Tuning the band gap and structure from wide gap SrBi₃O₄Cl₃ to narrow gap Bi₄O₄SeCl₂ by aliovalent anion substitution Article Swipe

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Thompson Robinson , A. Safdar , John Still , Ieuan D. Seymour , Quinn Gibson ·

YOU? · · 2025 · Open Access · · DOI: https://doi.org/10.1039/d5tc01510c

Aliovalent substitution can generates a complex solid solution between SrBi 3 O 4 Cl 3 and Bi 4 O 4 SeCl 2 with very different band gaps, leading to a nearly isolated Se p band and two distinct band-gap like onset energies in intermediate compounds.

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Condensed Matter Physics

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Materials science Band gap Electronic structure Substitution (logic) Metal Crystallography Optoelectronics Condensed matter physics Metallurgy Physics Chemistry Computer science Programming language

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Type: article
Language: en
Landing Page: https://doi.org/10.1039/d5tc01510c
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DOI: https://doi.org/10.1039/d5tc01510c

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Title: Tuning the band gap and structure from wide gap SrBi₃O₄Cl₃ to narrow gap Bi₄O₄SeCl₂ by aliovalent anion substitution

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Language: en

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Publication year: 2025

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Authors: Thompson Robinson, A. Safdar, John Still, Ieuan D. Seymour, Quinn Gibson

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Concepts: Materials science, Band gap, Electronic structure, Substitution (logic), Metal, Crystallography, Optoelectronics, Condensed matter physics, Metallurgy, Physics, Chemistry, Computer science, Programming language

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Tuning the band gap and structure from wide gap SrBi3O4Cl3 to narrow gap Bi4O4SeCl2 by aliovalent anion substitution Article Swipe

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