Tip-Induced Nitrene Generation Article Swipe
Leonard-Alexander Lieske
,
Aaron H. Oechsle
,
Igor Rončević
,
Ilias Gazizullin
,
Florian Albrecht
,
Matthias Krinninger
,
Leonhard Grill
,
Friedrich Esch
,
Leo Groß
·
YOU?
·
· 2025
· Open Access
·
· DOI: https://doi.org/10.1021/acsnano.5c08710
YOU?
·
· 2025
· Open Access
·
· DOI: https://doi.org/10.1021/acsnano.5c08710
We generated trinitreno-s-heptazine, a small molecule featuring three nitrene centers, by tip-induced chemistry from the precursor 2,5,8-triazido-s-heptazine on bilayer NaCl on Au(111). The precursor's azide groups were dissociated to form mono-, di- and trinitreno-s-heptazine, yielding molecules with one to three nitrene centers. The precursor and its products are characterized by atomic force microscopy and scanning tunnelling microscopy. Broken-symmetry DFT and configuration interaction calculations of inter-nitrene and intra-nitrene exchange couplings suggest a ferromagnetic coupling of the S = 1 nitrene centers, resulting in a high-spin septet ground state for neutral trinitreno-s-heptazine in the gas phase. On bilayer NaCl on Au(111), the combined results of experiments and theory suggest trinitreno-s-heptazine to be an anion with a sextet ground state.
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- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1021/acsnano.5c08710
- https://pubs.acs.org/doi/pdf/10.1021/acsnano.5c08710?ref=article_openPDF
- OA Status
- hybrid
- Cited By
- 1
- References
- 116
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4413786424
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- OpenAlex ID
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https://openalex.org/W4413786424Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1021/acsnano.5c08710Digital Object Identifier
- Title
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Tip-Induced Nitrene GenerationWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2025Year of publication
- Publication date
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2025-08-28Full publication date if available
- Authors
-
Leonard-Alexander Lieske, Aaron H. Oechsle, Igor Rončević, Ilias Gazizullin, Florian Albrecht, Matthias Krinninger, Leonhard Grill, Friedrich Esch, Leo GroßList of authors in order
- Landing page
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https://doi.org/10.1021/acsnano.5c08710Publisher landing page
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https://pubs.acs.org/doi/pdf/10.1021/acsnano.5c08710?ref=article_openPDFDirect link to full text PDF
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YesWhether a free full text is available
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hybridOpen access status per OpenAlex
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https://pubs.acs.org/doi/pdf/10.1021/acsnano.5c08710?ref=article_openPDFDirect OA link when available
- Concepts
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Nitrene, Scanning tunneling microscope, Bilayer, Chemical physics, Chemistry, Molecule, Materials science, Crystallography, Nanotechnology, Photochemistry, Membrane, Organic chemistry, Catalysis, BiochemistryTop concepts (fields/topics) attached by OpenAlex
- Cited by
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1Total citation count in OpenAlex
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2025: 1Per-year citation counts (last 5 years)
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116Number of works referenced by this work
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10Other works algorithmically related by OpenAlex
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