Andrew D. Bond
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View article: Synthesis and Electrolyte Study of Lithium Bis(perfluorinated pinacolato)Borate for Lithium‐Ion Batteries
Synthesis and Electrolyte Study of Lithium Bis(perfluorinated pinacolato)Borate for Lithium‐Ion Batteries Open
Lithium‐ion batteries are the leading rechargeable battery technology. 1 M lithium hexafluorophosphate (LiPF 6 ) dissolved in carbonate solvents is commonly used as the electrolyte; however, LiPF 6 is hygroscopic and forms toxic HF in the …
View article: Understanding the Photophysical Properties of the Polyoxotitanates Ln<sub>2</sub>Ti<sub>4</sub>O<sub>6</sub>(phen)<sub>2</sub>(met)<sub>10</sub>
Understanding the Photophysical Properties of the Polyoxotitanates Ln<sub>2</sub>Ti<sub>4</sub>O<sub>6</sub>(phen)<sub>2</sub>(met)<sub>10</sub> Open
Understanding and tuning the luminescent properties of lanthanide(III) ions is of great interest for a range of optical applications, for example photo down-shifters for photovoltaics. In this work a series of isostructural polyoxotitanate…
View article: Synthesis and Optical Properties of Ln <sub>2</sub> Ln′ <sub>2</sub> ‐Tetranuclear Lanthanide(III) Complexes
Synthesis and Optical Properties of Ln <sub>2</sub> Ln′ <sub>2</sub> ‐Tetranuclear Lanthanide(III) Complexes Open
A set of structurally related heterotetranuclear lanthanide(III) (Ln) complexes containing Ln 1 2 Ln 2 2 cores has been synthesized as potential downshifting materials for solar applications. The Ln 1 2 Ln 2 2 complexes can be regarded as …
View article: Radical TADF: Quartet‐Derived Luminescence with Dark TEMPO
Radical TADF: Quartet‐Derived Luminescence with Dark TEMPO Open
High‐spin states in organic molecules offer promising tuneability for quantum technologies. Photogenerated quartet excitons are an extensively studied platform, but their applications are limited by the absence of optical read‐out via lumi…
View article: GaussianVideo: Efficient Video Representation via Hierarchical Gaussian Splatting
GaussianVideo: Efficient Video Representation via Hierarchical Gaussian Splatting Open
Efficient neural representations for dynamic video scenes are critical for applications ranging from video compression to interactive simulations. Yet, existing methods often face challenges related to high memory usage, lengthy training t…
View article: Accessing iridium Cp* as a cofactor for artificial metalloenzymes
Accessing iridium Cp* as a cofactor for artificial metalloenzymes Open
By introducing new-to-nature transformations, artificial metalloenzymes hold great potential for expanding the biosynthetic toolbox. The chemistry of an active cofactor in these enzymes is highly dependent on how the holoprotein is assembl…
View article: Quantification of the effects of n-π* interactions on the H-bonding properties of amide groups
Quantification of the effects of n-π* interactions on the H-bonding properties of amide groups Open
The free energy contribution due to cooperativity between an n–π* interaction and a H-bond was found to be within the experimental error, suggesting that associated contributions to the stability of folded proteins are small.
View article: Relationship between interaction geometry and cooperativity measured in H-bonded networks of hydroxyl groups
Relationship between interaction geometry and cooperativity measured in H-bonded networks of hydroxyl groups Open
Cooperativity in H-bonded networks of hydroxyl groups depends strongly on the polarity of the interacting groups but is relatively insensitive to the precise geometric arrangement and alignment of the OH bonds.
View article: Substituent Effects on Cooperativity in Three-Component H-Bond Networks Involving Phenol–Phenol Interactions
Substituent Effects on Cooperativity in Three-Component H-Bond Networks Involving Phenol–Phenol Interactions Open
Cooperativity between H-bonding interactions in networks is a fundamental aspect of solvation and self-assembly in molecular systems. The interaction of a series of bisphenols, which make an intramolecular H-bond between the two hydroxyl g…
View article: The role of Li⋯F interactions in lithium and heterobimetallic lithium–magnesium complexes of the hexafluoroisopropoxide anion
The role of Li⋯F interactions in lithium and heterobimetallic lithium–magnesium complexes of the hexafluoroisopropoxide anion Open
View article: Open-shell TADF: Quartet-derived luminescence with dark radicals
Open-shell TADF: Quartet-derived luminescence with dark radicals Open
High-spin states in organic molecules offer promising tuneability for quantum technologies. Photogenerated quartet excitons are an extensively studied platform, but their applications are limited by the absence of optical read-out via lumi…
View article: Borates <i>vs</i>. aluminates: comparing the anion for lithium-ion batteries
Borates <i>vs</i>. aluminates: comparing the anion for lithium-ion batteries Open
Of a series of related borate and aluminate salts investigated, the unsolvated aluminate Li[Al(hfip) 4 ] (hfip = (CF 3 ) 2 CHO) resulted in superior battery cycling and is a promising electrolyte for next-generation lithium batteries.
View article: Transparent, Sprayable Plastic Films for Luminescent Down‐Shifted‐Assisted Plant Growth
Transparent, Sprayable Plastic Films for Luminescent Down‐Shifted‐Assisted Plant Growth Open
The world's steadily growing population and global heating due to climate change are a threat to food security. To meet this challenge, novel technologies are needed to increase crop production in a sustainable way. In this work, the use o…
View article: Steric Control of Luminescence in Phenyl-Substituted Trityl Radicals
Steric Control of Luminescence in Phenyl-Substituted Trityl Radicals Open
Triphenylmethyl (trityl) radicals have shown potential for use in organic optoelectronic applications, but the design of practical trityl structures has been limited to donor/radical charge-transfer systems due to the poor luminescence of …
View article: Suppressing <i>Cis</i>/<i>Trans</i> ‘Ring‐Flipping’ in Organoaluminium(III)‐2‐Pyridyl Dimers–Design Strategies Towards Lewis Acid Catalysts for Alkene Oligomerisation
Suppressing <i>Cis</i>/<i>Trans</i> ‘Ring‐Flipping’ in Organoaluminium(III)‐2‐Pyridyl Dimers–Design Strategies Towards Lewis Acid Catalysts for Alkene Oligomerisation Open
Owing to its high natural abundance compared to the commonly used transition (precious) metals, as well as its high Lewis acidity and ability to change oxidation state, aluminium has recently been explored as the basis for a range of singl…
View article: Suppression of Dexter transfer by covalent encapsulation for efficient matrix-free narrowband deep blue hyperfluorescent OLEDs
Suppression of Dexter transfer by covalent encapsulation for efficient matrix-free narrowband deep blue hyperfluorescent OLEDs Open
View article: Sodium Tetrakis(hexafluoroisopropyloxy)aluminates: Synthesis and Electrochemical Characterisation of a Room‐Temperature Solvated Ionic Liquid.
Sodium Tetrakis(hexafluoroisopropyloxy)aluminates: Synthesis and Electrochemical Characterisation of a Room‐Temperature Solvated Ionic Liquid. Open
Invited for this issue's Front Cover is the groups of Grey and Wright. The cover picture shows the chemical structure of sodium tetrakis(hexafluoroisopropyloxy)aluminate, with the sodium ion in the beach ball and the aluminate anion floati…
View article: Manganese(<scp>ii</scp>) promotes prebiotically plausible non-enzymatic RNA ligation reactions
Manganese(<span>ii</span>) promotes prebiotically plausible non-enzymatic RNA ligation reactions Open
Using different prebiotically plausible activating reagents, the RNA ligation yield was significantly increased in the presence of Mn(II).
View article: Front Cover: Sodium Tetrakis(hexafluoroisopropyloxy)aluminates: Synthesis and Electrochemical Characterisation of a Room‐Temperature Solvated Ionic Liquid (ChemElectroChem 2/2024)
Front Cover: Sodium Tetrakis(hexafluoroisopropyloxy)aluminates: Synthesis and Electrochemical Characterisation of a Room‐Temperature Solvated Ionic Liquid (ChemElectroChem 2/2024) Open
The Front Cover art uses a pool theme as the sodium aluminate salt synthesised in this work is a room-temperature ionic liquid, thus the sodium salt in the pool represents this. The application of the salt in a sodium-ion battery is shown …
View article: Exploring the Landscape of Heterocyclic Quinones for Redox Flow Batteries
Exploring the Landscape of Heterocyclic Quinones for Redox Flow Batteries Open
Redox flow batteries (RFBs) rely on the development of cheap, highly soluble, and high energy-density electrolytes. Several candidate quinones have already been investigated in the literature as two-electron anolytes or catholytes, benefit…
View article: CCDC 2283717: Experimental Crystal Structure Determination
CCDC 2283717: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2283718: Experimental Crystal Structure Determination
CCDC 2283718: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2283721: Experimental Crystal Structure Determination
CCDC 2283721: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2283720: Experimental Crystal Structure Determination
CCDC 2283720: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2283716: Experimental Crystal Structure Determination
CCDC 2283716: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2283719: Experimental Crystal Structure Determination
CCDC 2283719: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2283722: Experimental Crystal Structure Determination
CCDC 2283722: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2283715: Experimental Crystal Structure Determination
CCDC 2283715: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2256898: Experimental Crystal Structure Determination
CCDC 2256898: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2256897: Experimental Crystal Structure Determination
CCDC 2256897: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …