Transmetalation in Phosphorus‐Nitrogen PN3P‐Pincer Complexes: Competitive Ligand‐Metal Affinity Article Swipe
Kuo‐Wei Huang
,
Priyanka Chakraborty
,
Théo P. Gonçalves
,
Delong Han
,
Li Yang
,
Pradip Das
·
YOU?
·
· 2025
· Open Access
·
· DOI: https://doi.org/10.1002/ejic.202500137
YOU?
·
· 2025
· Open Access
·
· DOI: https://doi.org/10.1002/ejic.202500137
Simple and straightforward thermodynamically controlled transmetalation of phosphorus‐nitrogen Zn complex to phosphorus‐nitrogen pincer cobalt and nickel complexes were demonstrated. All the transmetalation products were well characterized by SCXRD, HRMS (positive and negative mode), and NMR. B−H plots from UV‐Vis studies further justify the transmetalation process. Transmetalation results and DFT calculations established the thermodynamic stability of these three complexes in the order of Zn
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- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1002/ejic.202500137
- https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/ejic.202500137
- OA Status
- hybrid
- Cited By
- 1
- References
- 35
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4408766902
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Raw OpenAlex JSON
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https://openalex.org/W4408766902Canonical identifier for this work in OpenAlex
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https://doi.org/10.1002/ejic.202500137Digital Object Identifier
- Title
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Transmetalation in Phosphorus‐Nitrogen PN3P‐Pincer Complexes: Competitive Ligand‐Metal AffinityWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2025Year of publication
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2025-03-23Full publication date if available
- Authors
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Kuo‐Wei Huang, Priyanka Chakraborty, Théo P. Gonçalves, Delong Han, Li Yang, Pradip DasList of authors in order
- Landing page
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https://doi.org/10.1002/ejic.202500137Publisher landing page
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https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/ejic.202500137Direct link to full text PDF
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YesWhether a free full text is available
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hybridOpen access status per OpenAlex
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https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/ejic.202500137Direct OA link when available
- Concepts
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Chemistry, Transmetalation, Phosphorus, Pincer movement, Ligand (biochemistry), Nitrogen, Metal, Pincer ligand, Combinatorial chemistry, Inorganic chemistry, Organic chemistry, Catalysis, Receptor, BiochemistryTop concepts (fields/topics) attached by OpenAlex
- Cited by
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1Total citation count in OpenAlex
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2025: 1Per-year citation counts (last 5 years)
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10Other works algorithmically related by OpenAlex
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| primary_location.raw_source_name | European Journal of Inorganic Chemistry |
| primary_location.landing_page_url | https://doi.org/10.1002/ejic.202500137 |
| publication_date | 2025-03-23 |
| publication_year | 2025 |
| referenced_works | https://openalex.org/W2738356564, https://openalex.org/W3105345402, https://openalex.org/W1989761345, https://openalex.org/W169534460, https://openalex.org/W2032455275, https://openalex.org/W4361984832, https://openalex.org/W4391967427, https://openalex.org/W2954164798, https://openalex.org/W4200095230, https://openalex.org/W4293240772, https://openalex.org/W2323548019, https://openalex.org/W1986992464, https://openalex.org/W2084112085, https://openalex.org/W2910673989, https://openalex.org/W2753671348, https://openalex.org/W3127671806, https://openalex.org/W2888537058, https://openalex.org/W3136194946, https://openalex.org/W2898609055, https://openalex.org/W2016392781, https://openalex.org/W2327481815, https://openalex.org/W2895184803, https://openalex.org/W2793203279, https://openalex.org/W4313494583, https://openalex.org/W2314281029, https://openalex.org/W2139478288, https://openalex.org/W2013136690, https://openalex.org/W3045845094, https://openalex.org/W1964114347, https://openalex.org/W3025886775, https://openalex.org/W1567540105, https://openalex.org/W2321972685, https://openalex.org/W2063694470, https://openalex.org/W2993511937, https://openalex.org/W2023246165 |
| referenced_works_count | 35 |
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| abstract_inverted_index.by | 27 |
| abstract_inverted_index.in | 59 |
| abstract_inverted_index.of | 7, 55, 62 |
| abstract_inverted_index.to | 11, 82 |
| abstract_inverted_index.All | 20 |
| abstract_inverted_index.DFT | 49 |
| abstract_inverted_index.The | 64 |
| abstract_inverted_index.and | 2, 15, 31, 34, 48, 74 |
| abstract_inverted_index.the | 21, 43, 52, 60, 84 |
| abstract_inverted_index.Bond | 66 |
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| abstract_inverted_index.NMR. | 35 |
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| abstract_inverted_index.well | 25 |
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| abstract_inverted_index.Order, | 68 |
| abstract_inverted_index.SCXRD, | 28 |
| abstract_inverted_index.Simple | 1 |
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| abstract_inverted_index.mode), | 33 |
| abstract_inverted_index.nickel | 16 |
| abstract_inverted_index.pincer | 13 |
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| abstract_inverted_index.Extended | 75 |
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| abstract_inverted_index.UV‐Vis | 39 |
| abstract_inverted_index.charges, | 73 |
| abstract_inverted_index.negative | 32 |
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| abstract_inverted_index.complexes | 17, 58 |
| abstract_inverted_index.function, | 71 |
| abstract_inverted_index.stability | 54 |
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| abstract_inverted_index.CHELPG‐ESP | 72 |
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| abstract_inverted_index.localization | 70 |
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| abstract_inverted_index.demonstrated. | 19 |
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| abstract_inverted_index.phosphorus‐nitrogen | 8, 12 |
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| cited_by_percentile_year.min | 91 |
| corresponding_author_ids | https://openalex.org/A5074334575 |
| countries_distinct_count | 1 |
| institutions_distinct_count | 6 |
| corresponding_institution_ids | https://openalex.org/I71920554 |
| citation_normalized_percentile.value | 0.79291772 |
| citation_normalized_percentile.is_in_top_1_percent | False |
| citation_normalized_percentile.is_in_top_10_percent | True |