Alexander O. Terent’ev
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View article: Boronosteroids as potential antitumor drugs: A review
Boronosteroids as potential antitumor drugs: A review Open
Boron’s unique chemical properties have long fascinated scientists, particularly its ability to form stable five- or six-membered spiroborate compounds. Among these, tetracoordinate compounds, where boron is bonded to four oxygen ato…
View article: 1,2-Diol Xanthophylls and Their Boron Complexes
1,2-Diol Xanthophylls and Their Boron Complexes Open
This concise review delves into an intriguing subject—a unique class of natural pigments known as xanthophylls. These carotenoids feature a 1,2-diol functional group within their molecular structure, which allows them to engage with boric …
View article: Synthesis of β-ketophosphonates through aerobic copper(II)-mediated phosphorylation of enol acetates
Synthesis of β-ketophosphonates through aerobic copper(II)-mediated phosphorylation of enol acetates Open
Aerobic copper(II)-mediated phosphorylation of enol acetates with H-phosphonates leading to the formation of β-ketophosphonates was discovered. The proposed method is applicable to a wide range of H-phosphonates or phosphine oxides as PH-r…
View article: Azo Dyes and the Microbial World: Synthesis, Breakdown, and Bioactivity
Azo Dyes and the Microbial World: Synthesis, Breakdown, and Bioactivity Open
This review discusses natural and synthetic azo compounds found in bacteria, fungal endophytes, fungi, plants, and invertebrates. More than 100 of these compounds have demonstrated significant pharmacological activity, including antitumor,…
View article: Photocatalytic Germylation via Direct Hydrogen Atom Transfer
Photocatalytic Germylation via Direct Hydrogen Atom Transfer Open
Comprehensive Summary An innovative visible‐light‐driven direct hydrogen atom transfer ( d ‐HAT) of Ge–H bond has been developed, wherein the photoexcited 9,10‐phenanthraquinone ( PC HAT 9 ) serves as an efficient photocatalyst for the gen…
View article: <i>N</i>‐Substituted Bridged Azaozonides as Promising Antimalarial Agents
<i>N</i>‐Substituted Bridged Azaozonides as Promising Antimalarial Agents Open
Forty‐five aminoperoxides belonging to bridged azaozonides, bridged N ‐substituted azaozonides, and tricyclic aminoperoxides were evaluated for in vitro antimalarial activity against Plasmodium falciparum (3D7) and for cytotoxicity against…
View article: Mediterranean Blue Flowers with a Scent of Cannabis
Mediterranean Blue Flowers with a Scent of Cannabis Open
The aromatic herb Plectranthus neochilus with a cannabis smell, widely used in folk medicine, has become the subject of a study of its essential oils of flowers and leaves. GC-MS analysis revealed a unique composition, the oils of flowers,…
View article: “Trading” a CC moiety for four C–O bonds and a peroxide: combining ozone and <i>O</i> -nucleophiles for peroxidative ring expansion of cycloalkenes into medium-sized 1,2-dioxacycloalkanes
“Trading” a CC moiety for four C–O bonds and a peroxide: combining ozone and <i>O</i> -nucleophiles for peroxidative ring expansion of cycloalkenes into medium-sized 1,2-dioxacycloalkanes Open
Synergistic action of ozone and O -nucleophiles induces unexpected ring expansion of cycloalkenes into medium-sized peroxycycles.
View article: Human Health, Environmental Comfort and Well-Being. Part 1. Engineering and Design Resources of the Bioindustry on the Way to Safe Competition with the Resources of Natural Biocenoses and Health-Saving Systems
Human Health, Environmental Comfort and Well-Being. Part 1. Engineering and Design Resources of the Bioindustry on the Way to Safe Competition with the Resources of Natural Biocenoses and Health-Saving Systems Open
Everyone has the right to the highest attainable standard of health, and modern preventive, preventive and rehabilitative manipulations promote health and well-being. Thanks to a number of fundamental projects on the study of human health …
View article: Human Health, Environmental Comfort and Well-Being. Part 2. Ecological Comfort as a New and Strategic Factor in the Protection of Modern Human Health
Human Health, Environmental Comfort and Well-Being. Part 2. Ecological Comfort as a New and Strategic Factor in the Protection of Modern Human Health Open
Since the dawn of humanity, human beings have inherently sought a state of security, trying to make their existence as comfortable as possible. Accordingly, among the many factors affecting human health, comfort and well-being, the quality…
View article: Electrochemically Induced Synthesis of <i>N</i>-Allyloxyphthalimides via Cross-Dehydrogenative C–O Coupling of <i>N</i>-Hydroxyphthalimide with Alkenes Bearing the Allylic Hydrogen Atom
Electrochemically Induced Synthesis of <i>N</i>-Allyloxyphthalimides via Cross-Dehydrogenative C–O Coupling of <i>N</i>-Hydroxyphthalimide with Alkenes Bearing the Allylic Hydrogen Atom Open
The electrochemically induced reaction between alkenes, bearing an allylic hydrogen atom, and N-hydroxyphthalimide was investigated. Cross-dehydrogenative C-O coupling with phthalimide-N-oxyl radical, derived from N-hy…
View article: Ammonium Dinitramide as a Prospective N–NO2 Synthon: Electrochemical Synthesis of Nitro-NNO-Azoxy Compounds from Nitrosoarenes
Ammonium Dinitramide as a Prospective N–NO2 Synthon: Electrochemical Synthesis of Nitro-NNO-Azoxy Compounds from Nitrosoarenes Open
In this study, the electrochemical coupling of nitrosoarenes with ammonium dinitramide is discovered, leading to the facile construction of the nitro-NNO-azoxy group, which represents an important motif in the design of energetic materials…
View article: Advances in radical peroxidation with hydroperoxides
Advances in radical peroxidation with hydroperoxides Open
Organic peroxides have become sought-after functionalities, particularly following the multi-tone consumption in polymer production and success in medicinal chemistry. The selective introduction of a peroxide fragment at different position…
View article: Macrocyclic Organic Peroxides: Constructing Medium and Large Cycles with O-O Bonds
Macrocyclic Organic Peroxides: Constructing Medium and Large Cycles with O-O Bonds Open
Macrocycles bridge the gap between conventional small molecules and polymers. Drawing inspiration from successful carbon heteroatom-containing macrocycles, peroxide-containing macrocycles are gaining attention for enhanced bioactivity, pot…
View article: CO2 capture and in-situ conversion to organic molecules
CO2 capture and in-situ conversion to organic molecules Open
To address the CO2 accumulation in atmosphere, various initiatives have been proposed, among which CO2 capture and utilization (CCU) is regarded as an appealing strategy to reconcile carbon emission and resource utilization. Especially, in…
View article: Contents list
Contents list Open
View article: Peroxide derivatives as SARS-CoV-2 entry inhibitors
Peroxide derivatives as SARS-CoV-2 entry inhibitors Open
View article: C–O Coupling of Hydrazones with Diacetyliminoxyl Radical Leading to Azo Oxime Ethers—Novel Antifungal Agents
C–O Coupling of Hydrazones with Diacetyliminoxyl Radical Leading to Azo Oxime Ethers—Novel Antifungal Agents Open
Selective oxidative C–O coupling of hydrazones with diacetyliminoxyl is demonstrated, in which diacetyliminoxyl plays a dual role. It is an oxidant (hydrogen atom acceptor) and an O-partner for the oxidative coupling. The reaction is compl…
View article: CCDC 2290138: Experimental Crystal Structure Determination
CCDC 2290138: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: A New Catalytic Method for the Synthesis of Cyclic Azaperoxides with High Cytotoxic Activity
A New Catalytic Method for the Synthesis of Cyclic Azaperoxides with High Cytotoxic Activity Open
An efficient method has been developed for the synthesis of N‐aryl‐1,2,4‐dioxazolidines, N‐aryl‐tetraoxaspiroalkanes, and N‐aryl‐hexaoxadispiroalkanes by cycloaminomethylation of OH acids (hydrogen peroxide, gem‐bis‐hydroperoxides, and 1,1…
View article: CCDC 2214526: Experimental Crystal Structure Determination
CCDC 2214526: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: t-BuOOH/TiO2 Photocatalytic System as a Convenient Peroxyl Radical Source at Room Temperature under Visible Light and Its Application for the CH-Peroxidation of Barbituric Acids
t-BuOOH/TiO2 Photocatalytic System as a Convenient Peroxyl Radical Source at Room Temperature under Visible Light and Its Application for the CH-Peroxidation of Barbituric Acids Open
TiO2 is one of the most promising heterogeneous photoredox catalysts employed in oxidative pollutant destruction, CO2 reduction, water splitting, disinfection, solar cell design and organic synthesis. Due to the wide bandgap of TiO2, visib…
View article: CCDC 2253860: Experimental Crystal Structure Determination
CCDC 2253860: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2253892: Experimental Crystal Structure Determination
CCDC 2253892: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2253861: Experimental Crystal Structure Determination
CCDC 2253861: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Insights into the Reactivity of Gd2−xSrxFe2O7 (x = 0 ÷ 0.4) in CO Radical Hydrogenation
Insights into the Reactivity of Gd2−xSrxFe2O7 (x = 0 ÷ 0.4) in CO Radical Hydrogenation Open
The effect of strontium substitution in the structure of the complex oxide Gd2SrFe2O7 on the production of light olefins by CO hydrogenation was investigated. Perovskite-type oxides Gd2−xSr1+xFe2O7 (x = 0; 0.1; 0.2; 0.3; 0.4) were synthesi…
View article: CCDC 2260228: Experimental Crystal Structure Determination
CCDC 2260228: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2260239: Experimental Crystal Structure Determination
CCDC 2260239: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2159166: Experimental Crystal Structure Determination
CCDC 2159166: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2159146: Experimental Crystal Structure Determination
CCDC 2159146: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …