Thermodynamic Insights of the Molecular Interactions of Dopamine (Neurotransmitter) with Anionic Surfactant in Non-Aqueous Media Article Swipe
Arshid Nabi
,
Christopher G. Jesudason
,
Jamal S. M. Sabir
,
Majid Rasool Kamli
·
YOU?
·
· 2023
· Open Access
·
· DOI: https://doi.org/10.3390/ph16091187
YOU?
·
· 2023
· Open Access
·
· DOI: https://doi.org/10.3390/ph16091187
This study was aimed at establishing the interactions prevailing in an anionic surfactant, sodium dodecyl sulfate, and dopamine hydrochloride in an alcoholic (ethanol) media by using volumetric, conductometric, and tensiometric techniques. Various methods were utilized to estimate the critical micelle concentration (cmc) values at different temperatures. The entire methods yielded the same cmc values. The corresponding thermodynamic parameters viz. the standard free energy of micellization (Gmico), enthalpy of micellization (Hmico), and entropy of micellization (Smico) were predicted by applying the pseudo-phase separation model. The experimental density data at different temperatures (298.15 K, 303.15 K, 308.15 K, and 313.15 K) were utilized to estimate the apparent molar volumes (Vϕo) at an infinite dilution, apparent molar volumes (Vφcmc) at the critical micelle concentration, and apparent molar volumes (ΔVφm) upon micellization. Various micellar and interfacial parameters, for example, the surface excess concentration (Γmax), standard Gibbs free energy of adsorption at the interface (ΔGoad), and the minimum surface area per molecule (Amin), were appraised using the surface tension data. The results were used to interpret the intermolecular interactions prevailing in the mixed systems under the specified experimental conditions.
Related Topics
Concepts
Gibbs free energy
Critical micelle concentration
Standard molar entropy
Chemistry
Thermodynamics of micellization
Gibbs isotherm
Enthalpy
Pulmonary surfactant
Thermodynamics
Surface tension
Micelle
Sodium dodecyl sulfate
Aqueous solution
Intermolecular force
Adsorption
Physical chemistry
Standard enthalpy of formation
Chromatography
Molecule
Organic chemistry
Biochemistry
Physics
Metadata
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.3390/ph16091187
- https://www.mdpi.com/1424-8247/16/9/1187/pdf?version=1692668367
- OA Status
- gold
- Cited By
- 2
- References
- 69
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4386050148
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W4386050148Canonical identifier for this work in OpenAlex
- DOI
-
https://doi.org/10.3390/ph16091187Digital Object Identifier
- Title
-
Thermodynamic Insights of the Molecular Interactions of Dopamine (Neurotransmitter) with Anionic Surfactant in Non-Aqueous MediaWork title
- Type
-
articleOpenAlex work type
- Language
-
enPrimary language
- Publication year
-
2023Year of publication
- Publication date
-
2023-08-22Full publication date if available
- Authors
-
Arshid Nabi, Christopher G. Jesudason, Jamal S. M. Sabir, Majid Rasool KamliList of authors in order
- Landing page
-
https://doi.org/10.3390/ph16091187Publisher landing page
- PDF URL
-
https://www.mdpi.com/1424-8247/16/9/1187/pdf?version=1692668367Direct link to full text PDF
- Open access
-
YesWhether a free full text is available
- OA status
-
goldOpen access status per OpenAlex
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https://www.mdpi.com/1424-8247/16/9/1187/pdf?version=1692668367Direct OA link when available
- Concepts
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Gibbs free energy, Critical micelle concentration, Standard molar entropy, Chemistry, Thermodynamics of micellization, Gibbs isotherm, Enthalpy, Pulmonary surfactant, Thermodynamics, Surface tension, Micelle, Sodium dodecyl sulfate, Aqueous solution, Intermolecular force, Adsorption, Physical chemistry, Standard enthalpy of formation, Chromatography, Molecule, Organic chemistry, Biochemistry, PhysicsTop concepts (fields/topics) attached by OpenAlex
- Cited by
-
2Total citation count in OpenAlex
- Citations by year (recent)
-
2025: 2Per-year citation counts (last 5 years)
- References (count)
-
69Number of works referenced by this work
- Related works (count)
-
10Other works algorithmically related by OpenAlex
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