Bernd Berger
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View article: Deoxygenation of Ketones and α‐Ketoesters with a Bimetallic Iridium‐Molybdenum Catalyst
Deoxygenation of Ketones and α‐Ketoesters with a Bimetallic Iridium‐Molybdenum Catalyst Open
The selective reduction of ketones to the corresponding hydrocarbons is a fundamental transformation in organic synthesis with applications ranging from pharmaceuticals to biomass valorization. Traditional methods such as the Wolff–Kishner…
View article: On the Viability of Carbonyl Hydroboration Catalysed by Aluminium Hydrides
On the Viability of Carbonyl Hydroboration Catalysed by Aluminium Hydrides Open
The hydroboration of aldehydes and ketones by pinacolborane (HBpin) catalysed by (Nacnac) Dipp Al(OTf)H ((Nacnac) Dipp = HC(MeCDippN) 2 ; Dipp = C 6 H 3 i Pr 2 ‐2,6; Tf = SO 2 CF 3 ) was first reported in 2015. This study represented a lan…
View article: On the Viability of Carbonyl Hydroboration Catalysed by Aluminium Hydrides
On the Viability of Carbonyl Hydroboration Catalysed by Aluminium Hydrides Open
The hydroboration of aldehydes and ketones by pinacolborane (HBpin) catalysed by (Nacnac) Dipp Al(OTf)H ((Nacnac) Dipp = HC(MeCDippN) 2 ; Dipp = C 6 H 3 i Pr 2 ‐2,6; Tf = SO 2 CF 3 ) was first reported in 2015. This study represented a lan…
View article: C–H functionalization via single atom metathesis of C–H and C–X bonds
C–H functionalization via single atom metathesis of C–H and C–X bonds Open
Metathesis and reversible catalytic reactions are fundamentally intriguing and powerful tools in modern synthetic chemistry. While most reversible catalytic reactions are predicated on breaking and forming reactive functional groups, the a…