Alan J. Lough
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View article: CCDC 2473289: Experimental Crystal Structure Determination
CCDC 2473289: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Impressive 1D (Ferrocenyl⋯C6F5R⋯)n Stacking Due to Cooperative Interactions in N-(Ferrocenylmethyl)Pentafluorobenzenecarboxamide: Four Crystal Structures and Contacts Analyses in N-(Ferrocenylalkyl)Benzenecarboxamides
Impressive 1D (Ferrocenyl⋯C6F5R⋯)n Stacking Due to Cooperative Interactions in N-(Ferrocenylmethyl)Pentafluorobenzenecarboxamide: Four Crystal Structures and Contacts Analyses in N-(Ferrocenylalkyl)Benzenecarboxamides Open
The crystal structures, interactions, and contacts analyses of four N-(ferrocenylalkyl)benzene-carboxamide derivatives are described as the N-(ferrocenylmethyl)benzenecarboxamide 4a, N-(ferrocenylmethyl)-2,6-difluorobenzenecarboxamide 4e, …
View article: Impressive 1D (FERROCENYL⋯C6F5R⋯)n Stacking Due to Cooperative Interactions in N-(Ferrocenylmethyl)pentafluorobenzenecarboxamide: Four Crystal Structures and Contacts Analyses in N-(Ferrocenylalkyl)benzenecarboxamides
Impressive 1D (FERROCENYL⋯C6F5R⋯)n Stacking Due to Cooperative Interactions in N-(Ferrocenylmethyl)pentafluorobenzenecarboxamide: Four Crystal Structures and Contacts Analyses in N-(Ferrocenylalkyl)benzenecarboxamides Open
The crystal structures, interactions and contacts analyses of four N-(ferrocenylalkyl)benzene-carboxamide derivatives are described as the N-(ferrocenylmethyl)benzene-carboxamide 4a, N-(ferrocenylmethyl)-2,6-difluorobenzenecarboxamide 4e, …
View article: A facile route to <i>cis</i>-olefin-linked phosphino-phosphonium salts of the form: [Ph<sub>2</sub>PC(R)C(H)P(R′)<sub>2</sub>H][AlCl<sub>4</sub>]
A facile route to <i>cis</i>-olefin-linked phosphino-phosphonium salts of the form: [Ph<sub>2</sub>PC(R)C(H)P(R′)<sub>2</sub>H][AlCl<sub>4</sub>] Open
Diphenylphosphirenium salts [Ph 2 PC(R)C(H)][AlCl 4 ] react with sterically hindered secondary phosphines to give dissymmetric bidentate phosphonium salts, [Ph 2 PC(R)C(H)P(R′) 2 H][AlCl 4 ].
View article: The influence of the axial group on the crystal structures of boron subphthalocyanines
The influence of the axial group on the crystal structures of boron subphthalocyanines Open
The crystal structures of 16 boron subphthalocyanines (BsubPcs) with structurally diverse axial groups were analyzed and compared to elucidate the impact of the axial group on the intermolecular π–π interactions, axial-group interactions, …
View article: Hypercoordinating Stannanes with C,N-Donor Ligands: A Structural, Computational, and Polymerization Study
Hypercoordinating Stannanes with C,N-Donor Ligands: A Structural, Computational, and Polymerization Study Open
Select triphenyl stannanes bearing either a formally sp2 or sp3 hybridized amine, viz 2-(pyC2H4)SnPh3 (2: py = pyridinyl), 4-(pyC2H4)SnPh3 (3), 2-(pzC2H4)SnPh3 (4: pz = pyrazyl), and Me2N(CH2)3SnPh3 (6), were prepared and characterized by …
View article: Mechanochemical Synthesis of Chromium(III) Complexes Containing Bidentate PN and Tridentate P-NH-P and P-NH-P′ Ligands
Mechanochemical Synthesis of Chromium(III) Complexes Containing Bidentate PN and Tridentate P-NH-P and P-NH-P′ Ligands Open
Chromium(III) complexes bearing bidentate {NH2(CH2)2PPh2: PN, (S,S)-[NH2(CHPh)2PPh2]: P'N} and tridentate [Ph2P(CH2)2N(H)(CH2)2PPh2: P-NH-P, (S,S)-(iPr)2PCH2CH2N(H)CH(Ph)CH(Ph)PPh2: P-NH-P'] ligands have been synthesized using a mechanoche…
View article: Bulking Up the Bay-Position Substituents Enables Enhanced Selectivity of <i>C</i><sub><i>s</i></sub>-Symmetric Boron Subphthalocyanine–Subnaphthalocyanine Hybrids
Bulking Up the Bay-Position Substituents Enables Enhanced Selectivity of <i>C</i><sub><i>s</i></sub>-Symmetric Boron Subphthalocyanine–Subnaphthalocyanine Hybrids Open
The precise synthesis of subporphyrinoid hybrids with π-expanded topologies and unique material properties plays a promising role in the design of functional macrocycles. Easy, selective, and controllable routes to boron subphthalocyanine-…
View article: A Boron Scan of Ethyl Acetoacetate Leads to Versatile Building Blocks
A Boron Scan of Ethyl Acetoacetate Leads to Versatile Building Blocks Open
Discovered in the 19th century, ethyl acetoacetate has been central to the development of organic chemistry, including its pedagogy and applications. In this study, we present borylated derivatives of this venerable molecule. A boron handl…
View article: A Boron Scan of Ethyl Acetoacetate Leads to Versatile Building Blocks
A Boron Scan of Ethyl Acetoacetate Leads to Versatile Building Blocks Open
Discovered in the 19th century, ethyl acetoacetate has been central to the development of organic chemistry, including its pedagogy and applications. In this study, we present borylated derivatives of this venerable molecule. A boron handl…
View article: Correction: A chelated borinium cation
Correction: A chelated borinium cation Open
Correction for ‘A chelated borinium cation’ by Christopher Major et al. , Dalton Trans. , 2024, 53 , 10075–10078, https://doi.org/10.1039/D4DT01242A.
View article: CCDC 2258623: Experimental Crystal Structure Determination
CCDC 2258623: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: A S<sub>N</sub>Ar‐Active External Initiator that Enables Heterobifunctional Clickable Polythiophenes
A S<sub>N</sub>Ar‐Active External Initiator that Enables Heterobifunctional Clickable Polythiophenes Open
Poly(3‐hexylthiophene) (P3HT) is a well‐studied conjugated polymer; however, the end‐group functionalization of these polymers is limited by fundamental synthetic challenges. Generally, end‐capping agents are used to terminate the Kumada c…
View article: CCDC 2223760: Experimental Crystal Structure Determination
CCDC 2223760: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2223758: Experimental Crystal Structure Determination
CCDC 2223758: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2223759: Experimental Crystal Structure Determination
CCDC 2223759: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2223761: Experimental Crystal Structure Determination
CCDC 2223761: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2223757: Experimental Crystal Structure Determination
CCDC 2223757: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2223756: Experimental Crystal Structure Determination
CCDC 2223756: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2241960: Experimental Crystal Structure Determination
CCDC 2241960: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2194391: Experimental Crystal Structure Determination
CCDC 2194391: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2194392: Experimental Crystal Structure Determination
CCDC 2194392: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Surface-attached sulfonamide containing quaternary ammonium antimicrobials for textiles and plastics
Surface-attached sulfonamide containing quaternary ammonium antimicrobials for textiles and plastics Open
With the risks associated with healthcare-associated infections and the rise of antibiotic resistant microorganisms, there is an important need to control the proliferation of these factors in hospitals, retirement homes and other institut…
View article: Surface-attached sulfonamide containing quaternary ammonium antimicrobials for textiles and plastics
Surface-attached sulfonamide containing quaternary ammonium antimicrobials for textiles and plastics Open
With the risks associated with healthcare-associated infections and the rise of antibiotic resistant microorganisms, there is an important need to control the proliferation of these factors in hospitals, retirement homes and other institut…
View article: Surface-attached sulfonamide containing quaternary ammonium antimicrobials for textiles and plastics
Surface-attached sulfonamide containing quaternary ammonium antimicrobials for textiles and plastics Open
With the risks associated with healthcare-associated infections and the rise of antibiotic resistant microorganisms, there is an important need to control the proliferation of these factors in hospitals, retirement homes and other institut…
View article: 3-Amino-1-methylpyrazin-1-ium chloride
3-Amino-1-methylpyrazin-1-ium chloride Open
In the cation of the title compound, C5H8N3+·Cl-, the C-N(H2) bond distance [1.348 (3) Å] is at the lower end of the range for aryl amines. In the crystal structure, cations and anions are linked via N-Hhttps://scripts.iucr.org/logos/entit…
View article: N,1-Bis(4-chloro-2-methylbenzyl)-3- methyl-2-oxo-1,2,3,4-tetrahydroquinoline-3-carboxamide
N,1-Bis(4-chloro-2-methylbenzyl)-3- methyl-2-oxo-1,2,3,4-tetrahydroquinoline-3-carboxamide Open
In the title molecule, C27H26Cl2N2O2, the chloro-substituted benzene rings make dihedral angles of 83.29 (9) and 80.81 (9) with the benzene ring of the tetrahydroquinoline group. The dihedral angle formed by the two chloro-substituted ben…
View article: N,1-Bis(4-chloro-2-methylbenzyl)-3- methyl-2-oxo-1,2,3,4-tetrahydroquinoline-3-carboxamide
N,1-Bis(4-chloro-2-methylbenzyl)-3- methyl-2-oxo-1,2,3,4-tetrahydroquinoline-3-carboxamide Open
In the title molecule, C27H26Cl2N2O2, the chloro-substituted benzene rings make dihedral angles of 83.29 (9) and 80.81 (9) with the benzene ring of the tetrahydroquinoline group. The dihedral angle formed by the two chloro-substituted ben…
View article: Surface-attached sulfonamide containing quaternary ammonium antimicrobials for textiles and plastics
Surface-attached sulfonamide containing quaternary ammonium antimicrobials for textiles and plastics Open
With the risks associated with healthcare-associated infections and the rise of antibiotic resistant microorganisms, there is an important need to control the proliferation of these factors in hospitals, retirement homes and other institut…
View article: 3-Amino-1-methylpyrazin-1-ium chloride
3-Amino-1-methylpyrazin-1-ium chloride Open
In the cation of the title compound, C5H8N3+·Cl-, the C-N(H2) bond distance [1.348 (3) Å] is at the lower end of the range for aryl amines. In the crystal structure, cations and anions are linked via N-Hhttps://scripts.iucr.org/logos/entit…