Antony Nearchou
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View article: Mechanistic Insights into Cs-Ion Exchange in the Zeolite Chabazite from <i>In Situ</i> Powder X-Ray Diffraction
Mechanistic Insights into Cs-Ion Exchange in the Zeolite Chabazite from <i>In Situ</i> Powder X-Ray Diffraction Open
Zeolites contain extraframework cations that are exchangeable under favorable aqueous conditions; this is the fundamental feature for their application in water purification and necessary to produce cation forms for other applications such…
View article: Engineered species-selective ion-exchange in tuneable dual-phase zeolite composites
Engineered species-selective ion-exchange in tuneable dual-phase zeolite composites Open
The partial interzeolite transformation of a natural mordenite presents an effective method to diversify the structure of natural zeolites and enhance their ion-exchange properties.
View article: Doped umbite materials for selective abatement of cesium radionuclides from nuclear waste streams
Doped umbite materials for selective abatement of cesium radionuclides from nuclear waste streams Open
Sb- and Nb-doped Zr and Sn-umbites have been prepared using hydrothermal synthesis with both high purity and yield. All four materials display excellent removal of Cs+ cations from acidic, neutral, and basic solutions, abating at least 80%…
View article: CSD 2178841: Experimental Crystal Structure Determination
CSD 2178841: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: CSD 2178842: Experimental Crystal Structure Determination
CSD 2178842: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: Crystal Structures of a Cubic Tin(II) Germanate, α-Sn<sub>6</sub>GeO<sub>8</sub>, and a Tetragonal Tin(II) Silicate, γ-Sn<sub>6</sub>SiO<sub>8</sub>
Crystal Structures of a Cubic Tin(II) Germanate, α-Sn<sub>6</sub>GeO<sub>8</sub>, and a Tetragonal Tin(II) Silicate, γ-Sn<sub>6</sub>SiO<sub>8</sub> Open
A cubic tin(II) germanate, α-Sn6GeO8 (space group F4̅3m, a = 10.52521(2) Å, and Z = 4), has been synthesized by both regular hydrothermal and microwave-assisted hydrothermal methods, and the crystal structure of this material has been solve…
View article: The Effect of Cation Exchange on the Pore Geometry of Zeolite L
The Effect of Cation Exchange on the Pore Geometry of Zeolite L Open
Zeolites with the LTL framework topology are attractive materials for use in optoelectronics, gas adsorption and as chemical reactors. This is due to their unique, one-dimensional (1D) channel systems which are large enough to act as hosts…
View article: The Effect of Cation Exchange on the Pore Geometry of Zeolite L
The Effect of Cation Exchange on the Pore Geometry of Zeolite L Open
Zeolites with the LTL framework topology are attractive materials for use in optoelectronics, gas adsorption and as chemical reactors. This is due to their unique, one-dimensional (1D) channel systems which are large enough to act as hosts…
View article: The Structure and Location of 18-Crown-6 Ether in Zeolites RHO and ZK-5
The Structure and Location of 18-Crown-6 Ether in Zeolites RHO and ZK-5 Open
The use of organic additives presents the greatest versatility and control of zeolite synthesis in order to prepare novel architectures for desired applications. Despite this prospect, there is little clarity of how organic additives are i…
View article: The structure and location of 18-crown-6 ether in zeolites RHO and ZK-5
The structure and location of 18-crown-6 ether in zeolites RHO and ZK-5 Open
The use of organic additives presents the greatest versatility and control of zeolite synthesis in order to prepare novel architectures for desired applications. Despite this prospect, there is little clarity of how organic additives are i…
View article: Dataset for "Zeolites fit for a Crown: Probing Host-Guest Interactions with Thermogravimetric Methods"
Dataset for "Zeolites fit for a Crown: Probing Host-Guest Interactions with Thermogravimetric Methods" Open
This dataset contains the relevant data for the article "Zeolites fit for a Crown: Probing Host-Guest Interactions with Thermogravimetric Methods". This includes the following. Powder X-ray diffraction (PXRD) data used to identify and conf…
View article: Differentiating the role of organic additives to assemble open framework aluminosilicates using INS spectroscopy
Differentiating the role of organic additives to assemble open framework aluminosilicates using INS spectroscopy Open
Uneasy lies a pore that bears a crown – INS study on crown-ether containing zeolites.
View article: Differentiating the Role of Organic Additives to Assemble Open Framework Aluminosilicate Zeolites Using INS Spectroscopy
Differentiating the Role of Organic Additives to Assemble Open Framework Aluminosilicate Zeolites Using INS Spectroscopy Open
Presently there is little clarity concerning how organic additives control structure formation in the synthesis of zeolite catalysts and their chemistry. Such ambiguity is a major obstacle towards the synthesis design for new bespoke zeoli…
View article: Differentiating the Role of Organic Additives to Assemble Open Framework Aluminosilicate Zeolites Using INS Spectroscopy
Differentiating the Role of Organic Additives to Assemble Open Framework Aluminosilicate Zeolites Using INS Spectroscopy Open
Presently there is little clarity concerning how organic additives control structure formation in the synthesis of zeolite catalysts and their chemistry. Such ambiguity is a major obstacle towards the synthesis design for new bespoke zeol…
View article: Dataset for "Pressure-induced symmetry changes in body-centred cubic zeolites"
Dataset for "Pressure-induced symmetry changes in body-centred cubic zeolites" Open
A repository of data used for the article "Pressure-induced symmetry changes in body-centred cubic zeolites". This includes high pressure powder X-ray diffraction data collected at the ID15B beamline at the European Synchrotron Radiation F…
View article: Pressure-induced symmetry changes in body-centred cubic zeolites
Pressure-induced symmetry changes in body-centred cubic zeolites Open
Previous work has shown a strong correlation between zeolite framework flexibility and the nature of structural symmetry and phase transitions. However, there is little experimental data regarding this relationship, in addition to how flex…
View article: Dataset for "Intrinsic flexibility of the EMT zeolite framework under pressure"
Dataset for "Intrinsic flexibility of the EMT zeolite framework under pressure" Open
A collection of the data used, and reported in the article "Intrinsic flexibility of the EMT zeolite framework under pressure". This includes high pressure powder X-ray diffraction data collected on the ID15B and ID27 beamlines at the Euro…
View article: Intrinsic Flexibility of the EMT Zeolite Framework under Pressure
Intrinsic Flexibility of the EMT Zeolite Framework under Pressure Open
The roles of organic additives in the assembly and crystallisation of zeolites are still not fully understood. This is important when attempting to prepare novel frameworks to produce new zeolites. We consider 18-crown-6 ether (18C6) as an…
View article: Intrinsic Flexibility of the EMT Zeolite Framework Under Pressure
Intrinsic Flexibility of the EMT Zeolite Framework Under Pressure Open
The roles of organic additives in the assembly and crystallisation of zeolites is still not fully understood. This is important when attempting to prepare novel frameworks to produce new zeolites. We consider 18-crown-6 ether as an additiv…
View article: Intrinsic Flexibility of the EMT Zeolite Framework Under Pressure
Intrinsic Flexibility of the EMT Zeolite Framework Under Pressure Open
The roles of organic additives in the assembly and crystallisation of zeolites is still not fully understood. This is important when attempting to prepare novel frameworks to produce new zeolites. We consider 18-crown-6 ether as an additiv…
View article: Pressure-Induced Symmetry Changes in Body-Centered Cubic Zeolites
Pressure-Induced Symmetry Changes in Body-Centered Cubic Zeolites Open
Previous work has shown a strong correlation between zeolite framework flexibility and the nature of structural symmetry and phase transitions. However, there is little experimental data regarding this relationship, in addition to how flex…
View article: Pressure-Induced Symmetry Changes in Body-Centered Cubic Zeolites
Pressure-Induced Symmetry Changes in Body-Centered Cubic Zeolites Open
Previous work has shown a strong correlation between zeolite framework flexibility and the nature of structural symmetry and phase transitions. However, there is little experimental data regarding this relationship, in addition to how flex…
View article: Zeolites Fit For A Crown: Probing Host-Guest Interactions with Thermogravimetric Methods
Zeolites Fit For A Crown: Probing Host-Guest Interactions with Thermogravimetric Methods Open
Through a combination of thermogravimetry, mass spectrometry and differential thermal analysis, we demonstrate for the first time that all four zeolites show experimental differences in their host-guest interactions with 18C6. In addition,…
View article: Zeolites Fit For A Crown: Probing Host-Guest Interactions with Thermogravimetric Methods
Zeolites Fit For A Crown: Probing Host-Guest Interactions with Thermogravimetric Methods Open
Through a combination of thermogravimetry, mass spectrometry and differential thermal analysis, we demonstrate for the first time that all four zeolites show experimental differences in their host-guest interactions with 18C6. In addition,…
View article: Dataset for "Systematic approaches towards template-free synthesis of EMT-type zeolites"
Dataset for "Systematic approaches towards template-free synthesis of EMT-type zeolites" Open
This dataset contains powder X-ray diffraction data, scanning electron microscopy (SEM) images and solid state nuclear magnetic resonance (NMR) spectroscopy data (29-Si, 27-Al and 23-Na nuclei), used in the article 'Systematic approaches t…