Alain Dedieu
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View article: Stereospecific Reaction of Molecular Halogens with Palladacyclopentadienes Containing Bidentate Nitrogen Ligands To Give 1,4-Dihalo-1,3-dienes via Palladium(IV) Intermediates
Stereospecific Reaction of Molecular Halogens with Palladacyclopentadienes Containing Bidentate Nitrogen Ligands To Give 1,4-Dihalo-1,3-dienes via Palladium(IV) Intermediates Open
A synthetic and computational study concerning the reactivity of palladacyclopentadienes containing bidentate nitrogen ligands toward dihalogens is described. The complexes 2,3,4,5-tetrakis(carbomethoxy)palladacyclopentadiene(NN) (1a−c; NN…
View article: CCDC 206170: Experimental Crystal Structure Determination
CCDC 206170: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 206169: Experimental Crystal Structure Determination
CCDC 206169: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 157516: Experimental Crystal Structure Determination
CCDC 157516: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 157515: Experimental Crystal Structure Determination
CCDC 157515: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 157514: Experimental Crystal Structure Determination
CCDC 157514: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: σ-Bond Metathesis Reactions Involving Palladium(II) Hydride and Methyl Complexes: A Theoretical Assessment
σ-Bond Metathesis Reactions Involving Palladium(II) Hydride and Methyl Complexes: A Theoretical Assessment Open
sigma-Bond metathesis reactions of water and methanol with palladium hydride and methyl complexes to yield hydrogen and methane, respectively, have been studied using ab-initio molecular orbital methods at the second-order Møller-Plesset (…
View article: Synthesis and Theoretical Studies of a Diorganohydridoplatinum(IV) Complex, PtHMe<sub>2</sub>{(pz)<sub>3</sub>BH-<i>N</i>,<i>N‘</i>,<i>N‘‘</i>} ([(pz)<sub>3</sub>BH]<sup>-</sup> = Tris(pyrazol-1-yl)borate)
Synthesis and Theoretical Studies of a Diorganohydridoplatinum(IV) Complex, PtHMe<sub>2</sub>{(pz)<sub>3</sub>BH-<i>N</i>,<i>N‘</i>,<i>N‘‘</i>} ([(pz)<sub>3</sub>BH]<sup>-</sup> = Tris(pyrazol-1-yl)borate) Open
The platinum(II) tris(pyrazol-1-yl)borate complex [PtMe 2{(pz) 3BH-N1N}] - reacts with phenol or aqueous HBF 4 in acetone to form the dimethylhydridoplatinum(IV) complex PtHMe 2{(pz) 3BH-N,N,N}. The complex decomposes above 140 C in toluen…
View article: High-Pressure NMR and ab Initio Computational Studies on the Insertion Mechanism of Carbon Monoxide into Cationic Monoorganopalladium(II) Complexes Bearing Tridentate Nitrogen Donor Ligands
High-Pressure NMR and ab Initio Computational Studies on the Insertion Mechanism of Carbon Monoxide into Cationic Monoorganopalladium(II) Complexes Bearing Tridentate Nitrogen Donor Ligands Open
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTHigh-Pressure NMR and ab Initio Computational Studies on the Insertion Mechanism of Carbon Monoxide into Cationic Monoorganopalladium(II) Complexes Bearing Tridentate Nitrogen Donor LigandsBertus…
View article: Rhizobium meliloti elicits transient expression of the early nodulin gene ENOD12 in the differentiating root epidermis of transgenic alfalfa.
Rhizobium meliloti elicits transient expression of the early nodulin gene ENOD12 in the differentiating root epidermis of transgenic alfalfa. Open
To study the molecular responses of the host legume during early stages of the symbiotic interaction with Rhizobium, we have cloned and characterized the infection-related early nodulin gene MtENOD12 from Medicago truncatula. In situ hybri…
View article: Synthesis of a 125I-labelled derivative of the antibiotic griseofulvin.
Synthesis of a 125I-labelled derivative of the antibiotic griseofulvin. Open
A derivative of griseofulvin has been synthesised, in which the 2'-O-methyl group is replaced by a 2'-(2-iodoethoxy), 125I-labelled group. This derivative is at least as potent as griseofulvin itself, when assayed for inhibition of growth …