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View article: Conformational and Substitution Effects on the Donor and Reducing Strength of Tin(II) Porphyrinogens
Conformational and Substitution Effects on the Donor and Reducing Strength of Tin(II) Porphyrinogens Open
Meso ‐octaalkylcalix[4]pyrrolates are a class of redox‐active porphyrinogen ligands. They have been well established in d ‐ and f ‐block chemistry for over three decades but have only recently been introduced as ligands for p ‐block elemen…
View article: Concatenating Structural Constraint Effects at Tin for the Sequential Generation, Stabilization, and Transfer of Acyclic Aminocarbenes
Concatenating Structural Constraint Effects at Tin for the Sequential Generation, Stabilization, and Transfer of Acyclic Aminocarbenes Open
Structural constraint approaches have been employed toward different ends in recent years, from augmenting the nucleophilicity in pyramidalized low-valent p-block compounds to enhancing the Lewis acidities at planarized tetravalent p-block…
View article: CCDC 2102839: Experimental Crystal Structure Determination
CCDC 2102839: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2102841: Experimental Crystal Structure Determination
CCDC 2102841: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2102840: Experimental Crystal Structure Determination
CCDC 2102840: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Access to Unsymmetrically Substituted Diaryl Gold N‐Acyclic Carbene (NAC) and N‐Heterocyclic Carbene (NHC) Complexes via the Isonitrile Route
Access to Unsymmetrically Substituted Diaryl Gold N‐Acyclic Carbene (NAC) and N‐Heterocyclic Carbene (NHC) Complexes via the Isonitrile Route Open
A variety of unsymmetric diaryl gold N‐acyclic c arbene (NAC) complexes was synthesized via the isonitrile route by three different methods: (a) solvent free in a melt, (b) mechanochemically and (c) in THF at room temperature. The latter m…