Ultra-sensitive ethanol detection using a chemiresistive SnO2 thin-film gas sensor functionalized with RuO2 nanosheets Article Swipe
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· 2025
· Open Access
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· DOI: https://doi.org/10.1038/s41378-025-01055-6
· OA: W4415979055
This study presents the design and fabrication of a ruthenium dioxide (RuO<sub>2</sub>) nanosheets-functionalized tin dioxide (SnO<sub>2</sub>) thin-film gas sensor integrated with a microheater in a suspended membrane structure. The RuO<sub>2</sub> nanosheets are synthesized via an intercalation-driven exfoliation process and subsequently deposited onto a sputtered SnO<sub>2</sub> thin film. Due to the catalytic properties and high surface-to-volume ratio of RuO<sub>2</sub> nanosheets, the functionalized sensor demonstrates a 337% increase in response (R<sub>air</sub>/R<sub>gas</sub>) to 10 ppm ethanol compared to pristine SnO<sub>2</sub> thin film. The sensor achieves sensitive detection from a few parts-per-million (ppm) down to several parts-per-billion (ppb) concentrations of ethanol. Evaluations under varied humidity conditions, as well as selectivity and 28-day stability tests, demonstrate that the RuO<sub>2</sub> nanosheets-functionalized sensor maintains reliable performance. These results highlight its potential as a sensitive, selective, and low-power solution for ethanol gas detection. Furthermore, the sensor successfully tracks breath alcohol concentration in real-time through controlled alcohol intake experiments, demonstrating its feasibility for practical breath alcohol detection.
