Wake-up-free properties and high fatigue resistance of HfxZr1−xO2-based metal–ferroelectric–semiconductor using top ZrO2 nucleation layer at low thermal budget (300 °C) Article Swipe
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· 2022
· Open Access
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· DOI: https://doi.org/10.1063/5.0091661
Ferroelectricity and crystallinity of TiN/ZrO2/HfxZr1−xO2 (Hf:Zr = 0.43:0.57; HZO)/SiO2/Si metal–ferroelectric–semiconductor (MFS) capacitors with a top ZrO2 nucleation layer fabricated by low-temperature processes at 300 °C of atomic layer deposition and post-metallization annealing (PMA) were systematically investigated. The HZO (10 nm)-based MFS capacitors without (w/o) and with 2- and 10-nm-thick ZrO2 films (ZrO2-2 nm and ZrO2-10 nm, respectively) were found to form an extremely thin SiO2 interfacial layer (SiO2-IL) with a thickness of one or two monolayers. The HZO film in the TiN/ZrO2/HZO/SiO2/Si capacitors formed the ferroelectric orthorhombic phase even with a low thermal budget of 300 °C; in contrast, that of the w/o capacitor exhibited a predominantly amorphous structure. This result is attributed to the polycrystalline ZrO2 film acting as a nucleation layer for the crystallization of an amorphous HZO film during PMA treatment. Therefore, the remnant polarization (2Pr) increased in the order of w/o (2.2 µC/cm2) < ZrO2-2 nm (6.8 µC/cm2) < ZrO2-10 nm (15 µC/cm2). The endurance properties of the ZrO2-10 nm capacitor were free from the wake-up effect and exhibited less degradation because of the insertion of a thick ZrO2 film of 10 nm at the TiN/HZO interface, which promoted the preferential formation of the ferroelectric orthorhombic phase and prevented the formation of oxygen vacancies at the ZrO2/HZO interface. These results suggest that superior ferroelectricity with wake-up-free properties and higher fatigue resistance of HZO-based MFS capacitors can be achieved by a low-temperature fabrication technique (300 °C) using a top ZrO2 nucleation layer.
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- Type
- article
- Language
- en
- Landing Page
- https://doi.org/10.1063/5.0091661
- https://aip.scitation.org/doi/pdf/10.1063/5.0091661
- OA Status
- gold
- Cited By
- 36
- References
- 50
- Related Works
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- OpenAlex ID
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https://openalex.org/W4280636802Canonical identifier for this work in OpenAlex
- DOI
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https://doi.org/10.1063/5.0091661Digital Object Identifier
- Title
-
Wake-up-free properties and high fatigue resistance of HfxZr1−xO2-based metal–ferroelectric–semiconductor using top ZrO2 nucleation layer at low thermal budget (300 °C)Work title
- Type
-
articleOpenAlex work type
- Language
-
enPrimary language
- Publication year
-
2022Year of publication
- Publication date
-
2022-05-01Full publication date if available
- Authors
-
Takashi Onaya, Toshihide Nabatame, Mari Inoue, Tomomi Sawada, Hiroyuki Ota, Yukinori MoritaList of authors in order
- Landing page
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https://doi.org/10.1063/5.0091661Publisher landing page
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https://aip.scitation.org/doi/pdf/10.1063/5.0091661Direct link to full text PDF
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YesWhether a free full text is available
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goldOpen access status per OpenAlex
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https://aip.scitation.org/doi/pdf/10.1063/5.0091661Direct OA link when available
- Concepts
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Materials science, Ferroelectricity, Tin, Amorphous solid, Orthorhombic crystal system, Nucleation, Crystallite, Crystallinity, Crystallization, Annealing (glass), Capacitor, Dielectric, Analytical Chemistry (journal), Optoelectronics, Composite material, Crystallography, Crystal structure, Chemical engineering, Metallurgy, Chemistry, Quantum mechanics, Physics, Voltage, Engineering, Organic chemistry, ChromatographyTop concepts (fields/topics) attached by OpenAlex
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36Total citation count in OpenAlex
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2025: 12, 2024: 10, 2023: 10, 2022: 4Per-year citation counts (last 5 years)
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50Number of works referenced by this work
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10Other works algorithmically related by OpenAlex
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