Alexander Hinz
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View article: Silicon‐Based Azo Compound‐Mediated CO Activation and N <sub>2</sub> Release
Silicon‐Based Azo Compound‐Mediated CO Activation and N <sub>2</sub> Release Open
Silicon‐substituted azo compounds featuring Si─N═N─Si linkages remain elusive in main‐group chemistry. Herein, we report the synthesis of a silicon‐based azo compound generated directly from a mixed‐valent silaiminyl–silylene precursor and…
View article: Silicon‐Based Azo Compound‐Mediated CO Activation and N <sub>2</sub> Release
Silicon‐Based Azo Compound‐Mediated CO Activation and N <sub>2</sub> Release Open
Silicon‐substituted azo compounds featuring Si─N═N─Si linkages remain elusive in main‐group chemistry. Herein, we report the synthesis of a silicon‐based azo compound generated directly from a mixed‐valent silaiminyl–silylene precursor and…
View article: Di- and trivalent Bis(stannolediides) of Dysprosium and Terbium: A novel class of High-Performance Single Molecule Magnets
Di- and trivalent Bis(stannolediides) of Dysprosium and Terbium: A novel class of High-Performance Single Molecule Magnets Open
Two isostructural homoleptic η5-stannole complexes of trivalent lanthanides [Ln(η5-LSn)2K(thf)4], where Ln = Tb, Dy and LSn = [1,4-bis-(tert-butyl-dimethylsilyl)-2,3-bis-phenyl-stannolediide], have been synthesized via salt metathesis of t…
View article: Stabilisation of a Strontium Hydride with a Monodentate Carbazolyl Ligand and its Reactivity
Stabilisation of a Strontium Hydride with a Monodentate Carbazolyl Ligand and its Reactivity Open
The molecular strontium hydride 2 [( dtbp Cbz)SrH(L)] 2 (L=benzene, toluene) was isolated and stabilized by employing a sterically demanding carbazole ligand ( dtbp Cbz=1,8‐bis(3,5‐ditertbutylphenyl)‐3,6‐ditertbutylcarbazolyl). Compound 2 …
View article: Divalent Lanthanide Hydride Complexes
Divalent Lanthanide Hydride Complexes Open
Molecular hydride complexes have attracted recent attention, and divalent lanthanides as central atoms in particular are very interesting. They open up possibilities of combining hydride reactivity and lanthanide reactivity. To date, only …
View article: De‐ and Rearomatisation of Pyridine in Silylene Chemistry
De‐ and Rearomatisation of Pyridine in Silylene Chemistry Open
Traditional methods relying on metal‐ligand cooperation for activating pyridine bonds in de‐ and rearomatisation are being challenged by the abundant metal‐free element species as alternatives. Here, we investigated the de/re‐aromatisation…
View article: Silylenes with a Small Chalcogenide Substituent: Tuning Frontier Orbital Energies from O to Te
Silylenes with a Small Chalcogenide Substituent: Tuning Frontier Orbital Energies from O to Te Open
The general synthesis of heteroleptic acyclic silylenes with a bulky carbazolyl substituent ( dtbp Cbz) is detailed and a series of compounds with a chalcogenide substituent of the type [( dtbp Cbz)SiE 16 R] (E 16 R=O t Bu, SEt, SePh, TePh…
View article: Cation‐Dependent Nuclearity of New Homoleptic Azidocuprates(II), From Discrete Ions to Anionic Strands and Sheets
Cation‐Dependent Nuclearity of New Homoleptic Azidocuprates(II), From Discrete Ions to Anionic Strands and Sheets Open
In chemical reactions of copper(II) acetate dihydrate with imidazolium azide salts in ethanol solution several new homoleptic azidocuprates(II) were obtained. In dependency of the used counter cation various different azidocuprate moieties…
View article: CO reduction by calcium and ytterbium hydride complexes with a bulky monodentate carbazolyl ligand
CO reduction by calcium and ytterbium hydride complexes with a bulky monodentate carbazolyl ligand Open
Calcium and ytterbium hydrides supported by a monodentate carbazolyl ligand show three characteristic M 2 H 2 vibrations and reacted with carbon monoxide.
View article: Reactivities of phosphaalkynes towards diverse bis-silylenes
Reactivities of phosphaalkynes towards diverse bis-silylenes Open
The reactivity between different bis-silylenes and the phosphaalkyne t BuCP was investigated, which has expanded the synthetic possibilities of Si–P-containing heterocycles.
View article: CCDC 2285932: Experimental Crystal Structure Determination
CCDC 2285932: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2285935: Experimental Crystal Structure Determination
CCDC 2285935: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2285936: Experimental Crystal Structure Determination
CCDC 2285936: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2285933: Experimental Crystal Structure Determination
CCDC 2285933: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2285934: Experimental Crystal Structure Determination
CCDC 2285934: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2264936: Experimental Crystal Structure Determination
CCDC 2264936: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2264938: Experimental Crystal Structure Determination
CCDC 2264938: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2264949: Experimental Crystal Structure Determination
CCDC 2264949: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2264934: Experimental Crystal Structure Determination
CCDC 2264934: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2264953: Experimental Crystal Structure Determination
CCDC 2264953: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2264955: Experimental Crystal Structure Determination
CCDC 2264955: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2265192: Experimental Crystal Structure Determination
CCDC 2265192: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2264954: Experimental Crystal Structure Determination
CCDC 2264954: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2264939: Experimental Crystal Structure Determination
CCDC 2264939: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2264950: Experimental Crystal Structure Determination
CCDC 2264950: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2264937: Experimental Crystal Structure Determination
CCDC 2264937: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2264948: Experimental Crystal Structure Determination
CCDC 2264948: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2264935: Experimental Crystal Structure Determination
CCDC 2264935: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2264951: Experimental Crystal Structure Determination
CCDC 2264951: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …