Benjamin Wittwer
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View article: Diverging Reactivity in Anilidophosphine Supported Group III Complexes
Diverging Reactivity in Anilidophosphine Supported Group III Complexes Open
We report the synthesis of scandium and yttrium halide complexes with bidentate, monoanionic anilidophosphine (PN) ligands and the general formula (PN) 2 MX (M = Sc ( 1‐X ), Y ( 2‐X ); X = Cl ( 1‐Cl / 2‐Cl ), X = I ( 1‐I / 2‐I ). Attempts …
View article: Modular Synthesis of Monoanionic PN Ligands Leads to Unexpected Structural Diversity in Lanthanum Chemistry
Modular Synthesis of Monoanionic PN Ligands Leads to Unexpected Structural Diversity in Lanthanum Chemistry Open
We report a new synthetic entry to a series of N-substituted anilidophosphine ligands (short HPNR, R = pTol (HPNTol), 3,5-dimethylphenyl (HPN3,5Me), 3,5-bis(trifluoromethy…
View article: Light-induced splitting of P–C bonds in a lanthanum(<scp>iii</scp>) hemiphosphinal complex
Light-induced splitting of P–C bonds in a lanthanum(<span>iii</span>) hemiphosphinal complex Open
Irradiation of hemiphosphinal lanthanum complexes results in unprecedented C–P bond scission, leading to crystalline ketyl radicals and P–P diphosphine coupling.
View article: Scrutinizing the redox chemistry of group 10 complexes supported by a redox-active bis-phenolate mesoionic carbene
Scrutinizing the redox chemistry of group 10 complexes supported by a redox-active bis-phenolate mesoionic carbene Open
We present the synthesis of an isostructural series of group 10 mesoionic carbene complexes with the general formula [M(MIC)Py] (with M = Ni (1), Pd (2) and Pt (3), Py = pyridine and MIC = bis-phenolate triazolylidene). Their electrochemic…
View article: CCDC 2153145: Experimental Crystal Structure Determination
CCDC 2153145: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2225297: Experimental Crystal Structure Determination
CCDC 2225297: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2153308: Experimental Crystal Structure Determination
CCDC 2153308: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2153142: Experimental Crystal Structure Determination
CCDC 2153142: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2153140: Experimental Crystal Structure Determination
CCDC 2153140: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2097750: Experimental Crystal Structure Determination
CCDC 2097750: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2236155: Experimental Crystal Structure Determination
CCDC 2236155: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2153309: Experimental Crystal Structure Determination
CCDC 2153309: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2153141: Experimental Crystal Structure Determination
CCDC 2153141: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2156408: Experimental Crystal Structure Determination
CCDC 2156408: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2097753: Experimental Crystal Structure Determination
CCDC 2097753: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2225298: Experimental Crystal Structure Determination
CCDC 2225298: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2231867: Experimental Crystal Structure Determination
CCDC 2231867: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2153143: Experimental Crystal Structure Determination
CCDC 2153143: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2153144: Experimental Crystal Structure Determination
CCDC 2153144: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2156633: Experimental Crystal Structure Determination
CCDC 2156633: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2099970: Experimental Crystal Structure Determination
CCDC 2099970: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Expanding the Utility of β-Diketiminate Ligands in Heavy Group VI Chemistry of Molybdenum and Tungsten
Expanding the Utility of β-Diketiminate Ligands in Heavy Group VI Chemistry of Molybdenum and Tungsten Open
We report the synthesis of 17 molybdenum and tungsten complexes supported by the ubiquitous BDI ligand framework (BDI = β-diketiminate). The focal entry point is the synthesis of four molybdenum and tungsten(V) BDI complexes of the general…
View article: CCDC 1993282: Experimental Crystal Structure Determination
CCDC 1993282: Experimental Crystal Structure Determination Open
View article: CCDC 1953710: Experimental Crystal Structure Determination
CCDC 1953710: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: A mesoionic carbene complex of manganese in five oxidation states
A mesoionic carbene complex of manganese in five oxidation states Open
A rare, high-valent manganese( iv ) mesoionic carbene complex is shown to be stable in five oxidation states, spanning a 3 Volt voltage range.