Topology-Controlled Self-Assembly of Amphiphilic Block Copolymers Article Swipe
YOU?
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· 2023
· Open Access
·
· DOI: https://doi.org/10.26434/chemrxiv-2023-1vw27-v2
Contemporary synthetic chemistry approaches can be used to yield a range of distinct polymer topologies with precise control. The topology of a polymer strongly influences its self-assembly into complex nanostructures however a clear mechanistic understanding of the relationship between polymer topology and self-assembly has not yet been developed. In this work, we use atomistic molecular dynamics simulations to provide a nanoscale picture of the self-assembly of three poly(ethylene oxide)-poly(methyl acrylate) block copolymers with different topologies into micelles. We find that the topology affects the ability of the micelle to form a compact hydrophobic core, which directly affects its stability. Also, we apply unsupervised machine learning techniques to show that the topology of a polymer affects its ability to take a conformation in response to the local environment within the micelles. This work provides foundations for the rational design of polymer nanostructures based on their underlying topology.
Related Topics
- Type
- preprint
- Language
- en
- Landing Page
- https://doi.org/10.26434/chemrxiv-2023-1vw27-v2
- https://chemrxiv.org/engage/api-gateway/chemrxiv/assets/orp/resource/item/63ebabaefcfb27a31fc7a64a/original/topology-controlled-self-assembly-of-amphiphilic-block-copolymers.pdf
- OA Status
- gold
- Cited By
- 2
- References
- 35
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4320922394
Raw OpenAlex JSON
- OpenAlex ID
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https://openalex.org/W4320922394Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.26434/chemrxiv-2023-1vw27-v2Digital Object Identifier
- Title
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Topology-Controlled Self-Assembly of Amphiphilic Block CopolymersWork title
- Type
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preprintOpenAlex work type
- Language
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enPrimary language
- Publication year
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2023Year of publication
- Publication date
-
2023-02-15Full publication date if available
- Authors
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Raquel López-Ríos de Castro, Robert M. Ziolek, Christian D. LorenzList of authors in order
- Landing page
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https://doi.org/10.26434/chemrxiv-2023-1vw27-v2Publisher landing page
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https://chemrxiv.org/engage/api-gateway/chemrxiv/assets/orp/resource/item/63ebabaefcfb27a31fc7a64a/original/topology-controlled-self-assembly-of-amphiphilic-block-copolymers.pdfDirect link to full text PDF
- Open access
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YesWhether a free full text is available
- OA status
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goldOpen access status per OpenAlex
- OA URL
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https://chemrxiv.org/engage/api-gateway/chemrxiv/assets/orp/resource/item/63ebabaefcfb27a31fc7a64a/original/topology-controlled-self-assembly-of-amphiphilic-block-copolymers.pdfDirect OA link when available
- Concepts
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Micelle, Topology (electrical circuits), Polymer, Amphiphile, Copolymer, Materials science, Network topology, Nanostructure, Ethylene oxide, Self-assembly, Block (permutation group theory), Nanotechnology, Chemistry, Computer science, Mathematics, Organic chemistry, Aqueous solution, Combinatorics, Composite material, Operating system, GeometryTop concepts (fields/topics) attached by OpenAlex
- Cited by
-
2Total citation count in OpenAlex
- Citations by year (recent)
-
2024: 1, 2023: 1Per-year citation counts (last 5 years)
- References (count)
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35Number of works referenced by this work
- Related works (count)
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10Other works algorithmically related by OpenAlex
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