Understanding and Controlling Photothermal Responses in MXenes Article Swipe
YOU?
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· 2023
· Open Access
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· DOI: https://doi.org/10.1021/acs.nanolett.2c05001
MXenes have the potential for efficient light-to-heat conversion in photothermal applications. To effectively utilize MXenes in such applications, it is important to understand the underlying nonequilibrium processes, including electron-phonon and phonon-phonon couplings. Here, we use transient electron and X-ray diffraction to investigate the heating and cooling of photoexcited MXenes at femtosecond to nanosecond time scales. Our results show extremely strong electron-phonon coupling in Ti3C2-based MXenes, resulting in lattice heating within a few hundred femtoseconds. We also systematically study heat dissipation in MXenes with varying film thicknesses, chemical surface terminations, flake sizes, and annealing conditions. We find that the thermal boundary conductance (TBC) governs the thermal relaxation in films thinner than the optical penetration depth. We achieve a 2-fold enhancement of the TBC, reaching 20 MW m-2 K-1, by controlling the flake size or chemical surface termination, which is promising for engineering heat dissipation in photothermal and thermoelectric applications of the MXenes.
Related Topics
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1021/acs.nanolett.2c05001
- OA Status
- green
- Cited By
- 45
- References
- 69
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4324129530
Raw OpenAlex JSON
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https://openalex.org/W4324129530Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1021/acs.nanolett.2c05001Digital Object Identifier
- Title
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Understanding and Controlling Photothermal Responses in MXenesWork title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2023Year of publication
- Publication date
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2023-03-14Full publication date if available
- Authors
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Burak Güzeltürk, Vladislav Kamysbayev, Di Wang, Huicheng Hu, Ruiyu Li, Sarah B. King, Alexander H. Reid, Ming‐Fu Lin, Xijie Wang, Donald A. Walko, Xiaoyi Zhang, Aaron M. Lindenberg, Dmitri V. TalapinList of authors in order
- Landing page
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https://doi.org/10.1021/acs.nanolett.2c05001Publisher landing page
- Open access
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YesWhether a free full text is available
- OA status
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greenOpen access status per OpenAlex
- OA URL
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https://www.osti.gov/biblio/1997366Direct OA link when available
- Concepts
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MXenes, Materials science, Photothermal therapy, Femtosecond, Phonon, Optoelectronics, Electron, Chemical physics, Nanotechnology, Condensed matter physics, Optics, Chemistry, Physics, Laser, Quantum mechanicsTop concepts (fields/topics) attached by OpenAlex
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45Total citation count in OpenAlex
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2025: 20, 2024: 18, 2023: 7Per-year citation counts (last 5 years)
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69Number of works referenced by this work
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-
10Other works algorithmically related by OpenAlex
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