Turning Normal to Abnormal: Reversing CO2/C2‐Hydrocarbon Selectivity in HKUST‐1 Article Swipe
Mona H. Mohamed
,
Islam Elzeny
,
Joshua Samuel
,
Wenqian Xu
,
Christos D. Malliakas
,
Yoosuf N. Picard
,
Tony Pham
,
Lenore Miller
,
Adam Hogan
,
Brian Space
,
David Hopkinson
,
Sameh K. Elsaidi
·
YOU?
·
· 2024
· Open Access
·
· DOI: https://doi.org/10.1002/adfm.202312280
YOU?
·
· 2024
· Open Access
·
· DOI: https://doi.org/10.1002/adfm.202312280
Metal–organic frameworks (MOFs) can efficiently purify hydrocarbons from CO 2 , but their rapid saturation, driven by preferential hydrocarbon adsorption, requires energy‐intensive adsorption–desorption processes. To address these challenges, an innovative approach is developed, enabling control over MOF flexibility through densification and defect engineering, resulting in an intriguing inverse CO 2 /C2 hydrocarbon selectivity. In this study, the densification process induces the shearing of the crystal lattice and contraction of pores in a defective CuBTC MOF. These changes have led to a remarkable transformation in selectivity, where the originally hydrocarbon‐selective CuBTC MOF becomes CO 2 ‐selective. The selectivity values for densified CuBTC are significantly reversed when compared to its powder form, with notable improvements observed in CO 2 /C 2 H 6 (4416 vs 0.61), CO 2 /C 2 H 4 (15 vs 0.28), and CO 2 /C 2 H 2 (4 vs 0.2). The densified material shows impressive separation, regeneration, and recyclability during dynamic breakthrough experiments with complex quinary gas mixtures. Simulation studies indicate faster CO 2 passage through the tetragonal structure of densified CuBTC compared to C 2 H 2 . Experimental kinetic diffusion studies confirm accelerated CO 2 diffusion over hydrocarbons in the densified MOF, attributed to its small pore window and minimal interparticle voids. This research introduces a promising strategy for refining existing and future MOF materials, enhancing their separation performance.
Related Topics
Concepts
Metadata
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1002/adfm.202312280
- OA Status
- green
- Cited By
- 21
- References
- 47
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4390727567
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
-
https://openalex.org/W4390727567Canonical identifier for this work in OpenAlex
- DOI
-
https://doi.org/10.1002/adfm.202312280Digital Object Identifier
- Title
-
Turning Normal to Abnormal: Reversing CO2/C2‐Hydrocarbon Selectivity in HKUST‐1Work title
- Type
-
articleOpenAlex work type
- Language
-
enPrimary language
- Publication year
-
2024Year of publication
- Publication date
-
2024-01-09Full publication date if available
- Authors
-
Mona H. Mohamed, Islam Elzeny, Joshua Samuel, Wenqian Xu, Christos D. Malliakas, Yoosuf N. Picard, Tony Pham, Lenore Miller, Adam Hogan, Brian Space, David Hopkinson, Sameh K. ElsaidiList of authors in order
- Landing page
-
https://doi.org/10.1002/adfm.202312280Publisher landing page
- Open access
-
YesWhether a free full text is available
- OA status
-
greenOpen access status per OpenAlex
- OA URL
-
https://www.osti.gov/biblio/2281263Direct OA link when available
- Concepts
-
Selectivity, Materials science, Hydrocarbon, Metal-organic framework, Chemical engineering, Adsorption, Desorption, Kinetic control, Nanotechnology, Organic chemistry, Catalysis, Chemistry, EngineeringTop concepts (fields/topics) attached by OpenAlex
- Cited by
-
21Total citation count in OpenAlex
- Citations by year (recent)
-
2025: 18, 2024: 3Per-year citation counts (last 5 years)
- References (count)
-
47Number of works referenced by this work
- Related works (count)
-
10Other works algorithmically related by OpenAlex
Full payload
| id | https://openalex.org/W4390727567 |
|---|---|
| doi | https://doi.org/10.1002/adfm.202312280 |
| ids.doi | https://doi.org/10.1002/adfm.202312280 |
| ids.openalex | https://openalex.org/W4390727567 |
| fwci | 8.15975774 |
| type | article |
| title | Turning Normal to Abnormal: Reversing CO2/C2‐Hydrocarbon Selectivity in HKUST‐1 |
| awards[0].id | https://openalex.org/G712634257 |
| awards[0].funder_id | https://openalex.org/F4320306076 |
| awards[0].display_name | |
| awards[0].funder_award_id | DGE‐2137100 |
| awards[0].funder_display_name | National Science Foundation |
| awards[1].id | https://openalex.org/G6181283282 |
| awards[1].funder_id | https://openalex.org/F4320306084 |
| awards[1].display_name | |
| awards[1].funder_award_id | DE‐AC02‐06CH11357 |
| awards[1].funder_display_name | U.S. Department of Energy |
| awards[2].id | https://openalex.org/G3977665661 |
| awards[2].funder_id | https://openalex.org/F4320337480 |
| awards[2].display_name | |
| awards[2].funder_award_id | DE‐SC0024594 |
| awards[2].funder_display_name | Basic Energy Sciences |
| awards[3].id | https://openalex.org/G6719711198 |
| awards[3].funder_id | https://openalex.org/F4320306076 |
| awards[3].display_name | |
| awards[3].funder_award_id | 2154882 |
| awards[3].funder_display_name | National Science Foundation |
| biblio.issue | 19 |
| biblio.volume | 34 |
| biblio.last_page | |
| biblio.first_page | |
| topics[0].id | https://openalex.org/T10096 |
| topics[0].field.id | https://openalex.org/fields/16 |
| topics[0].field.display_name | Chemistry |
| topics[0].score | 1.0 |
| topics[0].domain.id | https://openalex.org/domains/3 |
| topics[0].domain.display_name | Physical Sciences |
| topics[0].subfield.id | https://openalex.org/subfields/1604 |
| topics[0].subfield.display_name | Inorganic Chemistry |
| topics[0].display_name | Metal-Organic Frameworks: Synthesis and Applications |
| topics[1].id | https://openalex.org/T10967 |
| topics[1].field.id | https://openalex.org/fields/22 |
| topics[1].field.display_name | Engineering |
| topics[1].score | 0.9958999752998352 |
| topics[1].domain.id | https://openalex.org/domains/3 |
| topics[1].domain.display_name | Physical Sciences |
| topics[1].subfield.id | https://openalex.org/subfields/2210 |
| topics[1].subfield.display_name | Mechanical Engineering |
| topics[1].display_name | Carbon Dioxide Capture Technologies |
| topics[2].id | https://openalex.org/T11362 |
| topics[2].field.id | https://openalex.org/fields/22 |
| topics[2].field.display_name | Engineering |
| topics[2].score | 0.9943000078201294 |
| topics[2].domain.id | https://openalex.org/domains/3 |
| topics[2].domain.display_name | Physical Sciences |
| topics[2].subfield.id | https://openalex.org/subfields/2210 |
| topics[2].subfield.display_name | Mechanical Engineering |
| topics[2].display_name | Membrane Separation and Gas Transport |
| funders[0].id | https://openalex.org/F4320306076 |
| funders[0].ror | https://ror.org/021nxhr62 |
| funders[0].display_name | National Science Foundation |
| funders[1].id | https://openalex.org/F4320306084 |
| funders[1].ror | https://ror.org/01bj3aw27 |
| funders[1].display_name | U.S. Department of Energy |
| funders[2].id | https://openalex.org/F4320337480 |
| funders[2].ror | https://ror.org/05mg91w61 |
| funders[2].display_name | Basic Energy Sciences |
| is_xpac | False |
| apc_list.value | 5250 |
| apc_list.currency | USD |
| apc_list.value_usd | 5250 |
| apc_paid | |
| concepts[0].id | https://openalex.org/C118792377 |
| concepts[0].level | 3 |
| concepts[0].score | 0.8265044689178467 |
| concepts[0].wikidata | https://www.wikidata.org/wiki/Q108584245 |
| concepts[0].display_name | Selectivity |
| concepts[1].id | https://openalex.org/C192562407 |
| concepts[1].level | 0 |
| concepts[1].score | 0.764738917350769 |
| concepts[1].wikidata | https://www.wikidata.org/wiki/Q228736 |
| concepts[1].display_name | Materials science |
| concepts[2].id | https://openalex.org/C2777207669 |
| concepts[2].level | 2 |
| concepts[2].score | 0.7607421278953552 |
| concepts[2].wikidata | https://www.wikidata.org/wiki/Q43648 |
| concepts[2].display_name | Hydrocarbon |
| concepts[3].id | https://openalex.org/C179366358 |
| concepts[3].level | 3 |
| concepts[3].score | 0.6512112617492676 |
| concepts[3].wikidata | https://www.wikidata.org/wiki/Q909212 |
| concepts[3].display_name | Metal-organic framework |
| concepts[4].id | https://openalex.org/C42360764 |
| concepts[4].level | 1 |
| concepts[4].score | 0.6228660345077515 |
| concepts[4].wikidata | https://www.wikidata.org/wiki/Q83588 |
| concepts[4].display_name | Chemical engineering |
| concepts[5].id | https://openalex.org/C150394285 |
| concepts[5].level | 2 |
| concepts[5].score | 0.5934963226318359 |
| concepts[5].wikidata | https://www.wikidata.org/wiki/Q180254 |
| concepts[5].display_name | Adsorption |
| concepts[6].id | https://openalex.org/C162711632 |
| concepts[6].level | 3 |
| concepts[6].score | 0.508749783039093 |
| concepts[6].wikidata | https://www.wikidata.org/wiki/Q905514 |
| concepts[6].display_name | Desorption |
| concepts[7].id | https://openalex.org/C2991957519 |
| concepts[7].level | 3 |
| concepts[7].score | 0.4172297418117523 |
| concepts[7].wikidata | https://www.wikidata.org/wiki/Q2469857 |
| concepts[7].display_name | Kinetic control |
| concepts[8].id | https://openalex.org/C171250308 |
| concepts[8].level | 1 |
| concepts[8].score | 0.3423295319080353 |
| concepts[8].wikidata | https://www.wikidata.org/wiki/Q11468 |
| concepts[8].display_name | Nanotechnology |
| concepts[9].id | https://openalex.org/C178790620 |
| concepts[9].level | 1 |
| concepts[9].score | 0.22335323691368103 |
| concepts[9].wikidata | https://www.wikidata.org/wiki/Q11351 |
| concepts[9].display_name | Organic chemistry |
| concepts[10].id | https://openalex.org/C161790260 |
| concepts[10].level | 2 |
| concepts[10].score | 0.1646886169910431 |
| concepts[10].wikidata | https://www.wikidata.org/wiki/Q82264 |
| concepts[10].display_name | Catalysis |
| concepts[11].id | https://openalex.org/C185592680 |
| concepts[11].level | 0 |
| concepts[11].score | 0.1418379247188568 |
| concepts[11].wikidata | https://www.wikidata.org/wiki/Q2329 |
| concepts[11].display_name | Chemistry |
| concepts[12].id | https://openalex.org/C127413603 |
| concepts[12].level | 0 |
| concepts[12].score | 0.0 |
| concepts[12].wikidata | https://www.wikidata.org/wiki/Q11023 |
| concepts[12].display_name | Engineering |
| keywords[0].id | https://openalex.org/keywords/selectivity |
| keywords[0].score | 0.8265044689178467 |
| keywords[0].display_name | Selectivity |
| keywords[1].id | https://openalex.org/keywords/materials-science |
| keywords[1].score | 0.764738917350769 |
| keywords[1].display_name | Materials science |
| keywords[2].id | https://openalex.org/keywords/hydrocarbon |
| keywords[2].score | 0.7607421278953552 |
| keywords[2].display_name | Hydrocarbon |
| keywords[3].id | https://openalex.org/keywords/metal-organic-framework |
| keywords[3].score | 0.6512112617492676 |
| keywords[3].display_name | Metal-organic framework |
| keywords[4].id | https://openalex.org/keywords/chemical-engineering |
| keywords[4].score | 0.6228660345077515 |
| keywords[4].display_name | Chemical engineering |
| keywords[5].id | https://openalex.org/keywords/adsorption |
| keywords[5].score | 0.5934963226318359 |
| keywords[5].display_name | Adsorption |
| keywords[6].id | https://openalex.org/keywords/desorption |
| keywords[6].score | 0.508749783039093 |
| keywords[6].display_name | Desorption |
| keywords[7].id | https://openalex.org/keywords/kinetic-control |
| keywords[7].score | 0.4172297418117523 |
| keywords[7].display_name | Kinetic control |
| keywords[8].id | https://openalex.org/keywords/nanotechnology |
| keywords[8].score | 0.3423295319080353 |
| keywords[8].display_name | Nanotechnology |
| keywords[9].id | https://openalex.org/keywords/organic-chemistry |
| keywords[9].score | 0.22335323691368103 |
| keywords[9].display_name | Organic chemistry |
| keywords[10].id | https://openalex.org/keywords/catalysis |
| keywords[10].score | 0.1646886169910431 |
| keywords[10].display_name | Catalysis |
| keywords[11].id | https://openalex.org/keywords/chemistry |
| keywords[11].score | 0.1418379247188568 |
| keywords[11].display_name | Chemistry |
| language | en |
| locations[0].id | doi:10.1002/adfm.202312280 |
| locations[0].is_oa | False |
| locations[0].source.id | https://openalex.org/S135204980 |
| locations[0].source.issn | 1616-301X, 1616-3028 |
| locations[0].source.type | journal |
| locations[0].source.is_oa | False |
| locations[0].source.issn_l | 1616-301X |
| locations[0].source.is_core | True |
| locations[0].source.is_in_doaj | False |
| locations[0].source.display_name | Advanced Functional Materials |
| locations[0].source.host_organization | https://openalex.org/P4310320595 |
| locations[0].source.host_organization_name | Wiley |
| locations[0].source.host_organization_lineage | https://openalex.org/P4310320595 |
| locations[0].source.host_organization_lineage_names | Wiley |
| locations[0].license | |
| locations[0].pdf_url | |
| locations[0].version | publishedVersion |
| locations[0].raw_type | journal-article |
| locations[0].license_id | |
| locations[0].is_accepted | True |
| locations[0].is_published | True |
| locations[0].raw_source_name | Advanced Functional Materials |
| locations[0].landing_page_url | https://doi.org/10.1002/adfm.202312280 |
| locations[1].id | pmh:oai:osti.gov:2281263 |
| locations[1].is_oa | True |
| locations[1].source.id | https://openalex.org/S4306402487 |
| locations[1].source.issn | |
| locations[1].source.type | repository |
| locations[1].source.is_oa | False |
| locations[1].source.issn_l | |
| locations[1].source.is_core | False |
| locations[1].source.is_in_doaj | False |
| locations[1].source.display_name | OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information) |
| locations[1].source.host_organization | https://openalex.org/I139351228 |
| locations[1].source.host_organization_name | Office of Scientific and Technical Information |
| locations[1].source.host_organization_lineage | https://openalex.org/I139351228 |
| locations[1].license | |
| locations[1].pdf_url | |
| locations[1].version | submittedVersion |
| locations[1].raw_type | |
| locations[1].license_id | |
| locations[1].is_accepted | False |
| locations[1].is_published | False |
| locations[1].raw_source_name | |
| locations[1].landing_page_url | https://www.osti.gov/biblio/2281263 |
| locations[2].id | pmh:oai:osti.gov:2367177 |
| locations[2].is_oa | True |
| locations[2].source.id | https://openalex.org/S4306402487 |
| locations[2].source.issn | |
| locations[2].source.type | repository |
| locations[2].source.is_oa | False |
| locations[2].source.issn_l | |
| locations[2].source.is_core | False |
| locations[2].source.is_in_doaj | False |
| locations[2].source.display_name | OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information) |
| locations[2].source.host_organization | https://openalex.org/I139351228 |
| locations[2].source.host_organization_name | Office of Scientific and Technical Information |
| locations[2].source.host_organization_lineage | https://openalex.org/I139351228 |
| locations[2].license | |
| locations[2].pdf_url | |
| locations[2].version | submittedVersion |
| locations[2].raw_type | |
| locations[2].license_id | |
| locations[2].is_accepted | False |
| locations[2].is_published | False |
| locations[2].raw_source_name | |
| locations[2].landing_page_url | https://www.osti.gov/biblio/2367177 |
| locations[3].id | pmh:oai:osti.gov:2477356 |
| locations[3].is_oa | True |
| locations[3].source.id | https://openalex.org/S4306402487 |
| locations[3].source.issn | |
| locations[3].source.type | repository |
| locations[3].source.is_oa | False |
| locations[3].source.issn_l | |
| locations[3].source.is_core | False |
| locations[3].source.is_in_doaj | False |
| locations[3].source.display_name | OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information) |
| locations[3].source.host_organization | https://openalex.org/I139351228 |
| locations[3].source.host_organization_name | Office of Scientific and Technical Information |
| locations[3].source.host_organization_lineage | https://openalex.org/I139351228 |
| locations[3].license | |
| locations[3].pdf_url | |
| locations[3].version | submittedVersion |
| locations[3].raw_type | |
| locations[3].license_id | |
| locations[3].is_accepted | False |
| locations[3].is_published | False |
| locations[3].raw_source_name | |
| locations[3].landing_page_url | https://www.osti.gov/biblio/2477356 |
| indexed_in | crossref |
| authorships[0].author.id | https://openalex.org/A5111815620 |
| authorships[0].author.orcid | |
| authorships[0].author.display_name | Mona H. Mohamed |
| authorships[0].countries | EG, US |
| authorships[0].affiliations[0].institution_ids | https://openalex.org/I180949307 |
| authorships[0].affiliations[0].raw_affiliation_string | Department of Chemistry, Illinois Institute of Technology, Chicago, IL, 60616 USA |
| authorships[0].affiliations[1].institution_ids | https://openalex.org/I4210111873 |
| authorships[0].affiliations[1].raw_affiliation_string | SE-MAT Smartly Engineered Materials LLC, Pittsburgh, PA, 15238 USA |
| authorships[0].affiliations[2].institution_ids | https://openalex.org/I84524832 |
| authorships[0].affiliations[2].raw_affiliation_string | Department of Chemistry, Faculty of Science, Alexandria University, Alexandria, Egypt |
| authorships[0].institutions[0].id | https://openalex.org/I84524832 |
| authorships[0].institutions[0].ror | https://ror.org/00mzz1w90 |
| authorships[0].institutions[0].type | education |
| authorships[0].institutions[0].lineage | https://openalex.org/I84524832 |
| authorships[0].institutions[0].country_code | EG |
| authorships[0].institutions[0].display_name | Alexandria University |
| authorships[0].institutions[1].id | https://openalex.org/I180949307 |
| authorships[0].institutions[1].ror | https://ror.org/037t3ry66 |
| authorships[0].institutions[1].type | education |
| authorships[0].institutions[1].lineage | https://openalex.org/I180949307 |
| authorships[0].institutions[1].country_code | US |
| authorships[0].institutions[1].display_name | Illinois Institute of Technology |
| authorships[0].institutions[2].id | https://openalex.org/I4210111873 |
| authorships[0].institutions[2].ror | https://ror.org/01bb1ac21 |
| authorships[0].institutions[2].type | company |
| authorships[0].institutions[2].lineage | https://openalex.org/I4210111873 |
| authorships[0].institutions[2].country_code | US |
| authorships[0].institutions[2].display_name | SCI Engineered Materials (United States) |
| authorships[0].author_position | first |
| authorships[0].raw_author_name | Mona H. Mohamed |
| authorships[0].is_corresponding | True |
| authorships[0].raw_affiliation_strings | Department of Chemistry, Faculty of Science, Alexandria University, Alexandria, Egypt, Department of Chemistry, Illinois Institute of Technology, Chicago, IL, 60616 USA, SE-MAT Smartly Engineered Materials LLC, Pittsburgh, PA, 15238 USA |
| authorships[1].author.id | https://openalex.org/A5093701732 |
| authorships[1].author.orcid | |
| authorships[1].author.display_name | Islam Elzeny |
| authorships[1].countries | US |
| authorships[1].affiliations[0].institution_ids | https://openalex.org/I180949307 |
| authorships[1].affiliations[0].raw_affiliation_string | Department of Chemistry, Illinois Institute of Technology, Chicago, IL, 60616 USA |
| authorships[1].institutions[0].id | https://openalex.org/I180949307 |
| authorships[1].institutions[0].ror | https://ror.org/037t3ry66 |
| authorships[1].institutions[0].type | education |
| authorships[1].institutions[0].lineage | https://openalex.org/I180949307 |
| authorships[1].institutions[0].country_code | US |
| authorships[1].institutions[0].display_name | Illinois Institute of Technology |
| authorships[1].author_position | middle |
| authorships[1].raw_author_name | Islam Elzeny |
| authorships[1].is_corresponding | False |
| authorships[1].raw_affiliation_strings | Department of Chemistry, Illinois Institute of Technology, Chicago, IL, 60616 USA |
| authorships[2].author.id | https://openalex.org/A5025664991 |
| authorships[2].author.orcid | https://orcid.org/0000-0001-8231-2988 |
| authorships[2].author.display_name | Joshua Samuel |
| authorships[2].countries | US |
| authorships[2].affiliations[0].institution_ids | https://openalex.org/I180949307 |
| authorships[2].affiliations[0].raw_affiliation_string | Department of Chemistry, Illinois Institute of Technology, Chicago, IL, 60616 USA |
| authorships[2].institutions[0].id | https://openalex.org/I180949307 |
| authorships[2].institutions[0].ror | https://ror.org/037t3ry66 |
| authorships[2].institutions[0].type | education |
| authorships[2].institutions[0].lineage | https://openalex.org/I180949307 |
| authorships[2].institutions[0].country_code | US |
| authorships[2].institutions[0].display_name | Illinois Institute of Technology |
| authorships[2].author_position | middle |
| authorships[2].raw_author_name | Joshua Samuel |
| authorships[2].is_corresponding | False |
| authorships[2].raw_affiliation_strings | Department of Chemistry, Illinois Institute of Technology, Chicago, IL, 60616 USA |
| authorships[3].author.id | https://openalex.org/A5074779671 |
| authorships[3].author.orcid | https://orcid.org/0000-0002-4815-6253 |
| authorships[3].author.display_name | Wenqian Xu |
| authorships[3].countries | US |
| authorships[3].affiliations[0].institution_ids | https://openalex.org/I1282105669 |
| authorships[3].affiliations[0].raw_affiliation_string | X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Lemont, IL, 60439 USA |
| authorships[3].institutions[0].id | https://openalex.org/I1282105669 |
| authorships[3].institutions[0].ror | https://ror.org/05gvnxz63 |
| authorships[3].institutions[0].type | facility |
| authorships[3].institutions[0].lineage | https://openalex.org/I1282105669, https://openalex.org/I1330989302, https://openalex.org/I39565521, https://openalex.org/I40347166 |
| authorships[3].institutions[0].country_code | US |
| authorships[3].institutions[0].display_name | Argonne National Laboratory |
| authorships[3].author_position | middle |
| authorships[3].raw_author_name | Wenqian Xu |
| authorships[3].is_corresponding | False |
| authorships[3].raw_affiliation_strings | X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Lemont, IL, 60439 USA |
| authorships[4].author.id | https://openalex.org/A5038077986 |
| authorships[4].author.orcid | https://orcid.org/0000-0003-4416-638X |
| authorships[4].author.display_name | Christos D. Malliakas |
| authorships[4].countries | US |
| authorships[4].affiliations[0].institution_ids | https://openalex.org/I111979921 |
| authorships[4].affiliations[0].raw_affiliation_string | Department of Chemistry, Northwestern University, Evanston, IL, 60208 USA |
| authorships[4].institutions[0].id | https://openalex.org/I111979921 |
| authorships[4].institutions[0].ror | https://ror.org/000e0be47 |
| authorships[4].institutions[0].type | education |
| authorships[4].institutions[0].lineage | https://openalex.org/I111979921 |
| authorships[4].institutions[0].country_code | US |
| authorships[4].institutions[0].display_name | Northwestern University |
| authorships[4].author_position | middle |
| authorships[4].raw_author_name | Christos D Malliakas |
| authorships[4].is_corresponding | False |
| authorships[4].raw_affiliation_strings | Department of Chemistry, Northwestern University, Evanston, IL, 60208 USA |
| authorships[5].author.id | https://openalex.org/A5014541776 |
| authorships[5].author.orcid | https://orcid.org/0000-0002-2853-5213 |
| authorships[5].author.display_name | Yoosuf N. Picard |
| authorships[5].countries | US |
| authorships[5].affiliations[0].institution_ids | https://openalex.org/I4210112314 |
| authorships[5].affiliations[0].raw_affiliation_string | DOE National Energy Technology Laboratory (NETL), Pittsburgh, PA, 15236 USA |
| authorships[5].affiliations[1].institution_ids | https://openalex.org/I4389425366 |
| authorships[5].affiliations[1].raw_affiliation_string | Oak Ridge Institute for Science and Education, Pittsburgh, PA, 15236 USA |
| authorships[5].institutions[0].id | https://openalex.org/I4389425366 |
| authorships[5].institutions[0].ror | https://ror.org/040vxhp34 |
| authorships[5].institutions[0].type | education |
| authorships[5].institutions[0].lineage | https://openalex.org/I1281378812, https://openalex.org/I1330989302, https://openalex.org/I4389425366 |
| authorships[5].institutions[0].country_code | |
| authorships[5].institutions[0].display_name | Oak Ridge Institute for Science and Education |
| authorships[5].institutions[1].id | https://openalex.org/I4210112314 |
| authorships[5].institutions[1].ror | https://ror.org/01x26mz03 |
| authorships[5].institutions[1].type | facility |
| authorships[5].institutions[1].lineage | https://openalex.org/I1330989302, https://openalex.org/I4210112314, https://openalex.org/I4210118742 |
| authorships[5].institutions[1].country_code | US |
| authorships[5].institutions[1].display_name | National Energy Technology Laboratory |
| authorships[5].author_position | middle |
| authorships[5].raw_author_name | Yoosuf N. Picard |
| authorships[5].is_corresponding | False |
| authorships[5].raw_affiliation_strings | DOE National Energy Technology Laboratory (NETL), Pittsburgh, PA, 15236 USA, Oak Ridge Institute for Science and Education, Pittsburgh, PA, 15236 USA |
| authorships[6].author.id | https://openalex.org/A5018821730 |
| authorships[6].author.orcid | https://orcid.org/0000-0001-5654-163X |
| authorships[6].author.display_name | Tony Pham |
| authorships[6].countries | US |
| authorships[6].affiliations[0].institution_ids | https://openalex.org/I2613432 |
| authorships[6].affiliations[0].raw_affiliation_string | Department of Chemistry, University of South Florida, Tampa, FL, 33620 USA |
| authorships[6].institutions[0].id | https://openalex.org/I2613432 |
| authorships[6].institutions[0].ror | https://ror.org/032db5x82 |
| authorships[6].institutions[0].type | education |
| authorships[6].institutions[0].lineage | https://openalex.org/I2613432 |
| authorships[6].institutions[0].country_code | US |
| authorships[6].institutions[0].display_name | University of South Florida |
| authorships[6].author_position | middle |
| authorships[6].raw_author_name | Tony Pham |
| authorships[6].is_corresponding | False |
| authorships[6].raw_affiliation_strings | Department of Chemistry, University of South Florida, Tampa, FL, 33620 USA |
| authorships[7].author.id | https://openalex.org/A5109707529 |
| authorships[7].author.orcid | |
| authorships[7].author.display_name | Lenore Miller |
| authorships[7].countries | US |
| authorships[7].affiliations[0].institution_ids | https://openalex.org/I137902535 |
| authorships[7].affiliations[0].raw_affiliation_string | Department of Chemistry, North Carolina State University, Raleigh, NC, 27607 USA |
| authorships[7].institutions[0].id | https://openalex.org/I137902535 |
| authorships[7].institutions[0].ror | https://ror.org/04tj63d06 |
| authorships[7].institutions[0].type | education |
| authorships[7].institutions[0].lineage | https://openalex.org/I137902535 |
| authorships[7].institutions[0].country_code | US |
| authorships[7].institutions[0].display_name | North Carolina State University |
| authorships[7].author_position | middle |
| authorships[7].raw_author_name | Lenore Miller |
| authorships[7].is_corresponding | False |
| authorships[7].raw_affiliation_strings | Department of Chemistry, North Carolina State University, Raleigh, NC, 27607 USA |
| authorships[8].author.id | https://openalex.org/A5017949459 |
| authorships[8].author.orcid | https://orcid.org/0000-0003-3102-3056 |
| authorships[8].author.display_name | Adam Hogan |
| authorships[8].countries | US |
| authorships[8].affiliations[0].institution_ids | https://openalex.org/I137902535 |
| authorships[8].affiliations[0].raw_affiliation_string | Department of Chemistry, North Carolina State University, Raleigh, NC, 27607 USA |
| authorships[8].institutions[0].id | https://openalex.org/I137902535 |
| authorships[8].institutions[0].ror | https://ror.org/04tj63d06 |
| authorships[8].institutions[0].type | education |
| authorships[8].institutions[0].lineage | https://openalex.org/I137902535 |
| authorships[8].institutions[0].country_code | US |
| authorships[8].institutions[0].display_name | North Carolina State University |
| authorships[8].author_position | middle |
| authorships[8].raw_author_name | Adam Hogan |
| authorships[8].is_corresponding | False |
| authorships[8].raw_affiliation_strings | Department of Chemistry, North Carolina State University, Raleigh, NC, 27607 USA |
| authorships[9].author.id | https://openalex.org/A5022312011 |
| authorships[9].author.orcid | https://orcid.org/0000-0003-0246-7408 |
| authorships[9].author.display_name | Brian Space |
| authorships[9].countries | US |
| authorships[9].affiliations[0].institution_ids | https://openalex.org/I137902535 |
| authorships[9].affiliations[0].raw_affiliation_string | Department of Chemistry, North Carolina State University, Raleigh, NC, 27607 USA |
| authorships[9].institutions[0].id | https://openalex.org/I137902535 |
| authorships[9].institutions[0].ror | https://ror.org/04tj63d06 |
| authorships[9].institutions[0].type | education |
| authorships[9].institutions[0].lineage | https://openalex.org/I137902535 |
| authorships[9].institutions[0].country_code | US |
| authorships[9].institutions[0].display_name | North Carolina State University |
| authorships[9].author_position | middle |
| authorships[9].raw_author_name | Brian Space |
| authorships[9].is_corresponding | False |
| authorships[9].raw_affiliation_strings | Department of Chemistry, North Carolina State University, Raleigh, NC, 27607 USA |
| authorships[10].author.id | https://openalex.org/A5021768097 |
| authorships[10].author.orcid | |
| authorships[10].author.display_name | David Hopkinson |
| authorships[10].countries | US |
| authorships[10].affiliations[0].institution_ids | https://openalex.org/I4210112314 |
| authorships[10].affiliations[0].raw_affiliation_string | DOE National Energy Technology Laboratory (NETL), Pittsburgh, PA, 15236 USA |
| authorships[10].institutions[0].id | https://openalex.org/I4210112314 |
| authorships[10].institutions[0].ror | https://ror.org/01x26mz03 |
| authorships[10].institutions[0].type | facility |
| authorships[10].institutions[0].lineage | https://openalex.org/I1330989302, https://openalex.org/I4210112314, https://openalex.org/I4210118742 |
| authorships[10].institutions[0].country_code | US |
| authorships[10].institutions[0].display_name | National Energy Technology Laboratory |
| authorships[10].author_position | middle |
| authorships[10].raw_author_name | David Hopkinson |
| authorships[10].is_corresponding | False |
| authorships[10].raw_affiliation_strings | DOE National Energy Technology Laboratory (NETL), Pittsburgh, PA, 15236 USA |
| authorships[11].author.id | https://openalex.org/A5064451037 |
| authorships[11].author.orcid | https://orcid.org/0000-0002-8326-6984 |
| authorships[11].author.display_name | Sameh K. Elsaidi |
| authorships[11].countries | US |
| authorships[11].affiliations[0].institution_ids | https://openalex.org/I4210111873 |
| authorships[11].affiliations[0].raw_affiliation_string | SE-MAT Smartly Engineered Materials LLC, Pittsburgh, PA, 15238 USA |
| authorships[11].affiliations[1].institution_ids | https://openalex.org/I180949307 |
| authorships[11].affiliations[1].raw_affiliation_string | Department of Chemistry, Illinois Institute of Technology, Chicago, IL, 60616 USA |
| authorships[11].institutions[0].id | https://openalex.org/I180949307 |
| authorships[11].institutions[0].ror | https://ror.org/037t3ry66 |
| authorships[11].institutions[0].type | education |
| authorships[11].institutions[0].lineage | https://openalex.org/I180949307 |
| authorships[11].institutions[0].country_code | US |
| authorships[11].institutions[0].display_name | Illinois Institute of Technology |
| authorships[11].institutions[1].id | https://openalex.org/I4210111873 |
| authorships[11].institutions[1].ror | https://ror.org/01bb1ac21 |
| authorships[11].institutions[1].type | company |
| authorships[11].institutions[1].lineage | https://openalex.org/I4210111873 |
| authorships[11].institutions[1].country_code | US |
| authorships[11].institutions[1].display_name | SCI Engineered Materials (United States) |
| authorships[11].author_position | last |
| authorships[11].raw_author_name | Sameh K. Elsaidi |
| authorships[11].is_corresponding | True |
| authorships[11].raw_affiliation_strings | Department of Chemistry, Illinois Institute of Technology, Chicago, IL, 60616 USA, SE-MAT Smartly Engineered Materials LLC, Pittsburgh, PA, 15238 USA |
| has_content.pdf | False |
| has_content.grobid_xml | False |
| is_paratext | False |
| open_access.is_oa | True |
| open_access.oa_url | https://www.osti.gov/biblio/2281263 |
| open_access.oa_status | green |
| open_access.any_repository_has_fulltext | False |
| created_date | 2025-10-10T00:00:00 |
| display_name | Turning Normal to Abnormal: Reversing CO2/C2‐Hydrocarbon Selectivity in HKUST‐1 |
| has_fulltext | False |
| is_retracted | False |
| updated_date | 2025-11-06T03:46:38.306776 |
| primary_topic.id | https://openalex.org/T10096 |
| primary_topic.field.id | https://openalex.org/fields/16 |
| primary_topic.field.display_name | Chemistry |
| primary_topic.score | 1.0 |
| primary_topic.domain.id | https://openalex.org/domains/3 |
| primary_topic.domain.display_name | Physical Sciences |
| primary_topic.subfield.id | https://openalex.org/subfields/1604 |
| primary_topic.subfield.display_name | Inorganic Chemistry |
| primary_topic.display_name | Metal-Organic Frameworks: Synthesis and Applications |
| related_works | https://openalex.org/W1984689874, https://openalex.org/W2022438866, https://openalex.org/W1586206203, https://openalex.org/W2619424135, https://openalex.org/W2114451818, https://openalex.org/W4253005003, https://openalex.org/W2033566589, https://openalex.org/W4405122524, https://openalex.org/W2951237352, https://openalex.org/W2074509783 |
| cited_by_count | 21 |
| counts_by_year[0].year | 2025 |
| counts_by_year[0].cited_by_count | 18 |
| counts_by_year[1].year | 2024 |
| counts_by_year[1].cited_by_count | 3 |
| locations_count | 4 |
| best_oa_location.id | pmh:oai:osti.gov:2281263 |
| best_oa_location.is_oa | True |
| best_oa_location.source.id | https://openalex.org/S4306402487 |
| best_oa_location.source.issn | |
| best_oa_location.source.type | repository |
| best_oa_location.source.is_oa | False |
| best_oa_location.source.issn_l | |
| best_oa_location.source.is_core | False |
| best_oa_location.source.is_in_doaj | False |
| best_oa_location.source.display_name | OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information) |
| best_oa_location.source.host_organization | https://openalex.org/I139351228 |
| best_oa_location.source.host_organization_name | Office of Scientific and Technical Information |
| best_oa_location.source.host_organization_lineage | https://openalex.org/I139351228 |
| best_oa_location.license | |
| best_oa_location.pdf_url | |
| best_oa_location.version | submittedVersion |
| best_oa_location.raw_type | |
| best_oa_location.license_id | |
| best_oa_location.is_accepted | False |
| best_oa_location.is_published | False |
| best_oa_location.raw_source_name | |
| best_oa_location.landing_page_url | https://www.osti.gov/biblio/2281263 |
| primary_location.id | doi:10.1002/adfm.202312280 |
| primary_location.is_oa | False |
| primary_location.source.id | https://openalex.org/S135204980 |
| primary_location.source.issn | 1616-301X, 1616-3028 |
| primary_location.source.type | journal |
| primary_location.source.is_oa | False |
| primary_location.source.issn_l | 1616-301X |
| primary_location.source.is_core | True |
| primary_location.source.is_in_doaj | False |
| primary_location.source.display_name | Advanced Functional Materials |
| primary_location.source.host_organization | https://openalex.org/P4310320595 |
| primary_location.source.host_organization_name | Wiley |
| primary_location.source.host_organization_lineage | https://openalex.org/P4310320595 |
| primary_location.source.host_organization_lineage_names | Wiley |
| primary_location.license | |
| primary_location.pdf_url | |
| primary_location.version | publishedVersion |
| primary_location.raw_type | journal-article |
| primary_location.license_id | |
| primary_location.is_accepted | True |
| primary_location.is_published | True |
| primary_location.raw_source_name | Advanced Functional Materials |
| primary_location.landing_page_url | https://doi.org/10.1002/adfm.202312280 |
| publication_date | 2024-01-09 |
| publication_year | 2024 |
| referenced_works | https://openalex.org/W2339540635, https://openalex.org/W2095457548, https://openalex.org/W2144754980, https://openalex.org/W2125053394, https://openalex.org/W2027053970, https://openalex.org/W4312041660, https://openalex.org/W2274294414, https://openalex.org/W4281629326, https://openalex.org/W2333471032, https://openalex.org/W3141572515, https://openalex.org/W2984785978, https://openalex.org/W4220687419, https://openalex.org/W3016190672, https://openalex.org/W2277238745, https://openalex.org/W2758601171, https://openalex.org/W2774921722, https://openalex.org/W2073178380, https://openalex.org/W2947576927, https://openalex.org/W4291061473, https://openalex.org/W2986911163, https://openalex.org/W4223461925, https://openalex.org/W2794088502, https://openalex.org/W2756103189, https://openalex.org/W2561762587, https://openalex.org/W3088255640, https://openalex.org/W2083356397, https://openalex.org/W2331586132, https://openalex.org/W2617637822, https://openalex.org/W3165317715, https://openalex.org/W3187218815, https://openalex.org/W3043268236, https://openalex.org/W3027714047, https://openalex.org/W2020171897, https://openalex.org/W2048358843, https://openalex.org/W3119321601, https://openalex.org/W2313657079, https://openalex.org/W2953629823, https://openalex.org/W2317401029, https://openalex.org/W2332283567, https://openalex.org/W2744818153, https://openalex.org/W4220956252, https://openalex.org/W3001819053, https://openalex.org/W3148110940, https://openalex.org/W2799413870, https://openalex.org/W4304080635, https://openalex.org/W2606183602, https://openalex.org/W4289519655 |
| referenced_works_count | 47 |
| abstract_inverted_index., | 11 |
| abstract_inverted_index.. | 182 |
| abstract_inverted_index.2 | 10, 50, 94, 117, 119, 126, 128, 136, 138, 140, 167, 179, 181, 190 |
| abstract_inverted_index.4 | 130 |
| abstract_inverted_index.6 | 121 |
| abstract_inverted_index.C | 178 |
| abstract_inverted_index.H | 120, 129, 139, 180 |
| abstract_inverted_index.a | 72, 81, 211 |
| abstract_inverted_index.(4 | 141 |
| abstract_inverted_index./C | 118, 127, 137 |
| abstract_inverted_index.CO | 9, 49, 93, 116, 125, 135, 166, 189 |
| abstract_inverted_index.In | 54 |
| abstract_inverted_index.To | 25 |
| abstract_inverted_index.an | 29, 46 |
| abstract_inverted_index.by | 17 |
| abstract_inverted_index.in | 45, 71, 84, 115, 194 |
| abstract_inverted_index.is | 32 |
| abstract_inverted_index.of | 63, 69, 173 |
| abstract_inverted_index.to | 80, 107, 177, 199 |
| abstract_inverted_index.vs | 123, 132, 142 |
| abstract_inverted_index.(15 | 131 |
| abstract_inverted_index./C2 | 51 |
| abstract_inverted_index.MOF | 37, 91, 219 |
| abstract_inverted_index.The | 96, 144 |
| abstract_inverted_index.and | 41, 67, 134, 151, 204, 217 |
| abstract_inverted_index.are | 102 |
| abstract_inverted_index.but | 12 |
| abstract_inverted_index.can | 4 |
| abstract_inverted_index.for | 99, 214 |
| abstract_inverted_index.gas | 160 |
| abstract_inverted_index.its | 108, 200 |
| abstract_inverted_index.led | 79 |
| abstract_inverted_index.the | 57, 61, 64, 87, 170, 195 |
| abstract_inverted_index.MOF, | 197 |
| abstract_inverted_index.MOF. | 75 |
| abstract_inverted_index.This | 208 |
| abstract_inverted_index.from | 8 |
| abstract_inverted_index.have | 78 |
| abstract_inverted_index.over | 36, 192 |
| abstract_inverted_index.pore | 202 |
| abstract_inverted_index.this | 55 |
| abstract_inverted_index.when | 105 |
| abstract_inverted_index.with | 111, 157 |
| abstract_inverted_index.(4416 | 122 |
| abstract_inverted_index.0.2). | 143 |
| abstract_inverted_index.CuBTC | 74, 90, 101, 175 |
| abstract_inverted_index.These | 76 |
| abstract_inverted_index.form, | 110 |
| abstract_inverted_index.pores | 70 |
| abstract_inverted_index.rapid | 14 |
| abstract_inverted_index.shows | 147 |
| abstract_inverted_index.small | 201 |
| abstract_inverted_index.their | 13, 222 |
| abstract_inverted_index.these | 27 |
| abstract_inverted_index.where | 86 |
| abstract_inverted_index.(MOFs) | 3 |
| abstract_inverted_index.0.28), | 133 |
| abstract_inverted_index.0.61), | 124 |
| abstract_inverted_index.defect | 42 |
| abstract_inverted_index.driven | 16 |
| abstract_inverted_index.during | 153 |
| abstract_inverted_index.faster | 165 |
| abstract_inverted_index.future | 218 |
| abstract_inverted_index.powder | 109 |
| abstract_inverted_index.purify | 6 |
| abstract_inverted_index.study, | 56 |
| abstract_inverted_index.values | 98 |
| abstract_inverted_index.voids. | 207 |
| abstract_inverted_index.window | 203 |
| abstract_inverted_index.address | 26 |
| abstract_inverted_index.becomes | 92 |
| abstract_inverted_index.changes | 77 |
| abstract_inverted_index.complex | 158 |
| abstract_inverted_index.confirm | 187 |
| abstract_inverted_index.control | 35 |
| abstract_inverted_index.crystal | 65 |
| abstract_inverted_index.dynamic | 154 |
| abstract_inverted_index.induces | 60 |
| abstract_inverted_index.inverse | 48 |
| abstract_inverted_index.kinetic | 184 |
| abstract_inverted_index.lattice | 66 |
| abstract_inverted_index.minimal | 205 |
| abstract_inverted_index.notable | 112 |
| abstract_inverted_index.passage | 168 |
| abstract_inverted_index.process | 59 |
| abstract_inverted_index.quinary | 159 |
| abstract_inverted_index.studies | 163, 186 |
| abstract_inverted_index.through | 39, 169 |
| abstract_inverted_index.Abstract | 0 |
| abstract_inverted_index.approach | 31 |
| abstract_inverted_index.compared | 106, 176 |
| abstract_inverted_index.enabling | 34 |
| abstract_inverted_index.existing | 216 |
| abstract_inverted_index.indicate | 164 |
| abstract_inverted_index.material | 146 |
| abstract_inverted_index.observed | 114 |
| abstract_inverted_index.refining | 215 |
| abstract_inverted_index.requires | 21 |
| abstract_inverted_index.research | 209 |
| abstract_inverted_index.reversed | 104 |
| abstract_inverted_index.shearing | 62 |
| abstract_inverted_index.strategy | 213 |
| abstract_inverted_index.defective | 73 |
| abstract_inverted_index.densified | 100, 145, 174, 196 |
| abstract_inverted_index.diffusion | 185, 191 |
| abstract_inverted_index.enhancing | 221 |
| abstract_inverted_index.mixtures. | 161 |
| abstract_inverted_index.promising | 212 |
| abstract_inverted_index.resulting | 44 |
| abstract_inverted_index.structure | 172 |
| abstract_inverted_index.Simulation | 162 |
| abstract_inverted_index.attributed | 198 |
| abstract_inverted_index.developed, | 33 |
| abstract_inverted_index.frameworks | 2 |
| abstract_inverted_index.impressive | 148 |
| abstract_inverted_index.innovative | 30 |
| abstract_inverted_index.intriguing | 47 |
| abstract_inverted_index.introduces | 210 |
| abstract_inverted_index.materials, | 220 |
| abstract_inverted_index.originally | 88 |
| abstract_inverted_index.processes. | 24 |
| abstract_inverted_index.remarkable | 82 |
| abstract_inverted_index.separation | 223 |
| abstract_inverted_index.tetragonal | 171 |
| abstract_inverted_index.accelerated | 188 |
| abstract_inverted_index.adsorption, | 20 |
| abstract_inverted_index.challenges, | 28 |
| abstract_inverted_index.contraction | 68 |
| abstract_inverted_index.efficiently | 5 |
| abstract_inverted_index.experiments | 156 |
| abstract_inverted_index.flexibility | 38 |
| abstract_inverted_index.hydrocarbon | 19, 52 |
| abstract_inverted_index.saturation, | 15 |
| abstract_inverted_index.selectivity | 97 |
| abstract_inverted_index.separation, | 149 |
| abstract_inverted_index.Experimental | 183 |
| abstract_inverted_index.breakthrough | 155 |
| abstract_inverted_index.engineering, | 43 |
| abstract_inverted_index.hydrocarbons | 7, 193 |
| abstract_inverted_index.improvements | 113 |
| abstract_inverted_index.performance. | 224 |
| abstract_inverted_index.preferential | 18 |
| abstract_inverted_index.selectivity, | 85 |
| abstract_inverted_index.selectivity. | 53 |
| abstract_inverted_index.densification | 40, 58 |
| abstract_inverted_index.interparticle | 206 |
| abstract_inverted_index.recyclability | 152 |
| abstract_inverted_index.regeneration, | 150 |
| abstract_inverted_index.significantly | 103 |
| abstract_inverted_index.‐selective. | 95 |
| abstract_inverted_index.transformation | 83 |
| abstract_inverted_index.Metal–organic | 1 |
| abstract_inverted_index.energy‐intensive | 22 |
| abstract_inverted_index.adsorption–desorption | 23 |
| abstract_inverted_index.hydrocarbon‐selective | 89 |
| cited_by_percentile_year.max | 100 |
| cited_by_percentile_year.min | 96 |
| corresponding_author_ids | https://openalex.org/A5111815620, https://openalex.org/A5064451037 |
| countries_distinct_count | 2 |
| institutions_distinct_count | 12 |
| corresponding_institution_ids | https://openalex.org/I180949307, https://openalex.org/I4210111873, https://openalex.org/I84524832 |
| sustainable_development_goals[0].id | https://metadata.un.org/sdg/7 |
| sustainable_development_goals[0].score | 0.5699999928474426 |
| sustainable_development_goals[0].display_name | Affordable and clean energy |
| citation_normalized_percentile.value | 0.95287024 |
| citation_normalized_percentile.is_in_top_1_percent | False |
| citation_normalized_percentile.is_in_top_10_percent | True |