Alex M. Confer
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View article: CCDC 2154287: Experimental Crystal Structure Determination
CCDC 2154287: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2154288: Experimental Crystal Structure Determination
CCDC 2154288: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2154284: Experimental Crystal Structure Determination
CCDC 2154284: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Investigating Metal–Metal Bond Polarization in a Heteroleptic Tris-Ylide Diiron System
Investigating Metal–Metal Bond Polarization in a Heteroleptic Tris-Ylide Diiron System Open
This article describes the synthesis, characterization, and S-atom transfer reactivity of a series of C3v-symmetric diiron complexes. The iron centers in each complex are coordinated in distinct ligand environments…
View article: CCDC 2154290: Experimental Crystal Structure Determination
CCDC 2154290: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2154289: Experimental Crystal Structure Determination
CCDC 2154289: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2154285: Experimental Crystal Structure Determination
CCDC 2154285: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2154286: Experimental Crystal Structure Determination
CCDC 2154286: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Evaluation of the Physicochemical Properties of the Iron Nanoparticle Drug Products: Brand and Generic Sodium Ferric Gluconate
Evaluation of the Physicochemical Properties of the Iron Nanoparticle Drug Products: Brand and Generic Sodium Ferric Gluconate Open
Complex iron nanoparticle-based drugs are one of the oldest and most frequently administered classes of nanomedicines. In the US, there are seven FDA-approved iron nanoparticle reference drug products, of which one also has an approved gen…
View article: Mononuclear, Nonheme, High-Spin {FeNO}<sup>7/8</sup> Complexes Supported by a Sterically Encumbered N<sub>4</sub>S-Thioether Ligand
Mononuclear, Nonheme, High-Spin {FeNO}<sup>7/8</sup> Complexes Supported by a Sterically Encumbered N<sub>4</sub>S-Thioether Ligand Open
The synthesis of a new nonheme iron NO binding complex, [FeII(CH3CN)(N3Py2PhSEtCN)](BF4)2 (1), is reported. Complex 1, which contains two sterically encumbering phenyl su…
View article: CCDC 1916943: Experimental Crystal Structure Determination
CCDC 1916943: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: A Mononuclear, Nonheme Fe<sup>II</sup>–Piloty’s Acid (PhSO<sub>2</sub>NHOH) Adduct: An Intermediate in the Production of {FeNO}<sup>7/8</sup> Complexes from Piloty’s Acid
A Mononuclear, Nonheme Fe<sup>II</sup>–Piloty’s Acid (PhSO<sub>2</sub>NHOH) Adduct: An Intermediate in the Production of {FeNO}<sup>7/8</sup> Complexes from Piloty’s Acid Open
Reaction of the mononuclear nonheme complex [FeII(CH3CN)(N3PyS)]BF4 (1) with an HNO donor, Piloty's acid (PhSO2NHOH, P.A.), at low temperature affords a high-spin ( S = 2) FeII-P.A. in…
View article: Comparative Physicochemical Characterization between Brand and Generic Intravenous Sodium Ferric Gluconate Complex in Sucrose Injection
Comparative Physicochemical Characterization between Brand and Generic Intravenous Sodium Ferric Gluconate Complex in Sucrose Injection Open
View article: A Nonheme Sulfur‐Ligated {FeNO}<sup>6</sup> Complex and Comparison with Redox‐Interconvertible {FeNO}<sup>7</sup> and {FeNO}<sup>8</sup> Analogues
A Nonheme Sulfur‐Ligated {FeNO}<sup>6</sup> Complex and Comparison with Redox‐Interconvertible {FeNO}<sup>7</sup> and {FeNO}<sup>8</sup> Analogues Open
A nonheme {FeNO} 6 complex, [Fe(NO)(N3PyS)] 2+ , was synthesized by reversible, one‐electron oxidation of an {FeNO} 7 analogue. This complex completes the first known series of sulfur‐ligated {FeNO} 6–8 complexes. All three {FeNO} 6–8 comp…
View article: A Nonheme, High-Spin {FeNO}<sup>8</sup> Complex that Spontaneously Generates N<sub>2</sub>O
A Nonheme, High-Spin {FeNO}<sup>8</sup> Complex that Spontaneously Generates N<sub>2</sub>O Open
One-electron reduction of [Fe(NO)-(N3PyS)]BF4 (1) leads to the production of the metastable nonheme {FeNO}8 complex, [Fe(NO)(N3PyS)] (3). Complex 3 is a rare example of a high-spin (S = 1) {FeNO}8 and is th…
View article: Aromatic C–F Hydroxylation by Nonheme Iron(IV)–Oxo Complexes: Structural, Spectroscopic, and Mechanistic Investigations
Aromatic C–F Hydroxylation by Nonheme Iron(IV)–Oxo Complexes: Structural, Spectroscopic, and Mechanistic Investigations Open
The synthesis and reactivity of a series of mononuclear nonheme iron complexes that carry out intramolecular aromatic C-F hydroxylation reactions is reported. The key intermediate prior to C-F hydroxylation, [FeIV(O)(N4Py2A…
View article: Photoinitiated Reactivity of a Thiolate-Ligated, Spin-Crossover Nonheme {FeNO}<sup>7</sup>Complex with Dioxygen
Photoinitiated Reactivity of a Thiolate-Ligated, Spin-Crossover Nonheme {FeNO}<sup>7</sup>Complex with Dioxygen Open
The nonheme iron complex, [Fe(NO)(N3PyS)]BF4, is a rare example of an {FeNO}(7) species that exhibits spin-crossover behavior. The comparison of X-ray crystallographic studies at low and high temperatures and variable-temperature magnetic …
View article: CCDC 1509559: Experimental Crystal Structure Determination
CCDC 1509559: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1422250: Experimental Crystal Structure Determination
CCDC 1422250: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1007935: Experimental Crystal Structure Determination
CCDC 1007935: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1509558: Experimental Crystal Structure Determination
CCDC 1509558: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1509560: Experimental Crystal Structure Determination
CCDC 1509560: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …