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View article: Towards the Industrial Implementation of Mn-based Catalyst for the Hydrogenation of Ketones and Carboxylic Esters
Towards the Industrial Implementation of Mn-based Catalyst for the Hydrogenation of Ketones and Carboxylic Esters Open
There is a constant pressure in industry to move away from platinum group metals (PGM) and achieve more environmentally friendly and sustainable production processes in the future. Recently developed Mn-based catalysts offer an interesting…
View article: Nickel-Catalyzed Trifluoromethylselenolation of Aryl and Alkenyl-Triflates: Scope and Mechanism
Nickel-Catalyzed Trifluoromethylselenolation of Aryl and Alkenyl-Triflates: Scope and Mechanism Open
International audience
View article: CCDC 2260118: Experimental Crystal Structure Determination
CCDC 2260118: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: From Academia to the Market – Air-stable Ni(II)/Josiphos Catalysts
From Academia to the Market – Air-stable Ni(II)/Josiphos Catalysts Open
The design, synthesis, commercialization and application of air stable Ni(II)/Josiphos complexes has been realized in a collaboration between Solvias and ICBMS (University Lyon 1). The Ni-complexes are utilized as versatile precatalysts fo…
View article: CuH-Catalyzed Asymmetric Reductive Amidation of α,β-Unsaturated Carboxylic Acids
CuH-Catalyzed Asymmetric Reductive Amidation of α,β-Unsaturated Carboxylic Acids Open
The direct enantioselective copper hydride (CuH)-catalyzed synthesis of β-chiral amides from α,β-unsaturated carboxylic acids and secondary amines under mild reaction conditions is reported. The method utilizes readily accessible carboxyli…
View article: Remote Central‐to‐Axial Chirality Conversion: Direct Atroposelective Ester to Biaryl Transformation
Remote Central‐to‐Axial Chirality Conversion: Direct Atroposelective Ester to Biaryl Transformation Open
A strategy for the remote central‐to‐axial chirality conversion by simultaneous planarization of an encoding and a transient stereocenter is presented. Based on a diastereoselective double addition of a chiral 1,5‐bifunctional organomagnes…
View article: 1,5-bifunctional organomagnesium reagents for the direct transformation of esters into arenes
1,5-bifunctional organomagnesium reagents for the direct transformation of esters into arenes Open
For the sustainable and economical supply of products relevant to our society, the development of new methods based on main group elements is indispensable. Arenes are privileged molecular scaffolds due to their stability, rigidity and the…
View article: Stereoselective arene formation
Stereoselective arene formation Open
The common perception of arenes as flat and symmetric entities is juxtaposed to the counterintuitive circumstance that stereoselective arene formation offers a means to prepare an exceptional range of chiral aromatic structures in isomeric…
View article: CCDC 1820085: Experimental Crystal Structure Determination
CCDC 1820085: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1820084: Experimental Crystal Structure Determination
CCDC 1820084: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1820086: Experimental Crystal Structure Determination
CCDC 1820086: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Catalytic Arene-forming Aldol Condensation: Stereoselective Synthesis of Rotationally Restricted Aromatic Compounds
Catalytic Arene-forming Aldol Condensation: Stereoselective Synthesis of Rotationally Restricted Aromatic Compounds Open
By taking inspiration from the fascinating biosynthetic machinery that creates aromatic polyketides, our group investigates analogous reactions catalyzed by small molecules. We are particularly captivated by the prospects of intramolecular…
View article: Direct Transformation of Esters into Arenes with 1,5‐Bifunctional Organomagnesium Reagents
Direct Transformation of Esters into Arenes with 1,5‐Bifunctional Organomagnesium Reagents Open
A direct transformation of carboxylic acid esters into arenes with 1,5‐bifunctional organomagnesium reagents is described. This efficient and practical method enables the one‐step defunctionalization of various carboxylic acid esters to pr…