Unusually High Occupation of Co 3d State in Magnetic Weyl Semimetal Co3Sn2S2 Article Swipe
YOU?
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· 2025
· Open Access
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· DOI: https://doi.org/10.1021/acsnano.4c13750
The physical properties of magnetic topological materials are strongly influenced by their nontrivial band topology coupled with the magnetic structure. Co3Sn2S2 is a ferromagnetic kagome Weyl semimetal displaying giant intrinsic anomalous Hall effect which can be further tuned via elemental doping, such as Ni substitution for Co. Despite significant interest, the exact valency of Co and the magnetic order of the Ni dopants remained unclear. Here, we report a study of Ni-doped Co3Sn2S2 single crystals using synchrotron-based X-ray magnetic circular dichroism (XMCD), X-ray photoelectron emission microscopy (XPEEM), and hard/soft X-ray photoemission spectroscopy (XPS) techniques. We confirm the presence of spin-dominated magnetism from Co in the host material, and also the establishment of ferromagnetic order from the Ni dopant. The oxygen-free photoemission spectrum of the Co 2p core levels in the crystal well resembles that of a metallic Co film, indicating a Co0+ valency. Surprisingly, we find the electron filling in the Co 3d state can reach 8.7-9.0 electrons in these single crystals. Our results highlight the importance of element-specific X-ray spectroscopy in understanding the electronic and magnetic properties that are fundamental to a heavily studied Weyl semimetal, which could aid in developing future spintronic applications based on magnetic topological materials.
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- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1021/acsnano.4c13750
- https://pubs.acs.org/doi/pdf/10.1021/acsnano.4c13750?ref=article_openPDF
- OA Status
- hybrid
- Cited By
- 3
- References
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- Related Works
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- OpenAlex ID
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https://openalex.org/W4407928364Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1021/acsnano.4c13750Digital Object Identifier
- Title
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Unusually High Occupation of Co 3d State in Magnetic Weyl Semimetal Co3Sn2S2Work title
- Type
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articleOpenAlex work type
- Language
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enPrimary language
- Publication year
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2025Year of publication
- Publication date
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2025-02-25Full publication date if available
- Authors
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Jieyi Liu, Yiheng Yang, Jianlei Shen, Defa Liu, Gohil S. Thakur, Charles Guillemard, Alevtina Smekhova, Houke Chen, Deepnarayan Biswas, Manuel Valvidares, Enke Liu, Claudia Felser, Tien-Lin Lee, T. Hesjedal, Yulin Chen, G. van der LaanList of authors in order
- Landing page
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https://doi.org/10.1021/acsnano.4c13750Publisher landing page
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https://pubs.acs.org/doi/pdf/10.1021/acsnano.4c13750?ref=article_openPDFDirect link to full text PDF
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YesWhether a free full text is available
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hybridOpen access status per OpenAlex
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https://pubs.acs.org/doi/pdf/10.1021/acsnano.4c13750?ref=article_openPDFDirect OA link when available
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Weyl semimetal, Semimetal, Materials science, Condensed matter physics, Physics, Band gapTop concepts (fields/topics) attached by OpenAlex
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3Total citation count in OpenAlex
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2025: 3Per-year citation counts (last 5 years)
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58Number of works referenced by this work
- Related works (count)
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10Other works algorithmically related by OpenAlex
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| abstract_inverted_index.electrons | 157 |
| abstract_inverted_index.elemental | 39 |
| abstract_inverted_index.hard/soft | 88 |
| abstract_inverted_index.highlight | 164 |
| abstract_inverted_index.interest, | 49 |
| abstract_inverted_index.intrinsic | 29 |
| abstract_inverted_index.magnetism | 100 |
| abstract_inverted_index.material, | 106 |
| abstract_inverted_index.materials | 6 |
| abstract_inverted_index.resembles | 132 |
| abstract_inverted_index.semimetal | 26 |
| abstract_inverted_index.developing | 191 |
| abstract_inverted_index.displaying | 27 |
| abstract_inverted_index.electronic | 174 |
| abstract_inverted_index.importance | 166 |
| abstract_inverted_index.indicating | 139 |
| abstract_inverted_index.influenced | 9 |
| abstract_inverted_index.materials. | 199 |
| abstract_inverted_index.microscopy | 85 |
| abstract_inverted_index.nontrivial | 12 |
| abstract_inverted_index.properties | 2, 177 |
| abstract_inverted_index.semimetal, | 186 |
| abstract_inverted_index.spintronic | 193 |
| abstract_inverted_index.structure. | 19 |
| abstract_inverted_index.fundamental | 180 |
| abstract_inverted_index.oxygen-free | 119 |
| abstract_inverted_index.significant | 48 |
| abstract_inverted_index.techniques. | 93 |
| abstract_inverted_index.topological | 5, 198 |
| abstract_inverted_index.applications | 194 |
| abstract_inverted_index.spectroscopy | 91, 170 |
| abstract_inverted_index.substitution | 44 |
| abstract_inverted_index.Surprisingly, | 143 |
| abstract_inverted_index.establishment | 110 |
| abstract_inverted_index.ferromagnetic | 23, 112 |
| abstract_inverted_index.photoelectron | 83 |
| abstract_inverted_index.photoemission | 90, 120 |
| abstract_inverted_index.understanding | 172 |
| abstract_inverted_index.spin-dominated | 99 |
| abstract_inverted_index.Co<sup>0+</sup> | 141 |
| abstract_inverted_index.element-specific | 168 |
| abstract_inverted_index.synchrotron-based | 76 |
| abstract_inverted_index.Co<sub>3</sub>Sn<sub>2</sub>S<sub>2</sub> | 20, 72 |
| cited_by_percentile_year.max | 97 |
| cited_by_percentile_year.min | 96 |
| corresponding_author_ids | https://openalex.org/A5080044000, https://openalex.org/A5029731283 |
| countries_distinct_count | 5 |
| institutions_distinct_count | 16 |
| corresponding_institution_ids | https://openalex.org/I2802711169, https://openalex.org/I40120149 |
| citation_normalized_percentile.value | 0.95177574 |
| citation_normalized_percentile.is_in_top_1_percent | False |
| citation_normalized_percentile.is_in_top_10_percent | True |