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View article: CCDC 2240221: Experimental Crystal Structure Determination
CCDC 2240221: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2240220: Experimental Crystal Structure Determination
CCDC 2240220: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2240219: Experimental Crystal Structure Determination
CCDC 2240219: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Metal–biomolecule frameworks (BioMOFs): a novel approach for “green” optoelectronic applications
Metal–biomolecule frameworks (BioMOFs): a novel approach for “green” optoelectronic applications Open
A water-stable, BDC-bioMOF was synthesized, characterized, and loaded with silver ions or highly emissive rare earth (RE). The materials were used as active layers in a proof-of-concept sustainable light-emitting device.
View article: Thermal defect engineering of precious group metal–organic frameworks: impact on the catalytic cyclopropanation reaction
Thermal defect engineering of precious group metal–organic frameworks: impact on the catalytic cyclopropanation reaction Open
This work highlights the catalytic cyclopropanation and its characteristics as a novel analytical tool to investigate complex MOF structures.
View article: A Titanium(IV)‐Based Metal–Organic Framework Featuring Defect‐Rich Ti‐O Sheets as an Oxidative Desulfurization Catalyst
A Titanium(IV)‐Based Metal–Organic Framework Featuring Defect‐Rich Ti‐O Sheets as an Oxidative Desulfurization Catalyst Open
While titanium‐based metal–organic frameworks (MOFs) have been widely studied for their (photo)catalytic potential, only a few Ti IV MOFs have been reported owing to the high reactivity of the employed titanium precursors. The synthesis of…
View article: Geminal Coordinatively Unsaturated Sites on MOF‐808 for the Selective Uptake of Phenolics from a Real Bio‐Oil Mixture
Geminal Coordinatively Unsaturated Sites on MOF‐808 for the Selective Uptake of Phenolics from a Real Bio‐Oil Mixture Open
The capping formate anions of the metal–organic framework (MOF) zirconium benzene‐1,3,5‐tricarboxylate (MOF‐808) were removed by a solvent exchange procedure, resulting in a formate‐free MOF‐808 sample containing “geminal” defects consisti…
View article: Active Role of Methanol in Post-Synthetic Linker Exchange in the Metal–Organic Framework UiO-66
Active Role of Methanol in Post-Synthetic Linker Exchange in the Metal–Organic Framework UiO-66 Open
UiO-66 is known as one of the most robust metal–organic framework materials. Nevertheless, UiO-66 has also been shown to undergo postsynthetic exchange of structural linkers with surprising ease in some solvents. To date, the exchange mech…
View article: Layered Zn<sub>2</sub>[Co(CN)<sub>6</sub>](CH<sub>3</sub>COO) double metal cyanide: a two-dimensional DMC phase with excellent catalytic performance
Layered Zn<sub>2</sub>[Co(CN)<sub>6</sub>](CH<sub>3</sub>COO) double metal cyanide: a two-dimensional DMC phase with excellent catalytic performance Open
A new, layered double metal cyanide phase proved to be a reusable, stable and highly active catalyst in two important DMC applications.
View article: Single-site metal–organic framework catalysts for the oxidative coupling of arenes <i>via</i> C–H/C–H activation
Single-site metal–organic framework catalysts for the oxidative coupling of arenes <i>via</i> C–H/C–H activation Open
Heterogeneous palladium single-site MOF catalysts for the oxidative coupling of arenes via C–H/C–H: superior TONs due to active site isolation.
View article: Network topology and cavity confinement-controlled diastereoselectivity in cyclopropanation reactions catalyzed by porphyrin-based MOFs
Network topology and cavity confinement-controlled diastereoselectivity in cyclopropanation reactions catalyzed by porphyrin-based MOFs Open
In this work, we show that the stereoselectivity of a reaction can be controlled by directing groups of substrates, by network topology and by local cavity confinement of metal–organic framework (MOF) catalysts.
View article: Phenolics isolation from bio-oil using the metal–organic framework MIL-53(Al) as a highly selective adsorbent
Phenolics isolation from bio-oil using the metal–organic framework MIL-53(Al) as a highly selective adsorbent Open
The selective uptake of phenolic compounds, a key step of bio-refining, was achieved on MIL-53(Al) and Basolite A100 both from a simulated bio-oil and a real pyrolysis bio-oil.
View article: Sodium-coupled electron transfer reactivity of metal–organic frameworks containing titanium clusters: the importance of cations in redox chemistry
Sodium-coupled electron transfer reactivity of metal–organic frameworks containing titanium clusters: the importance of cations in redox chemistry Open
Storage of electrons in the Ti8O8 nodes of MOF MIL-125 is controlled by the presence of charge-balancing Na+ cations.
View article: Highly stable and porous porphyrin-based zirconium and hafnium phosphonates – electron crystallography as an important tool for structure elucidation
Highly stable and porous porphyrin-based zirconium and hafnium phosphonates – electron crystallography as an important tool for structure elucidation Open
A highly porous and stable Zr-MOF containing a planar porphyrin-based tetraphosphonic acid was synthesized and characterized regarding its sorption properties and chemical stability.
View article: CCDC 1831844: Experimental Crystal Structure Determination
CCDC 1831844: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1581692: Experimental Crystal Structure Determination
CCDC 1581692: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: A precursor method for the synthesis of new Ce(<scp>iv</scp>) MOFs with reactive tetracarboxylate linkers
A precursor method for the synthesis of new Ce(<span>iv</span>) MOFs with reactive tetracarboxylate linkers Open
A new precursor method using glycinate/nitrate capped Ce6 clusters enables the synthesis of Ce(iv) MOFs with reactive linkers.
View article: Adsorption and Separation of Aromatic Amino Acids from Aqueous Solutions Using Metal–Organic Frameworks
Adsorption and Separation of Aromatic Amino Acids from Aqueous Solutions Using Metal–Organic Frameworks Open
Metal-organic frameworks (MOFs) are investigated for the adsorption of aromatic amino acids l-phenylalanine (l-Phe), l-tryptophan (l-Trp), and l-tyrosine (l-Tyr) from aqueous solutions. After screening a range of water-stable MOFs, the hyd…
View article: The Remarkable Amphoteric Nature of Defective UiO‐66 in Catalytic Reactions
The Remarkable Amphoteric Nature of Defective UiO‐66 in Catalytic Reactions Open
One of the major requirements in solid acid and base catalyzed reactions is that the reactants, intermediates or activated complexes cooperate with several functions of catalyst support. In this work the remarkable bifunctional behavior of…
View article: An in situ investigation of the water-induced phase transformation of UTSA-74 to MOF-74(Zn)
An in situ investigation of the water-induced phase transformation of UTSA-74 to MOF-74(Zn) Open
In water, UTSA-74 transforms through a dissolution–recrystallization process to its polymorph MOF-74(Zn).
View article: Gel-based morphological design of zirconium metal–organic frameworks
Gel-based morphological design of zirconium metal–organic frameworks Open
The ability of zirconium metal–organic frameworks (MOFs) to gelate under specific synthetic conditions opens up new opportunities in the preparation and shaping of hierarchically porous MOF monoliths, which could be directly implemented fo…
View article: A Breathing Zirconium Metal–Organic Framework with Reversible Loss of Crystallinity by Correlated Nanodomain Formation
A Breathing Zirconium Metal–Organic Framework with Reversible Loss of Crystallinity by Correlated Nanodomain Formation Open
The isoreticular analogue of the metal–organic framework UiO‐66(Zr), synthesized with the flexible trans ‐1,4‐cyclohexanedicarboxylic acid as linker, shows a peculiar breathing behavior by reversibly losing long‐range crystalline order upo…
View article: Towards metal–organic framework based field effect chemical sensors: UiO-66-NH<sub>2</sub> for nerve agent detection
Towards metal–organic framework based field effect chemical sensors: UiO-66-NH<sub>2</sub> for nerve agent detection Open
Kelvin probe monitoring of metal-organic framework coated electrodes is demonstrated as a route for ppb-level detection of alkyl phosphonates.
View article: CCDC 930933: Experimental Crystal Structure Determination
CCDC 930933: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1434981: Experimental Crystal Structure Determination
CCDC 1434981: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …