Amber D. Blair
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View article: Kinetics teach that electronic coupling lowers the free-energy change that accompanies electron transfer
Kinetics teach that electronic coupling lowers the free-energy change that accompanies electron transfer Open
Significance Nature’s use of electronic coupling (H DA ) and free-energy (ΔG o ) gradients to vectorially control electron transport provides inspiration for artificial photosynthesis. Theoretical predictions indicate that H DA and ΔG o ar…
View article: Crystal structure of 2-azido-1,3-bis(2,6-diisopropylphenyl)-1,3,2-diazaphospholidine
Crystal structure of 2-azido-1,3-bis(2,6-diisopropylphenyl)-1,3,2-diazaphospholidine Open
The title compound, C 26 H 38 N 5 P, was synthesized by reacting 2-chloro-1,3-bis(2,6-diisopropylphenyl)-1,3,2-diazaphospholidine with sodium azide and a catalytic amount of lithium chloride in tetrahydrofuran. The title compound is the fi…
View article: CCDC 1551849: Experimental Crystal Structure Determination
CCDC 1551849: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Controlling electron transfer at sensitized TiO₂ surfaces
Controlling electron transfer at sensitized TiO₂ surfaces Open
A series of three bis-tridentate ruthenium(II) complexes containing one cyclometalating ligand with terminal triphenylamine (TPA) substituents have been synthesized and characterized for insight into electron transfer reactions at TiO₂ sur…