
-
https://link.aps.org/pdf/10.1103/PhysRevResearch.6.023126Direct OA link when available
- Concepts
-
Scanning tunneling microscope, Electron, Spin polarized scanning tunneling microscopy, Scanning tunneling spectroscopy, Quantum tunnelling, Spin (aerodynamics), Resonance (particle physics), Condensed matter physics, Electron paramagnetic resonance, Physics, Microscopy, Nuclear magnetic resonance, Materials science, Atomic physics, Optics, Quantum mechanics, ThermodynamicsTop concepts (fields/topics) attached by OpenAlex
- Cited by
-
10Total citation count in OpenAlex
- Citations by year (recent)
-
2025: 7, 2024: 3Per-year citation counts (last 5 years)
- References (count)
-
68Number of works referenced by this work
- Related works (count)
-
10Other works algorithmically related by OpenAlex
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