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View article: High-areal capacity and binder-free thick-ceramic LFP electrodes manufactured by robocasting for Li-ion batteries
High-areal capacity and binder-free thick-ceramic LFP electrodes manufactured by robocasting for Li-ion batteries Open
View article: Powder extrusion moulding of thick all-ceramic Li4Ti5O12– carbon nanotubes electrodes for high-performance lithium-ion batteries
Powder extrusion moulding of thick all-ceramic Li4Ti5O12– carbon nanotubes electrodes for high-performance lithium-ion batteries Open
View article: From polymer electrolytes to calcium-conducting ionomers: A route towards rechargeable calcium batteries?
From polymer electrolytes to calcium-conducting ionomers: A route towards rechargeable calcium batteries? Open
International audience
View article: High-Areal Capacity and Binder-Free Thick-Ceramic Lfp Electrodes Manufactured by Robocasting for Li-Ion Batteries
High-Areal Capacity and Binder-Free Thick-Ceramic Lfp Electrodes Manufactured by Robocasting for Li-Ion Batteries Open
View article: Structure and Conductivity of Crosslinked Ca‐POE Polymer Electrolytes for Secondary Batteries
Structure and Conductivity of Crosslinked Ca‐POE Polymer Electrolytes for Secondary Batteries Open
Poly(oxyethylene) (POE) is frequently used as suitable component to prepare solid polymer electrolytes (SPEs), due to its: (i) ability to coordinate and dissociate doping salts; (ii) good mechanical properties; and (iii) high chemical and …
View article: Block Copolymer-Based Membranes for Vanadium Redox Flow Batteries: Synthesis, Characterization, and Performance
Block Copolymer-Based Membranes for Vanadium Redox Flow Batteries: Synthesis, Characterization, and Performance Open
Nonfluorinated polymers have been widely proposed to replace Nafion as raw materials for redox flow battery ion-exchange membranes. Hereby, block copolymers based on polysulfone (PSU) and polyphenylsulfone (PPSU) are synthesized and employ…
View article: Optimisation of powder extrusion moulding process for thick ceramic electrodes of LiCoO2 for enhanced energy-density lithium-ion batteries
Optimisation of powder extrusion moulding process for thick ceramic electrodes of LiCoO2 for enhanced energy-density lithium-ion batteries Open
Lithium-ion batteries are widely used in portable electronic devices because of their high energy and power density. To enhance the energy density of these batteries, one strategy involves increasing the active material loading by increasi…
View article: Modelling Li-V2O5 Batteries Using Galvanostatic Intermittent Titration Technique and Electrochemical Impedance Spectroscopy: Towards Final Applications
Modelling Li-V2O5 Batteries Using Galvanostatic Intermittent Titration Technique and Electrochemical Impedance Spectroscopy: Towards Final Applications Open
Given the relevance of lithium and post-lithium batteries as electrochemical energy storage systems, the peculiar crystalline structure of V2O5 and its doping capacity play key roles in lithium-ion battery technology. To integrate them in …
View article: Roadmap on multivalent batteries
Roadmap on multivalent batteries Open
Battery technologies based in multivalent charge carriers with ideally two or three electrons transferred per ion exchanged between the electrodes have large promises in raw performance numbers, most often expressed as high energy density,…
View article: Na<sub>3</sub>V<sub>2</sub>(PO<sub>4</sub>)<sub>3</sub> Cathode for Room-Temperature Solid-State Sodium-Ion Batteries: Advanced <i>In Situ</i> Synchrotron X-ray Studies to Understand Intermediate Phase Evolution
Na<sub>3</sub>V<sub>2</sub>(PO<sub>4</sub>)<sub>3</sub> Cathode for Room-Temperature Solid-State Sodium-Ion Batteries: Advanced <i>In Situ</i> Synchrotron X-ray Studies to Understand Intermediate Phase Evolution Open
Sodium-ion batteries (NIBs) can use elements that are abundantly present in Earth's crust and are technologically feasible for replacing lithium-ion batteries (LIBs). Hence, NIBs are essential components for sustainable energy storage appl…
View article: Advancements in Quasi-Solid-State Li Batteries: A Rigid Hybrid Electrolyte Using LATP Porous Ceramic Membrane and Infiltrated Ionic Liquid
Advancements in Quasi-Solid-State Li Batteries: A Rigid Hybrid Electrolyte Using LATP Porous Ceramic Membrane and Infiltrated Ionic Liquid Open
Despite the progress made in Li-ion battery components, technology still faces major challenges. Among them, the development of novel electrolytes with promising characteristics is required for next-generation energy storage devices. In th…
View article: Life cycle assessment of lab-scale solid sodium-ion batteries: A sustainable alternative to liquid lithium-ion batteries
Life cycle assessment of lab-scale solid sodium-ion batteries: A sustainable alternative to liquid lithium-ion batteries Open
This study presents a comprehensive life cycle assessment (LCA) of liquid lithium-ion batteries (liquid LIB), liquid sodium-ion batteries (liquid SIB), and solid sodium-ion batteries (solid SIB) to evaluate their environmental impacts in a…
View article: Spray Drying Technique as a method for improving Rheology of Alumina Feedstocks for Powder Injection Moulding
Spray Drying Technique as a method for improving Rheology of Alumina Feedstocks for Powder Injection Moulding Open
View article: A Comprehensive Study of Mil-88a as a Key Component of Hybrid Polymer Electrolytes for H2 Fuel Cells
A Comprehensive Study of Mil-88a as a Key Component of Hybrid Polymer Electrolytes for H2 Fuel Cells Open
View article: Corrigendum to “High-capacity Li4Ti5O12-C thick ceramic electrodes manufactured by powder injection moulding” [J. Eur. Ceram. Soc. 44 (2024) 978–985]
Corrigendum to “High-capacity Li4Ti5O12-C thick ceramic electrodes manufactured by powder injection moulding” [J. Eur. Ceram. Soc. 44 (2024) 978–985] Open
View article: High-capacity Li4Ti5O12-C thick ceramic electrodes manufactured by powder injection moulding
High-capacity Li4Ti5O12-C thick ceramic electrodes manufactured by powder injection moulding Open
Lithium-ion batteries are the most efficient electrochemical energy storage devices. However, there is still room for improvement in terms of safety and energy density, presently limited by conventional tape-casting electrode processing. I…
View article: All-solid-state sodium-ion batteries operating at room temperature based on NASICON-type NaTi2(PO4)3 cathode and ceramic NASICON solid electrolyte: A complete in situ synchrotron X-ray study
All-solid-state sodium-ion batteries operating at room temperature based on NASICON-type NaTi2(PO4)3 cathode and ceramic NASICON solid electrolyte: A complete in situ synchrotron X-ray study Open
All-solid-state sodium-ion batteries that work at ambient temperature are a potential approach for large-scale energy storage systems. Nowadays, ceramic solid electrolytes are gaining attention because of their good ionic conductivity and …
View article: CCDC 2161748: Experimental Crystal Structure Determination
CCDC 2161748: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: High Proton Conductivity of a Bismuth Phosphonate Metal–Organic Framework with Unusual Topology
High Proton Conductivity of a Bismuth Phosphonate Metal–Organic Framework with Unusual Topology Open
International audience
View article: High performance NASICON ceramic electrolytes produced by tape-casting and low temperature hot-pressing: Towards sustainable all-solid-state sodium batteries operating at room temperature
High performance NASICON ceramic electrolytes produced by tape-casting and low temperature hot-pressing: Towards sustainable all-solid-state sodium batteries operating at room temperature Open
View article: 3D-printing of easily recyclable all-ceramic thick LiCoO2 electrodes with enhanced areal capacity for Li-ion batteries using a highly filled thermoplastic filament
3D-printing of easily recyclable all-ceramic thick LiCoO2 electrodes with enhanced areal capacity for Li-ion batteries using a highly filled thermoplastic filament Open
In this work, the production of thick ceramic LiCoO2 (LCO) electrodes using a conventional desktop 3D-printing was developed as an alternative to conventional electrode manufacturing for Li-ion batteries. Firstly, the filament f…
View article: Influence of Cation Vacancies on Li Conductivity of La<sub>1/2</sub>Li<sub>1/2–2<i>x</i></sub>Sr<sub><i>x</i></sub>TiO<sub>3</sub> Perovskites (0 < <i>x</i> ≤ 0.25): The Role of Nominal and Effective Vacancies
Influence of Cation Vacancies on Li Conductivity of La<sub>1/2</sub>Li<sub>1/2–2<i>x</i></sub>Sr<sub><i>x</i></sub>TiO<sub>3</sub> Perovskites (0 < <i>x</i> ≤ 0.25): The Role of Nominal and Effective Vacancies Open
The Li1/2-2x Sr x La1/2TiO3 series (0 ≤ x ≤ 0.25) is investigated with X-ray diffraction, nuclear magnetic resonance, and impedance spectroscopy techniques. The substitution …
View article: Proton conducting sulfonated polysulfone and polyphenylsulfone multiblock copolymers with improved performances for fuel cell applications
Proton conducting sulfonated polysulfone and polyphenylsulfone multiblock copolymers with improved performances for fuel cell applications Open
View article: Flexible solvent-free polymer electrolytes for solid-state Na batteries
Flexible solvent-free polymer electrolytes for solid-state Na batteries Open
Post-lithium batteries, based on alkaline and alkaline earth elements, are cheaper technologies with the potential to produce disruptive changes in the transition towards cleaner and sustainable energy sources less dependent on fossil fuel…
View article: Using Metal-Organic Framework HKUST-1 for the Preparation of High-Conductive Hybrid Membranes Based on Multiblock Copolymers for Fuel Cells
Using Metal-Organic Framework HKUST-1 for the Preparation of High-Conductive Hybrid Membranes Based on Multiblock Copolymers for Fuel Cells Open
Novel proton-conducting hybrid membranes consisting of sulfonated multiblock copolymer of polysulfone and polyphenylsulfone (SPES) reinforced with a HKUST-1 metal-organic framework (MOF) (5, 10, and 20 wt. %) were prepared and characterize…
View article: Life Cycle Assessment of Lab-Scale Solid Sodium-Ion Batteries: A Sustainable Alternative to Liquid Lithium-Ion Batteries
Life Cycle Assessment of Lab-Scale Solid Sodium-Ion Batteries: A Sustainable Alternative to Liquid Lithium-Ion Batteries Open
View article: Effect of Relaxations on the Conductivity of La<sub>1/2+1/2<i>x</i></sub>Li<sub>1/2–1/2<i>x</i></sub>Ti<sub>1–<i>x</i></sub>Al<i><sub>x</sub></i>O<sub>3</sub> Fast Ion Conductors
Effect of Relaxations on the Conductivity of La<sub>1/2+1/2<i>x</i></sub>Li<sub>1/2–1/2<i>x</i></sub>Ti<sub>1–<i>x</i></sub>Al<i><sub>x</sub></i>O<sub>3</sub> Fast Ion Conductors Open
Perovskite-type solid-state electrolytes, Li3x La2/3-x TiO3 (LLTO), are considered among the most promising candidates for the development of all-solid-state batteries based on lithium metal. …
View article: Layer Shape LiFePO<sub>4</sub> Obtained by Powder Extrusion Molding as Solid Boosters for Ferro/Ferricyanide Catholyte in Semisolid Redox Flow Battery: Effect of Porosity and Shape
Layer Shape LiFePO<sub>4</sub> Obtained by Powder Extrusion Molding as Solid Boosters for Ferro/Ferricyanide Catholyte in Semisolid Redox Flow Battery: Effect of Porosity and Shape Open
Powder extrusion molding is proposed to fabricate ceramic LiFePO 4 layers (0.5–1.0 mm thickness) as solid booster for ferricyanide electrolyte in semisolid redox flow battery. In some extruded layers, the binder is partially decomposed, wh…
View article: High Performance Nasicon Ceramic Electrolytes Produced by Tape-Casting and Hot-Pressing: Towards Sustainable All-Solid-State Sodium Batteries Operating at Room Temperature
High Performance Nasicon Ceramic Electrolytes Produced by Tape-Casting and Hot-Pressing: Towards Sustainable All-Solid-State Sodium Batteries Operating at Room Temperature Open
View article: 3d-Printing of Easily Recyclable All-Ceramic Thick Licoo2 Electrodes with Enhanced Areal Capacity for Li-Ion Batteries Using a Highly Filled Thermoplastic Filament
3d-Printing of Easily Recyclable All-Ceramic Thick Licoo2 Electrodes with Enhanced Areal Capacity for Li-Ion Batteries Using a Highly Filled Thermoplastic Filament Open