Alessio Nicolini
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View article: CCDC 2443817: Experimental Crystal Structure Determination
CCDC 2443817: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2443816: Experimental Crystal Structure Determination
CCDC 2443816: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2443818: Experimental Crystal Structure Determination
CCDC 2443818: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Oxovanadium(IV) Thiocarboxylate Paddlewheels Containing Ancillary Group 10 Metals: A Comparative Study on Pd and Pt Derivatives
Oxovanadium(IV) Thiocarboxylate Paddlewheels Containing Ancillary Group 10 Metals: A Comparative Study on Pd and Pt Derivatives Open
Vanadyl-containing paddlewheel structures have recently joined the pool of molecular spin systems showing respectable coherence times (Tm). We extended the investigation of [PtVO(SOCR)4] (R = Me, Ph) by synthesizing the corresponding Pd de…
View article: Metal Hydroxide Organic Frameworks (MHOFs) for Oxygen Evolution by Intercalation of Dicarboxylate Linkers Into β‐Ni(OH)<sub>2</sub>: Impact of Host Crystallinity
Metal Hydroxide Organic Frameworks (MHOFs) for Oxygen Evolution by Intercalation of Dicarboxylate Linkers Into β‐Ni(OH)<sub>2</sub>: Impact of Host Crystallinity Open
Ni and Ni/Fe metal hydroxide organic frameworks (MHOFs) based on aromatic dicarboxylates are attracting great interest as emerging noble metal‐free catalysts for the oxygen evolution reaction (OER), during H 2 production by water splitting…
View article: Conclusive Insight into the Coordination Complexes of a Flexible Bis(β‐diketonato) Ligand and Their Phase‐Dependent Structure: A Multi‐Technique Approach
Conclusive Insight into the Coordination Complexes of a Flexible Bis(β‐diketonato) Ligand and Their Phase‐Dependent Structure: A Multi‐Technique Approach Open
Multichelating ligands with nuclear spin‐free donor atoms are of particular interest for creating stable electronic spin qubits based on paramagnetic transition metal ions. We recently focused on the coordinating ability of the bis(β‐diket…
View article: Water-Assisted Electrosynthesis of a Lithium–Aluminum Intermetallic from a Lithium Chloride-Ionic Liquid Melt
Water-Assisted Electrosynthesis of a Lithium–Aluminum Intermetallic from a Lithium Chloride-Ionic Liquid Melt Open
Although water is considered detrimental for Li-ion battery technology, a 1% w/w amount of water in a melt of LiCl in ionic liquid 1-butyl-3-methylimidazolium chloride promotes the reduction of lithium into a LiAl intermetallic along with …
View article: Dual Structure of a Vanadyl-Based Molecular Qubit Containing a Bis(β-diketonato) Ligand
Dual Structure of a Vanadyl-Based Molecular Qubit Containing a Bis(β-diketonato) Ligand Open
We report [VO(bdhb)] (1') as a new electronic qubit containing an oxovanadium(IV) ion (S = 1/2) embraced by a single bis(β-diketonato) ligand [H2bdhb = 1,3-bis(3,5-dioxo-1-hexyl)benzene]. 1H-DOSY and EPR experiments in organic solution con…
View article: Quantum spin coherence and electron spin distribution channels in vanadyl-containing lantern complexes. Open dataset
Quantum spin coherence and electron spin distribution channels in vanadyl-containing lantern complexes. Open dataset Open
Data supporting the original figures 3 and 4 of the related publication
View article: Quantum spin coherence and electron spin distribution channels in vanadyl-containing lantern complexes. Open dataset
Quantum spin coherence and electron spin distribution channels in vanadyl-containing lantern complexes. Open dataset Open
Data supporting the original figures 3 and 4 of the related publication
View article: Guest selectivity of [Ni<sub>2</sub>] supramolecular helicates
Guest selectivity of [Ni<sub>2</sub>] supramolecular helicates Open
A triple stranded [Ni( ii ) 2 ] coordination helicate acts as the host of a Cl − or a Br − ion in the solid state and in solution, with a selective preference for the former, as shown by paramagnetic 1 H NMR, mass spectrometry and DFT calc…
View article: Phase-dependent polymerization isomerism in the coordination complexes of a flexible bis(β-diketonato) ligand
Phase-dependent polymerization isomerism in the coordination complexes of a flexible bis(β-diketonato) ligand Open
A conformationally flexible bis(β-diketonato) ligand yields complexes with a phase-dependent structure. Its 1 : 1 Co 2+ adduct, assembled using ancillary pyridine ligands, is dimeric in the crystalline state but monomeric in organic soluti…
View article: Quantum spin coherence and electron spin distribution channels in vanadyl-containing lantern complexes
Quantum spin coherence and electron spin distribution channels in vanadyl-containing lantern complexes Open
Lantern complexes containing VO 2+ and Pt 2+ ions show electron spin coherence with phase memory times above 10 μs at 10 K. EPR spectra prove the delocalization of the unpaired spin density to the heavy metal ion through both π and δ coupl…
View article: Quantum Spin Coherence and Electron Spin Distribution Channels in Vanadyl-containing Lantern Complexes
Quantum Spin Coherence and Electron Spin Distribution Channels in Vanadyl-containing Lantern Complexes Open
We herein investigate the heterobimetallic lantern complexes [PtVO(SOCR)4] as electrically neutral electronic qubits based on vanadyl complexes (S = 1/2) with nuclear spin-free donor atoms. The derivatives with R = Me (1) and Ph (2) give h…
View article: CCDC 2246172: Experimental Crystal Structure Determination
CCDC 2246172: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: A Remarkably Unsymmetric Hexairon Core Embraced by Two High-Symmetry Tripodal Oligo-α-pyridylamido Ligands
A Remarkably Unsymmetric Hexairon Core Embraced by Two High-Symmetry Tripodal Oligo-α-pyridylamido Ligands Open
Oligo-α-pyridylamides offer an appealing route to polyiron complexes with short Fe-Fe separations and large room-temperature magnetic moments. A derivative of tris(2-aminoethyl)amine (H6tren) containing three oligo-α-pyridylamine branches …
View article: An efficient transition-metal-free route to oligo- <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mi>α</mml:mi> </mml:math> -pyridylamines via fluoroarenes
An efficient transition-metal-free route to oligo- -pyridylamines via fluoroarenes Open
The new polynucleating tripodal proligand , containing thirteen nitrogen donors of four different types, was designed, synthesized, and isolated in good yield ( 60%) via a transition-metal-free triple N-arylation of tren with…
View article: CCDC 2208667: Experimental Crystal Structure Determination
CCDC 2208667: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2208666: Experimental Crystal Structure Determination
CCDC 2208666: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2208665: Experimental Crystal Structure Determination
CCDC 2208665: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2208669: Experimental Crystal Structure Determination
CCDC 2208669: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2208668: Experimental Crystal Structure Determination
CCDC 2208668: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: The structure of a pentachromium(II) extended metal atom chain at 3 K: Cotton’s conjecture proven
The structure of a pentachromium(II) extended metal atom chain at 3 K: Cotton’s conjecture proven Open
We provide definitive experimental proof that prototypical string-like compound [Cr5(tpda)4(NCS)2] has alternating long and short Cr-Cr separations in the solid state, as conjectured by F. A. Cotton, rather than essentially equally spaced …
View article: CCDC 2165612: Experimental Crystal Structure Determination
CCDC 2165612: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2165614: Experimental Crystal Structure Determination
CCDC 2165614: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2165613: Experimental Crystal Structure Determination
CCDC 2165613: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Structural Diversity of Lithium Oligo-α-Pyridylamides
Structural Diversity of Lithium Oligo-α-Pyridylamides Open
Lithium oligo-α-pyridylamides are useful intermediates in coordination chemistry. Upon trans-metalation they have afforded a variety of extended metal atom chains (EMACs), which are currently investigated as molecular wires and single-mole…
View article: The structure of a pentachromium( <scp>ii</scp> ) extended metal atom chain at 3 K: Cotton's conjecture proven
The structure of a pentachromium( <span>ii</span> ) extended metal atom chain at 3 K: Cotton's conjecture proven Open
Cryocrystallography down to 3 K and twin refinement disclose the actual solid-state symmetry of [Cr 5 (C 15 H 11 N 5 ) 4 (NCS) 2 ], an archetypal EMAC. As conjectured by F. A. Cotton, the molecule is unsymmetric, with alternating long/shor…
View article: CCDC 2114257: Experimental Crystal Structure Determination
CCDC 2114257: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Stereoisomerism in Tetrametallic Propeller‐Like Complexes: A Solid‐State and Solution NMR Study on a Tetragallium(III) Derivative
Stereoisomerism in Tetrametallic Propeller‐Like Complexes: A Solid‐State and Solution NMR Study on a Tetragallium(III) Derivative Open
Tetragallium(III) complex in [Ga 4 (L 4‐Py ) 2 (dpm) 6 ] ⋅ EtOH, with H 3 L 4‐Py =2‐(hydroxymethyl)‐2‐(pyridin‐4‐yl)propane‐1,3‐diol and Hdpm=dipivaloylmethane, was investigated as a diamagnetic analogue of tetrametallic, propeller‐like si…