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Differentiating between F and OH Ligands in Homologous Gold(III) Complexes beyond X‐Ray Crystallography Open
The homologous fluoride and hydroxide complexes of gold(III) [PPh 4 ][(CF 3 ) 3 AuX] [X = F ( 1 ), OH ( 2 )] have been structurally characterized by single‐crystal X‐ray diffraction methods. Both of them crystallize in the P 2 1 / n space …
Protective effect of the perchlorophenyl group in organophosphorus chemistry Open
The homoleptic phosphine with the bulky perchlorophenyl group, (C6Cl5)3P (1), exhibits trigonal pyramidal structure (TPY-3), yet considerably flattened: Σ(C–P–C') = 321.0(1)°. Key steric and electronic properties of this simple organophosp…
Frontispiz: The CF<sub>3</sub> Group as a Synthon of the CF<sup>+</sup> Unit in Palladium Chemistry Open
Organometallic Chemistry. In their Communication (e202403108), Babil Menjón et al. demonstrate the CF3 group as a synthon of the CF+ unit in palladium chemistry.
Frontispiece: The CF<sub>3</sub> Group as a Synthon of the CF<sup>+</sup> Unit in Palladium Chemistry Open
Organometallic Chemistry. In their Communication (e202403108), Babil Menjón et al. demonstrate the CF3 group as a synthon of the CF+ unit in palladium chemistry.
The CF<sub>3</sub> Group as a Synthon of the CF<sup>+</sup> Unit in Palladium Chemistry Open
The homoleptic trifluoromethyl‐palladium(II) complex [Pd(CF 3 ) 4 ] 2− ( 1 ) is shown to be highly active towards amines. Thus, when treated with primary amines RNH 2 , it readily undergoes aminolysis of one of the CF 3 ligands affording t…
Cover Feature: The Fluoride Method: Access to Silver(III) NHC Complexes (Chem. Eur. J. 12/2024) Open
Multipurpose silver(III) fluoride. Access to the first silver(III) carbene complexes has been achieved by reaction of the fluoride [PPh4][(CF3)3AgF] precursor with different imidazolium salts. The novel methodology circumvents the use of f…
The Fluoride Method: Access to Silver(III) NHC Complexes Open
We have synthesized the first silver(III) carbene complexes, (CF 3 ) 3 Ag(NHC), by direct reaction of the silver(III) fluoride precursor complex [PPh 4 ][(CF 3 ) 3 AgF] with different imidazolium salts. This novel methodology circumvents t…
CCDC 2226908: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2226910: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2226909: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2226906: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2226905: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2226907: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2226904: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2180331: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2180333: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2180332: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
Electrophilicity of neutral square-planar organosilver(<span>iii</span>) compounds Open
Neutral silver( iii ) compounds stabilised with just monodentate ligands are found to exhibit a distinct tendency to associate an additional ligand at the apical position. They include the first documented compound with a Ag( iii )–As bond.
Terminal Au−N and Au−O Units in Organometallic Frames Open
Since gold is located well beyond the oxo wall, chemical species with terminal Au−N and Au−O units are extremely rare and limited to low coordination numbers. We report here that these unusual units can be trapped within a suitable organom…
A Five‐Coordinate Compound with Inverted Ligand Field: An Unprecedented Geometry for Silver(III) Open
By using suitable synthetic procedures, we have first isolated the square‐planar organosilver(III) compounds [PPh 4 ][ trans ‐(CF 3 ) 2 AgX 2 ] [X=Cl ( 1 a ), Br ( 2 a )]. The geometry and stereochemistry of the chloro‐derivative 1 a have …
A Five‐Coordinate Compound with Inverted Ligand Field: An Unprecedented Geometry for Silver(III) Open
By using suitable synthetic procedures, we have first isolated the square‐planar organosilver(III) compounds [PPh 4 ][ trans ‐(CF 3 ) 2 AgX 2 ] [X=Cl ( 1 a ), Br ( 2 a )]. The geometry and stereochemistry of the chloro‐derivative 1 a have …
CCDC 2084741: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2084742: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2084740: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2084743: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …