Andrea Zitolo
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View article: Effect of Tin Precursor Ligand in SnFe–N–C Single‐Site Catalysts for Oxygen Reduction Reaction
Effect of Tin Precursor Ligand in SnFe–N–C Single‐Site Catalysts for Oxygen Reduction Reaction Open
Iron–nitrogen–carbon materials are still the most promising alternative to platinum group materials for the electrochemical reduction of O 2 . Doping with a secondary metal center is a possible way to further enhance the activity, and Sn s…
View article: (<i>Invited</i>) Stabilization of Fe-N<sub>4</sub> Sites by Platinum During Oxygen Reduction in Acid Medium
(<i>Invited</i>) Stabilization of Fe-N<sub>4</sub> Sites by Platinum During Oxygen Reduction in Acid Medium Open
The deployment of proton-exchange-membrane fuel cells is hindered by the large amount of Pt required for anode and cathode electrocatalysis. While Fe–N–C materials have shown promising initial oxygen reduction reaction (ORR) activity, they…
View article: Platinum nanoparticle stability promotion in PEMFC via metal oxide addition: A comparative study between GDE and MEA
Platinum nanoparticle stability promotion in PEMFC via metal oxide addition: A comparative study between GDE and MEA Open
View article: Incorporation of isolated Ag atoms and Au nanoparticles in copper nitride for selective CO electroreduction to multicarbon alcohols
Incorporation of isolated Ag atoms and Au nanoparticles in copper nitride for selective CO electroreduction to multicarbon alcohols Open
View article: Corrigendum to “Unraveling oxygen vacancy formation, dynamics and site distribution in MoO3-x thin films” Mater. Chem. Phys. 333 (2025) 130317
Corrigendum to “Unraveling oxygen vacancy formation, dynamics and site distribution in MoO3-x thin films” Mater. Chem. Phys. 333 (2025) 130317 Open
View article: Unraveling oxygen vacancy formation, dynamics and site distribution in MoO<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" altimg="si440.svg" display="inline" id="d1e3035"><mml:msub><mml:mrow/><mml:mrow><mml:mtext>3-x</mml:mtext></mml:mrow></mml:msub></mml:math> thin films
Unraveling oxygen vacancy formation, dynamics and site distribution in MoO thin films Open
View article: Rearranging spin electrons by axial-ligand-induced hybridization state transition to boost the activity of nickel single-atom-catalysts for electrochemical CO <sub>2</sub> reduction
Rearranging spin electrons by axial-ligand-induced hybridization state transition to boost the activity of nickel single-atom-catalysts for electrochemical CO <sub>2</sub> reduction Open
A Cl axial ligand breaks the D 4h symmetry of Ni–N 4 , inducing Ni orbital hybridization and spin rearrangement. The Ni magnetic moment and d-band center spin difference are universal descriptors for the eCO 2 RR to CO on Ni–N 4 with vario…
View article: Platinum Nanoparticle Stability Promotion in Pemfc Via Metal Oxide Addition: A Comparative Study between Gde and Full Cell Testing
Platinum Nanoparticle Stability Promotion in Pemfc Via Metal Oxide Addition: A Comparative Study between Gde and Full Cell Testing Open
View article: <i>In situ</i> investigation of 1T′/1H phase transition in colloidal WS <sub>2</sub> monolayers
<i>In situ</i> investigation of 1T′/1H phase transition in colloidal WS <sub>2</sub> monolayers Open
In situ study of colloidal WS 2 monolayers shows reducing-ligand stabilization of 1T′ up to 300 °C. At higher temperature, transition to 1H occurs with kinetics controlled by nanosheet size and surface chemistry.
View article: Short‐range order and topology of Te‐rich amorphous Ge–Sb–Te alloys
Short‐range order and topology of Te‐rich amorphous Ge–Sb–Te alloys Open
The structure of evaporated amorphous Ge x Sb x Te 100−2 x ( x = 6, 9, 13) alloys was investigated by neutron diffraction, X‐ray diffraction, and extended X‐ray absorption spectroscopy at the Ge, Sb, and Te K‐edges. Large‐scale structural …
View article: Boosting the O<sub>2</sub>‐to‐H<sub>2</sub>O<sub>2</sub> Selectivity Using Sn‐Doped Carbon Electrocatalysts: Towards Highly Efficient Cathodes for Actual Water Decontamination
Boosting the O<sub>2</sub>‐to‐H<sub>2</sub>O<sub>2</sub> Selectivity Using Sn‐Doped Carbon Electrocatalysts: Towards Highly Efficient Cathodes for Actual Water Decontamination Open
The high cost and often complex synthesis procedure of new highly selective electrocatalysts (particularly those based on noble metals) for H 2 O 2 production are daunting obstacles to penetration of this technology into the wastewater tre…
View article: Lithium and cobalt extraction from LiCoO2 assisted by p(VBPDA-co-FDA) copolymers in supercritical CO2
Lithium and cobalt extraction from LiCoO2 assisted by p(VBPDA-co-FDA) copolymers in supercritical CO2 Open
View article: Silver and Copper Nitride Cooperate for CO Electroreduction to Propanol
Silver and Copper Nitride Cooperate for CO Electroreduction to Propanol Open
The need of carbon sources for the chemical industry, alternative to fossil sources, has pointed to CO 2 as a possible feedstock. While CO 2 electroreduction (CO 2 R) allows production of interesting organic compounds, it suffers from larg…
View article: A Novel Electrochemical Flow-Cell for Operando XAS Investigations On X-ray Opaque Supports
A Novel Electrochemical Flow-Cell for Operando XAS Investigations On X-ray Opaque Supports Open
Improvement of electrochemical technologies is one of the most popular topics in the field of renewable energy. However, this process requires a deep understanding of the electrode electrolyte interface behavior under operando conditions. …
View article: Single atom Cu-N-C catalysts for the electro-reduction of CO2 to CO assessed by rotating ring-disc electrode
Single atom Cu-N-C catalysts for the electro-reduction of CO2 to CO assessed by rotating ring-disc electrode Open
The electrochemical CO2 reduction reaction (CO2RR) to controllable chemicals is considered as a promising pathway to store intermittent renewable energy. Herein, a set of catalysts based on copper-nitrogen-doped carbon xerogel (Cu-N-C) are…
View article: A Peculiar Photo‐Induced Transformation Exalted in Nanometric Size CoFe Prussian Blue Analogs
A Peculiar Photo‐Induced Transformation Exalted in Nanometric Size CoFe Prussian Blue Analogs Open
The discovery of a photomagnetic effect in a CoFe Prussian blue analog (PBA) has triggered a growing interest for photo‐switchable bimetallic cyanide‐bridged systems. Nevertheless, in between cyanide‐bridged extended coordination polymers …
View article: Oxide Coating Role on the Bulk Structural Stability of Active LiMn<sub>2</sub>O<sub>4</sub> Cathodes
Oxide Coating Role on the Bulk Structural Stability of Active LiMn<sub>2</sub>O<sub>4</sub> Cathodes Open
The protective coating of the electrode materials is a known source of improvement of the cycling performances in battery devices. In the case of the LiMn2O4 cathodes, the coating with a thin alumina layer has been pr…
View article: How Nanoparticles Modify Adsorbed Proteins: Impact of Silica Nanoparticles on the Hemoglobin Active Site
How Nanoparticles Modify Adsorbed Proteins: Impact of Silica Nanoparticles on the Hemoglobin Active Site Open
The adsorption of proteins on surfaces has been studied for a long time, but the relationship between the structural and functional properties of the adsorbed protein and the adsorption mechanism remains unclear. Using hemoglobin adsorbed …
View article: Structural and Reactivity Effects of Secondary Metal Doping into Iron-Nitrogen-Carbon Catalysts for Oxygen Electroreduction
Structural and Reactivity Effects of Secondary Metal Doping into Iron-Nitrogen-Carbon Catalysts for Oxygen Electroreduction Open
While improved activity was recently reported for bimetallic iron-metal-nitrogen-carbon (FeMNC) catalysts for the oxygen reduction reaction (ORR) in acid medium, the nature of active sites and interactions between the two metals are poorly…
View article: Modulating the Fe-N4 active sites content by nitrogen source in Fe-N-C aerogel catalysts for Proton Exchange Membrane Fuel Cell
Modulating the Fe-N4 active sites content by nitrogen source in Fe-N-C aerogel catalysts for Proton Exchange Membrane Fuel Cell Open
View article: Author Correction: P-block single-metal-site tin/nitrogen-doped carbon fuel cell cathode catalyst for oxygen reduction reaction
Author Correction: P-block single-metal-site tin/nitrogen-doped carbon fuel cell cathode catalyst for oxygen reduction reaction Open
View article: Les matériaux carbonés Fe-N-C dopés au fer pour l'électrocatalyse
Les matériaux carbonés Fe-N-C dopés au fer pour l'électrocatalyse Open
International audience
View article: Dataset for the paper "High Loading of Single Atomic Iron Sites in Pyrolysed Fe-NC Oxygen Reduction Catalysts for Proton Exchange Membrane Fuel Cells", DOI:10.1038/s41929-022-00772-9
Dataset for the paper "High Loading of Single Atomic Iron Sites in Pyrolysed Fe-NC Oxygen Reduction Catalysts for Proton Exchange Membrane Fuel Cells", DOI:10.1038/s41929-022-00772-9 Open
The data in this spreadsheet was used to produce the figures in the paper Authors: Asad Mehmood, Mengjun Gong, Frédéric Jaouen, Aaron Roy, Andrea Zitolo, Anastassiya Khan, Moulay-Tahar Sougrati, Mathias Primbs, Ale…
View article: Dataset for the paper "High Loading of Single Atomic Iron Sites in Pyrolysed Fe-NC Oxygen Reduction Catalysts for Proton Exchange Membrane Fuel Cells", DOI:10.1038/s41929-022-00772-9
Dataset for the paper "High Loading of Single Atomic Iron Sites in Pyrolysed Fe-NC Oxygen Reduction Catalysts for Proton Exchange Membrane Fuel Cells", DOI:10.1038/s41929-022-00772-9 Open
The data in this spreadsheet was used to produce the figures in the paper Authors: Asad Mehmood, Mengjun Gong, Frédéric Jaouen, Aaron Roy, Andrea Zitolo, Anastassiya Khan, Moulay-Tahar Sougrati, Mathias Primbs, Alex Martinez Bonastre, Dash…
View article: Multi-Atom Pt and Ptru Catalysts for High Performance Aemfcs with Ultra-Low Pgm Content
Multi-Atom Pt and Ptru Catalysts for High Performance Aemfcs with Ultra-Low Pgm Content Open
View article: Pure silica-supported transition metal catalysts for the non-oxidative dehydrogenation of ethane: confinement effects on the stability
Pure silica-supported transition metal catalysts for the non-oxidative dehydrogenation of ethane: confinement effects on the stability Open
All-silica MFI zeolite was used as a support for the synthesis of promoter-free robust transition metal catalysts. Effects of different physical parameters and catalyst deactivation mechanism were studied for the ethane dehydrogenation rea…
View article: Understanding how single-atom site density drives the performance and durability of PGM-free Fe–N–C cathodes in anion exchange membrane fuel cells
Understanding how single-atom site density drives the performance and durability of PGM-free Fe–N–C cathodes in anion exchange membrane fuel cells Open
View article: Enhancing the electrocatalytic activity of Fe phthalocyanines for the oxygen reduction reaction by the presence of axial ligands: Pyridine-functionalized single-walled carbon nanotubes
Enhancing the electrocatalytic activity of Fe phthalocyanines for the oxygen reduction reaction by the presence of axial ligands: Pyridine-functionalized single-walled carbon nanotubes Open
View article: The origin of the high electrochemical activity of pseudo-amorphous iridium oxides
The origin of the high electrochemical activity of pseudo-amorphous iridium oxides Open
Combining high activity and stability, iridium oxide remains the gold standard material for the oxygen evolution reaction in acidic medium for green hydrogen production. The reasons for the higher electroactivity of amorphous iridium oxide…
View article: Stable Cr-MFI Catalysts for the Nonoxidative Dehydrogenation of Ethane: Catalytic Performance and Nature of the Active Sites
Stable Cr-MFI Catalysts for the Nonoxidative Dehydrogenation of Ethane: Catalytic Performance and Nature of the Active Sites Open
The nonoxidative catalytic dehydrogenation of ethane allows the production of ethylene at lower temperatures than those applied in steam crackers. This, however, requires stable catalysts that minimize coke production. Here, we report a si…