Alexander S. Filatov
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View article: Structure and Synthesizability of Iron–Sulfur Metal–Organic Frameworks
Structure and Synthesizability of Iron–Sulfur Metal–Organic Frameworks Open
Sulfur-based metal-organic frameworks (MOFs) and coordination polymers (CPs) are an emerging class of hybrid materials that have received growing attention due to their magnetic, conductive, and catalytic properties with potential applicat…
View article: Lithium-rich, oxygen-deficient spinel obtained through low-temperature decomposition of heterometallic molecular precursor
Lithium-rich, oxygen-deficient spinel obtained through low-temperature decomposition of heterometallic molecular precursor Open
A heterometallic single-source molecular precursor Li2Mn2(tbaoac)6 (1 , tbaoac = tert -butyl acetoacetato) has been specifically designed to achieve the lowest decomposition temperature and a clean conversion to mixed-metal oxides. The cry…
View article: Surface engineering of Pt nanocatalysts with transition metal oleates for selective catalysis: a case study on the hydrogenation of α,β-unsaturated aldehydes
Surface engineering of Pt nanocatalysts with transition metal oleates for selective catalysis: a case study on the hydrogenation of α,β-unsaturated aldehydes Open
The adsorption of transition metal oleates on Pt nanoparticle surfaces creates a negative charge, promoting selective hydrogenation of CO bonds over CC bonds in nonpolar solvents, ensuring reactant solubility and improving catalytic effi…
View article: Pre-synthetic redox control of structure and properties in copper TTFtt coordination polymers
Pre-synthetic redox control of structure and properties in copper TTFtt coordination polymers Open
Conductive coordination polymers (CPs) with sulfur-based ligands offer strong metal–ligand interactions and redox tunability, making them promising candidates for electronic applications.
View article: Unlocking Mesoscopic Disorder in Graphitic Carbon with Spectroelectrochemistry
Unlocking Mesoscopic Disorder in Graphitic Carbon with Spectroelectrochemistry Open
Intrinsic structural and oxidic defects activate graphitic carbon electrodes towards electrochemical reactions underpinning energy conversion and storage technologies. Yet, these defects can also disrupt the long‐range and periodic arrange…
View article: Structure and Synthesizability of Iron-Sulfur Metal-Organic Frameworks
Structure and Synthesizability of Iron-Sulfur Metal-Organic Frameworks Open
Sulfur-based metal-organic frameworks (MOFs) and coordination polymers (CPs) are an emerging class of hybrid materials that have received growing attention due to their potential magnetic, conductive, and catalytic properties with applicat…
View article: Influence of Grain Size on Shape Memory and Internal Friction in Cu69.26Al25.86Mn4.88 Alloy
Influence of Grain Size on Shape Memory and Internal Friction in Cu69.26Al25.86Mn4.88 Alloy Open
Shape-memory alloys belong to the functional materials, which exhibit shape memory, superelasticity and high damping-capacity phenomena. Cu–Al–Mn shape-memory alloys remain of particular interest as they show good ma-chinability and are mu…
View article: Functionalization of Monolayer MoS<sub>2</sub> with Layered Multimolecular Architectures
Functionalization of Monolayer MoS<sub>2</sub> with Layered Multimolecular Architectures Open
Two dimensional van der Waals materials have attracted attention due to their unique properties that arise in the monolayer versus bulk limits. Monolayer MoS2 has been at the forefront of 2D materials due to its broad applicabil…
View article: Isolation and Crystallographic Characterization of an Octavalent Co<sub>2</sub>O<sub>2</sub> Diamond Core
Isolation and Crystallographic Characterization of an Octavalent Co<sub>2</sub>O<sub>2</sub> Diamond Core Open
High-valent cobalt oxides play a pivotal role in alternative energy technology as catalysts for water splitting and as cathodes in lithium-ion batteries. Despite this importance, the properties governing the stability of high-valent cobalt…
View article: Catalytic, Spectroscopic, and Theoretical Studies of Fe<sub>4</sub>S<sub>4</sub>-Based Coordination Polymers as Heterogenous Coupled Proton–Electron Transfer Mediators for Electrocatalysis
Catalytic, Spectroscopic, and Theoretical Studies of Fe<sub>4</sub>S<sub>4</sub>-Based Coordination Polymers as Heterogenous Coupled Proton–Electron Transfer Mediators for Electrocatalysis Open
Iron-sulfur clusters play essential roles in biological systems, and thus synthetic [Fe4S4] clusters have been an area of active research. Recent studies have demonstrated that soluble [Fe4S4] cl…
View article: CCDC 2105081: Experimental Crystal Structure Determination
CCDC 2105081: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2109375: Experimental Crystal Structure Determination
CCDC 2109375: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2104998: Experimental Crystal Structure Determination
CCDC 2104998: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Mechanistic Insights into Copper(I) and Copper(II) Cation Exchange Reactions in CdSe Nanoplatelets
Mechanistic Insights into Copper(I) and Copper(II) Cation Exchange Reactions in CdSe Nanoplatelets Open
In this study, we investigated the synthesis of copper selenide nanoplatelets (NPLs) through a cation exchange reaction (CER) in 5-monolayer-thick CdSe NPLs using Cu(I) and Cu(II) precursors. We discovered that the exposure of CdSe NPLs to…
View article: Mechanistic Insights into Copper(I) and Copper (II) Cation Exchange Reactions in CdSe Nanoplatelets
Mechanistic Insights into Copper(I) and Copper (II) Cation Exchange Reactions in CdSe Nanoplatelets Open
In this study, we investigated the synthesis of copper selenide nanoplatelets (NPLs) through a cation exchange reaction (CER) in 5 monolayers thick CdSe NPLs using Cu(I) and Cu(II) precursors. We discovered that the exposure of CdSe NPLs t…
View article: CCDC 2173744: Experimental Crystal Structure Determination
CCDC 2173744: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2173743: Experimental Crystal Structure Determination
CCDC 2173743: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Hybrid organic–inorganic two-dimensional metal carbide MXenes with amido- and imido-terminated surfaces
Hybrid organic–inorganic two-dimensional metal carbide MXenes with amido- and imido-terminated surfaces Open
View article: Mechanistic Insights into Copper(I) and Copper (II) Cation Exchange Reactions in CdSe Nanoplatelets
Mechanistic Insights into Copper(I) and Copper (II) Cation Exchange Reactions in CdSe Nanoplatelets Open
In this study, we investigated the synthesis of copper selenide nanoplatelets (NPLs) through a cation exchange reaction (CER) in 5 monolayers thick CdSe NPLs using Cu(I) and Cu(II) precursors. We discovered that the exposure of CdSe NPLs t…
View article: Colloidal Gelation in Liquid Metals Enables Functional Nanocomposites of 2D Metal Carbides (MXenes) and Lightweight Metals
Colloidal Gelation in Liquid Metals Enables Functional Nanocomposites of 2D Metal Carbides (MXenes) and Lightweight Metals Open
Nanomaterials\ndispersed in different media, such as liquids or\npolymers, generate a variety of functional composites with synergistic\nproperties. In this work, we discuss liquid metals as the nanomaterials’\ndispersion media. For exampl…
View article: Hybrid organic-inorganic two-dimensional metal carbide MXenes with amido- and imido-terminated surfaces
Hybrid organic-inorganic two-dimensional metal carbide MXenes with amido- and imido-terminated surfaces Open
Two-dimensional (2D) transition-metal carbides and nitrides (MXenes) show impressive performance in applications, such as supercapacitors, batteries, electromagnetic interference shielding, or electrocatalysis. These materials combine the …
View article: Broad Electronic Modulation of Two-Dimensional Metal–Organic Frameworks over Four Distinct Redox States
Broad Electronic Modulation of Two-Dimensional Metal–Organic Frameworks over Four Distinct Redox States Open
Two-dimensional (2D) inorganic materials have emerged as exciting platforms for (opto)electronic, thermoelectric, magnetic, and energy storage applications. However, electronic redox tuning of these materials can be difficult. Instead, 2D …
View article: CCDC 2174521: Experimental Crystal Structure Determination
CCDC 2174521: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Broad Electronic Modulation of 2D Metal-Organic Frameworks Over Four Distinct Redox States
Broad Electronic Modulation of 2D Metal-Organic Frameworks Over Four Distinct Redox States Open
Two-dimensional (2D) inorganic materials have emerged as exciting platforms for (opto)electronic, thermoelectric, magnetic, and energy storage applications. However, electronic redox tuning of these materials can be difficult. Instead, 2D …
View article: Structure and Magnetic Properties of Pseudo-1D Chromium Thiolate Coordination Polymers
Structure and Magnetic Properties of Pseudo-1D Chromium Thiolate Coordination Polymers Open
The synthesis, structure, and magnetic properties of two novel, pseudo-one-dimensional (1D) chromium thiolate coordination polymers (CPs), CrBTT and Cr2BDT3, are reported. The structures of these materials were determ…
View article: CCDC 1877225: Experimental Crystal Structure Determination
CCDC 1877225: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1877227: Experimental Crystal Structure Determination
CCDC 1877227: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1877223: Experimental Crystal Structure Determination
CCDC 1877223: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Manganese(II) complexes of 1,1′-bis[(pyridin-2-yl)methyl)]-2,2′-bipiperidine (PYBP): Synthesis, structure, catalytic properties in alkene epoxidation with hydrogen peroxide, and related mechanistic studies
Manganese(II) complexes of 1,1′-bis[(pyridin-2-yl)methyl)]-2,2′-bipiperidine (PYBP): Synthesis, structure, catalytic properties in alkene epoxidation with hydrogen peroxide, and related mechanistic studies Open
View article: Intrinsic glassy-metallic transport in an amorphous coordination polymer
Intrinsic glassy-metallic transport in an amorphous coordination polymer Open