Explanipedia

[11C]Fentanyl: radiosynthesis and preclinical pet imaging for its pharmacokinetics Open

Woochan Kim, Aaron K. Wozniak, Nathaniel J. Burkard, Michael L. Freaney, Ailen Costamagna-Soto , et al. · 2025

Investigation of [11C]carfentanil for mu opioid receptor quantification in the rat brain Open

Andrew Kelleher, Torben D. Pearson, J Tyler Ramsey, Wenjing Zhao, Kelly A. O’Conor , et al. · 2024

Cobalt–Magnesium and Cobalt–Calcium Heterotrimetallic Dinitrogen Complexes Open

Jocelyn Polanco, Theresa Knoell, Abolghasem Bakhoda · 2024

We report the use of alkaline earth metals magnesium and calcium for the reduction of the cobalt(II) complex [ i Pr2NN]Co(μ-Cl)2Li(thf)2 [ i Pr2NN = 2,4-bis(2,6-diisopropylphenylimido)pentyl] that resulted in heterotrimetallic dinitrogen c…

CCDC 2306677: Experimental Crystal Structure Determination Open

Abolghasem Bakhoda · 2024

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …

Synthesis and crystal structure of [1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene](isocyanato-κN)gold(I) Open

Abolghasem Bakhoda · 2024

The title complex, [Au(NCO)(C 27 H 36 N 2 )], was synthesized by ligand metathesis from [1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]gold(I) chloride and sodium cyanate in anhydrous tetrahydrofuran and crystallized from toluene at 233…

Alkaline earth metal-assisted dinitrogen activation at nickel Open

Theresa Knoell, Jocelyn Polanco, Samantha N. MacMillan, Jeffery A. Bertke, Cina Foroutan‐Nejad , et al. · 2024

Rare examples of trinuclear [Ni–N 2 –M–N 2 –Ni] core (M = Ca, Mg) with linear bridged dinitrogen ligands are reported in this work.

Additive-Free Copper-Catalyzed Benzylic C(sp3)–H Carbamation: Simple Preparation of Primary Benzylic Amines Open

Abolghasem Bakhoda, William L. Schmidt · 2023

A simple and practical method for the synthesis of primary alkylamines by direct functionalization of hydrocarbons is described. The N-Boc-protected alkylamines are readily prepared from tert-butyl (trimethylsilyl)carbamate and N-fluoroben…

Naloxone’s dose-dependent displacement of [11C]carfentanil and duration of receptor occupancy in the rat brain Open

Yeona Kang, Kelly A. O’Conor, Andrew Kelleher, J Tyler Ramsey, Abolghasem Bakhoda , et al. · 2022

CCDC 2035780: Experimental Crystal Structure Determination Open

Isuri U. Jayasooriya, Abolghasem Bakhoda, Rachel Palmer, Kristi Ng, Nour L. Khachemoune , et al. · 2021

Discovery of Highly Potent Adenosine A1 Receptor Agonists: Targeting Positron Emission Tomography Probes Open

Min Guo, Abolghasem Bakhoda, Zhan‐Guo Gao, Joseph M. Ramsey, Yang Li , et al. · 2021

Adenosine receptor (AR) radiotracers for positron emission tomography (PET) have provided knowledge on the in vivo biodistribution of ARs in the central nervous system (CNS), which is of therapeutic interest for various neuropsychia…

Copper(II) Ketimides in sp3 C-H Amination Open

Isuri U. Jayasooriya, Abolghasem Bakhoda, Rachel Palmer, Kristi Ng, Nour L. Khachemoune , et al. · 2021

Commercialy available benzphenone imine (HN=CPh₂) reacts with b-diketiminato copper(II) tert-butoxide complexes [Cu^II]-O^tBu to form isolable copper(II) ketimides [Cu^II]-N=CPh_2<…

Copper(II) Ketimides in sp3 C-H Amination Open

Isuri U. Jayasooriya, Abolghasem Bakhoda, Rachel Palmer, Kristi Ng, Nour L. Khachemoune , et al. · 2021

Commercialy available benzphenone imine (HN=CPh 2 ) reacts with b-diketiminato copper(II) tert -butoxide complexes [Cu II ]-O t Bu to form isolable copper(II) ketimides [Cu II ]-N=CPh 2 . Structural characterization of the three coordinate…

Copper( ii ) ketimides in sp 3 C–H amination Open

Isuri U. Jayasooriya, Abolghasem Bakhoda, Rachel Palmer, Kristi Ng, Nour L. Khachemoune , et al. · 2021

Commercially available benzophenone imine (HNCPh 2 ) reacts with β-diketiminato copper( ii ) tert -butoxide complexes [Cu II ]–O t Bu to form isolable copper( ii ) ketimides [Cu II ]–NCPh 2 that serve as intermediates in catalytic sp 3 C…

CCDC 1945529: Experimental Crystal Structure Determination Open

Valiallah Hosseininasab, Alison C. McQuilken, Abolghasem Bakhoda, Jeffery A. Bertke, Qadir K. Timerghazin , et al. · 2020

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …

CCDC 1945527: Experimental Crystal Structure Determination Open

Valiallah Hosseininasab, Alison C. McQuilken, Abolghasem Bakhoda, Jeffery A. Bertke, Qadir K. Timerghazin , et al. · 2020

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …

CCDC 1945525: Experimental Crystal Structure Determination Open

Valiallah Hosseininasab, Alison C. McQuilken, Abolghasem Bakhoda, Jeffery A. Bertke, Qadir K. Timerghazin , et al. · 2020

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …

CCDC 1945528: Experimental Crystal Structure Determination Open

Valiallah Hosseininasab, Alison C. McQuilken, Abolghasem Bakhoda, Jeffery A. Bertke, Qadir K. Timerghazin , et al. · 2020

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …

CCDC 1938191: Experimental Crystal Structure Determination Open

Abolghasem Bakhoda, Otome E. Okoromoba, Christine Greene, Mahdi Raghibi Boroujeni, Jeffery A. Bertke , et al. · 2020

CCDC 1938190: Experimental Crystal Structure Determination Open

Abolghasem Bakhoda, Otome E. Okoromoba, Christine Greene, Mahdi Raghibi Boroujeni, Jeffery A. Bertke , et al. · 2020

CCDC 1938189: Experimental Crystal Structure Determination Open

Abolghasem Bakhoda, Otome E. Okoromoba, Christine Greene, Mahdi Raghibi Boroujeni, Jeffery A. Bertke , et al. · 2020

Uncovering a copper(II) Alkynyl Complex in C−C Bond Forming Reactions Open

Abolghasem Bakhoda, Otome E. Okoromoba, Christine Greene, Mahdi Raghibi Boroujeni, Jeffery A. Bertke , et al. · 2020

Copper(II) alkynyl species are proposed as key intermediates in numerous Cu−catalysed C−C coupling reactions. Supported by a β−diketiminate ligand, the three coordinate copper(II) alkynyl [Cu II ]−C≡CAr (Ar = 2,6−Cl 2 C 6 H 3 ) forms upon …

Uncovering a copper(II) Alkynyl Complex in C−C Bond Forming Reactions Open

Abolghasem Bakhoda, Otome E. Okoromoba, Christine Greene, Mahdi Raghibi Boroujeni, Jeffery A. Bertke , et al. · 2020

Copper(II) alkynyl species are proposed as key intermediates in numerous Cu−catalysed C−C coupling reactions. Supported by a β−diketiminate ligand, the three coordinate copper(II) alkynyl [Cu^II]−C≡CAr (Ar = 2,6−Cl₂C

CCDC 1861882: Experimental Crystal Structure Determination Open