Update on chiral recognition mechanisms in separation science Article Swipe
The stereospecific analysis of chiral molecules is an important issue in many scientific fields. In separation sciences, this is achieved via the formation of transient diastereomeric complexes between a chiral selector and the selectand enantiomers driven by molecular interactions including electrostatic, ion‐dipole, dipole‐dipole, van der Waals or π‐π interactions as well as hydrogen or halogen bonds depending on the nature of selector and selectand. Nuclear magnetic resonance spectroscopy and molecular modeling methods are currently the most frequently applied techniques to understand the selector‐selectand interactions at a molecular level and to draw conclusions on the chiral separation mechanism. The present short review summarizes some of the recent achievements for the understanding of the chiral recognition of the most important chiral selectors combining separation techniques with molecular modeling and/or spectroscopic techniques dating between 2020 and early 2024. The selectors include polysaccharide derivatives, cyclodextrins, macrocyclic glycopeptides, proteins, donor‐acceptor type selectors, ion‐exchangers, crown ethers, and molecular micelles. The application of chiral ionic liquids and chiral deep eutectic solvents, as well as further selectors, are also briefly addressed. A compilation of all published literature on chiral selectors has not been attempted.
Related Topics
Concepts
Chemistry
Molecular recognition
Enantiomer
Diastereomer
van der Waals force
Supramolecular chemistry
Non-covalent interactions
Computational chemistry
Chirality (physics)
Molecule
Hydrogen bond
Chemical physics
Combinatorial chemistry
Organic chemistry
Chiral symmetry breaking
Quark
Nambu–Jona-Lasinio model
Quantum mechanics
Physics
Metadata
- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1002/jssc.202400148
- https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/jssc.202400148
- OA Status
- bronze
- Cited By
- 31
- References
- 184
- Related Works
- 10
- OpenAlex ID
- https://openalex.org/W4398221237
All OpenAlex metadata
Raw OpenAlex JSON
- OpenAlex ID
-
https://openalex.org/W4398221237Canonical identifier for this work in OpenAlex
- DOI
-
https://doi.org/10.1002/jssc.202400148Digital Object Identifier
- Title
-
Update on chiral recognition mechanisms in separation scienceWork title
- Type
-
articleOpenAlex work type
- Language
-
enPrimary language
- Publication year
-
2024Year of publication
- Publication date
-
2024-05-01Full publication date if available
- Authors
-
Gerhard K. E. ScribaList of authors in order
- Landing page
-
https://doi.org/10.1002/jssc.202400148Publisher landing page
- PDF URL
-
https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/jssc.202400148Direct link to full text PDF
- Open access
-
YesWhether a free full text is available
- OA status
-
bronzeOpen access status per OpenAlex
- OA URL
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https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/jssc.202400148Direct OA link when available
- Concepts
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Chemistry, Molecular recognition, Enantiomer, Diastereomer, van der Waals force, Supramolecular chemistry, Non-covalent interactions, Computational chemistry, Chirality (physics), Molecule, Hydrogen bond, Chemical physics, Combinatorial chemistry, Organic chemistry, Chiral symmetry breaking, Quark, Nambu–Jona-Lasinio model, Quantum mechanics, PhysicsTop concepts (fields/topics) attached by OpenAlex
- Cited by
-
31Total citation count in OpenAlex
- Citations by year (recent)
-
2025: 28, 2024: 3Per-year citation counts (last 5 years)
- References (count)
-
184Number of works referenced by this work
- Related works (count)
-
10Other works algorithmically related by OpenAlex
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